Forging colloidal nanostructures via cation exchange reactions

Chemical Reviews

Volumn 116, Issue 18, 2016, Pages 10852-10887

  De Trizio, Luca ^a   Manna, Liberato ^a  

^a ISTITUTO ITALIANO DI TECNOLOGIA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

NANOCRYSTALS; NANOSTRUCTURES; POSITIVE IONS;

ALLOY NANOCRYSTALS; CATION EXCHANGE REACTIONS; CATION EXCHANGES; COLLOIDAL NANOCRYSTALS; NANO-HETEROSTRUCTURES; POSSIBLE FUTURES; POST-SYNTHESIS TREATMENT; VERSATILE TOOLS;

NANOCRYSTALLINE ALLOYS;

EID: 84978135297     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/acs.chemrev.5b00739     Document Type: Review

References (204)

1. Yin, Y.; Alivisatos, A. P. Colloidal nanocrystal synthesis and the organic-inorganic interface Nature 2005, 437, 664-670 10.1038/nature04165
2. Nurmikko, A. What future for quantum dot-based light emitters? Nat. Nanotechnol. 2015, 10, 1001-1004 10.1038/nnano.2015.288
3. Clifford, J. P.; Konstantatos, G.; Johnston, K. W.; Hoogland, S.; Levina, L.; Sargent, E. H. Fast, sensitive and spectrally tuneable colloidal-quantum-dot photodetectors Nat. Nanotechnol. 2009, 4, 40-44 10.1038/nnano.2008.313
4. Alivisatos, A. P.; Gu, W. W.; Larabell, C. Annual Review of Biomedical Engineering; Annual Reviews: Palo Alto, 2005; Vol. 7.
5. Li, Z.-B.; Cai, W.; Chen, X. Semiconductor Quantum Dots for In Vivo Imaging J. Nanosci. Nanotechnol. 2007, 7, 2567-2581 10.1166/jnn.2007.628
6. Jain, P.; Huang, X.; El-Sayed, I.; El-Sayed, M. Review of Some Interesting Surface Plasmon Resonance-enhanced Properties of Noble Metal Nanoparticles and Their Applications to Biosystems Plasmonics 2007, 2, 107-118 10.1007/s11468-007-9031-1
7. Klimov, V. I.; Mikhailovsky, A. A.; Xu, S.; Malko, A.; Hollingsworth, J. A.; Leatherdale, C. A.; Eisler, H.-J.; Bawendi, M. G. Optical Gain and Stimulated Emission in Nanocrystal Quantum Dots Science 2000, 290, 314-317 10.1126/science.290.5490.314
8. Bruchez, M.; Moronne, M.; Gin, P.; Weiss, S.; Alivisatos, A. P. Semiconductor Nanocrystals as Fluorescent Biological Labels Science 1998, 281, 2013-2016 10.1126/science.281.5385.2013
9. Brus, L. Electronic wave functions in semiconductor clusters: experiment and theory J. Phys. Chem. 1986, 90, 2555-2560 10.1021/j100403a003
10. Talapin, D. V.; Lee, J.-S.; Kovalenko, M. V.; Shevchenko, E. V. Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Chem. Rev. 2010, 110, 389-458 10.1021/cr900137k
11. Efros, A. L.; Efros, A. Interband absorption of light in semiconductor sphere Semiconductors 1982, 16, 772-775
12. Hergt, R.; Dutz, S.; Müller, R.; Zeisberger, M. Magnetic particle hyperthermia: nanoparticle magnetism and materials development for cancer therapy J. Phys.: Condens. Matter 2006, 18, S2919-S2934 10.1088/0953-8984/18/38/S26
13. Kovalenko, M. V. Opportunities and challenges for quantum dot photovoltaics Nat. Nanotechnol. 2015, 10, 994-997 10.1038/nnano.2015.284
14. Tian, N.; Zhou, Z.-Y.; Sun, S.-G.; Ding, Y.; Wang, Z. L. Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity Science 2007, 316, 732-735 10.1126/science.1140484
15. Pang, X.; Zhao, L.; Han, W.; Xin, X.; Lin, Z. A general and robust strategy for the synthesis of nearly monodisperse colloidal nanocrystals Nat. Nanotechnol. 2013, 8, 426-431 10.1038/nnano.2013.85
16. Milliron, D. J.; Hughes, S. M.; Cui, Y.; Manna, L.; Li, J.; Wang, L.-W.; Paul Alivisatos, A. Colloidal nanocrystal heterostructures with linear and branched topology Nature 2004, 430, 190-195 10.1038/nature02695
17. Oh, N.; Nam, S.; Zhai, Y.; Deshpande, K.; Trefonas, P.; Shim, M. Double-heterojunction nanorods Nat. Commun. 2014, 5, 3642 10.1038/ncomms4642
18. Kovalenko, M. V.; Heiss, W.; Shevchenko, E. V.; Lee, J.-S.; Schwinghammer, H.; Alivisatos, A. P.; Talapin, D. V. SnTe Nanocrystals: A New Example of Narrow-Gap Semiconductor Quantum Dots J. Am. Chem. Soc. 2007, 129, 11354-11355 10.1021/ja074481z
19. Mauser, C.; Limmer, T.; Da Como, E.; Becker, K.; Rogach, A. L.; Feldmann, J.; Talapin, D. V. Anisotropic optical emission of single CdSe/CdS tetrapod heterostructures: Evidence for a wavefunction symmetry breaking Phys. Rev. B: Condens. Matter Mater. Phys. 2008, 77, 153303 10.1103/PhysRevB.77.153303
20. Müller, J.; Lupton, J. M.; Lagoudakis, P. G.; Schindler, F.; Koeppe, R.; Rogach, A. L.; Feldmann, J.; Talapin, D. V.; Weller, H. Wave Function Engineering in Elongated Semiconductor Nanocrystals with Heterogeneous Carrier Confinement Nano Lett. 2005, 5, 2044-2049 10.1021/nl051596x
21. Talapin, D. V.; Koeppe, R.; Götzinger, S.; Kornowski, A.; Lupton, J. M.; Rogach, A. L.; Benson, O.; Feldmann, J.; Weller, H. Highly Emissive Colloidal CdSe/CdS Heterostructures of Mixed Dimensionality Nano Lett. 2003, 3, 1677-1681 10.1021/nl034815s
22. Scotognella, F.; Miszta, K.; Dorfs, D.; Zavelani-Rossi, M.; Brescia, R.; Marras, S.; Manna, L.; Lanzani, G.; Tassone, F. Ultrafast Exciton Dynamics in Colloidal CdSe/CdS Octapod Shaped Nanocrystals J. Phys. Chem. C 2011, 115, 9005-9011 10.1021/jp203000n
23. Pal, B. N.; Ghosh, Y.; Brovelli, S.; Laocharoensuk, R.; Klimov, V. I.; Hollingsworth, J. A.; Htoon, H. 'Giant' CdSe/CdS Core/Shell Nanocrystal Quantum Dots As Efficient Electroluminescent Materials: Strong Influence of Shell Thickness on Light-Emitting Diode Performance Nano Lett. 2012, 12, 331-336 10.1021/nl203620f
24. Ivanov, S. A.; Nanda, J.; Piryatinski, A.; Achermann, M.; Balet, L. P.; Bezel, I. V.; Anikeeva, P. O.; Tretiak, S.; Klimov, V. I. Light Amplification Using Inverted Core/Shell Nanocrystals: Towards Lasing in the Single-Exciton Regime J. Phys. Chem. B 2004, 108, 10625-10630 10.1021/jp0483371
25. Kudera, S.; Carbone, L.; Casula, M. F.; Cingolani, R.; Falqui, A.; Snoeck, E.; Parak, W. J.; Manna, L. Selective Growth of PbSe on One or Both Tips of Colloidal Semiconductor Nanorods Nano Lett. 2005, 5, 445-449 10.1021/nl048060g
26. Costi, R.; Saunders, A. E.; Banin, U. Colloidal Hybrid Nanostructures: A New Type of Functional Materials Angew. Chem., Int. Ed. 2010, 49, 4878-4897 10.1002/anie.200906010
27. Vaneski, A.; Susha, A. S.; Rodríguez-Fernández, J.; Berr, M.; Jäckel, F.; Feldmann, J.; Rogach, A. L. Hybrid Colloidal Heterostructures of Anisotropic Semiconductor Nanocrystals Decorated with Noble Metals: Synthesis and Function Adv. Funct. Mater. 2011, 21, 1547-1556 10.1002/adfm.201002444
28. Son, D. H.; Hughes, S. M.; Yin, Y.; Alivisatos, A. P. Cation Exchange Reactions in Ionic Nanocrystals Science 2004, 306, 1009-1012 10.1126/science.1103755
29. Jeong, U.; Camargo, P. H. C.; Lee, Y. H.; Xia, Y. Chemical transformation: a powerful route to metal chalcogenide nanowires J. Mater. Chem. 2006, 16, 3893-3897 10.1039/b606682h
30. Camargo, P. H. C.; Lee, Y. H.; Jeong, U.; Zou, Z.; Xia, Y. Cation Exchange: A Simple and Versatile Route to Inorganic Colloidal Spheres with the Same Size but Different Compositions and Properties Langmuir 2007, 23, 2985-2992 10.1021/la0632070
31. Moon, G. D.; Ko, S.; Xia, Y.; Jeong, U. Chemical Transformations in Ultrathin Chalcogenide Nanowires ACS Nano 2010, 4, 2307-2319 10.1021/nn9018575
32. Moon, G. D.; Ko, S.; Min, Y.; Zeng, J.; Xia, Y.; Jeong, U. Chemical transformations of nanostructured materials Nano Today 2011, 6, 186-203 10.1016/j.nantod.2011.02.006
33. Rivest, J. B.; Jain, P. K. Cation exchange on the nanoscale: an emerging technique for new material synthesis, device fabrication, and chemical sensing Chem. Soc. Rev. 2013, 42, 89-96 10.1039/C2CS35241A
34. Fayette, M.; Robinson, R. D. Chemical transformations of nanomaterials for energy applications J. Mater. Chem. A 2014, 2, 5965-5965 10.1039/C3TA13982D
35. Gupta, S.; Kershaw, S. V.; Rogach, A. L. 25th Anniversary Article: Ion Exchange in Colloidal Nanocrystals Adv. Mater. 2013, 25, 6923-6944 10.1002/adma.201302400
36. Mews, A.; Eychmüller, A.; Giersig, M.; Schooss, D.; Weller, H. Preparation, characterization, and photophysics of the quantum dot quantum well system CdS/HgS/CdS J. Phys. Chem. 1994, 98, 934-941 10.1021/j100054a032
37. Zhou, H. S.; Sasahara, H.; Honma, I.; Komiyama, H.; Haus, J. W. Coated Semiconductor Nanoparticles: The CdS/PbS System's Photoluminescence Properties Chem. Mater. 1994, 6, 1534-1541 10.1021/cm00045a010
38. Lechner, R. T.; Fritz-Popovski, G.; Yarema, M.; Heiss, W.; Hoell, A.; Schülli, T. U.; Primetzhofer, D.; Eibelhuber, M.; Paris, O. Crystal Phase Transitions in the Shell of PbS/CdS Core/Shell Nanocrystals Influences Photoluminescence Intensity Chem. Mater. 2014, 26, 5914-5922 10.1021/cm502521q
39. Zherebetskyy, D.; Zhang, Y.; Salmeron, M.; Wang, L.-W. Tolerance of Intrinsic Defects in PbS Quantum Dots J. Phys. Chem. Lett. 2015, 6, 4711-4716 10.1021/acs.jpclett.5b02202
40. Justo, Y.; Sagar, L. K.; Flamee, S.; Zhao, Q.; Vantomme, A.; Hens, Z. Less Is More. Cation Exchange and the Chemistry of the Nanocrystal Surface ACS Nano 2014, 8, 7948-7957 10.1021/nn5037812
41. Casavola, M.; van Huis, M. A.; Bals, S.; Lambert, K.; Hens, Z.; Vanmaekelbergh, D. Anisotropic Cation Exchange in PbSe/CdSe Core/Shell Nanocrystals of Different Geometry Chem. Mater. 2012, 24, 294-302 10.1021/cm202796s
42. Groeneveld, E.; Witteman, L.; Lefferts, M.; Ke, X.; Bals, S.; Van Tendeloo, G.; de Mello Donega, C. Tailoring ZnSe-CdSe Colloidal Quantum Dots via Cation Exchange: From Core/Shell to Alloy Nanocrystals ACS Nano 2013, 7, 7913-7930 10.1021/nn402931y
43. Routzahn, A. L.; Jain, P. K. Single-Nanocrystal Reaction Trajectories Reveal Sharp Cooperative Transitions Nano Lett. 2014, 14, 987-992 10.1021/nl4044289
44. 4 with a Hollow Nanocage J. Am. Chem. Soc. 2005, 127, 16024-16025 10.1021/ja055265y
45. Geng, J.; Liu, B.; Xu, L.; Hu, F.-N.; Zhu, J.-J. Facile Route to Zn-Based II-VI Semiconductor Spheres, Hollow Spheres, and Core/Shell Nanocrystals and Their Optical Properties Langmuir 2007, 23, 10286-10293 10.1021/la701299w
46. Saruyama, M.; So, Y.-G.; Kimoto, K.; Taguchi, S.; Kanemitsu, Y.; Teranishi, T. Spontaneous Formation of Wurzite-CdS/Zinc Blende-CdTe Heterodimers through a Partial Anion Exchange Reaction J. Am. Chem. Soc. 2011, 133, 17598-17601 10.1021/ja2078224
47. Park, J.; Zheng, H.; Jun, Y.-w.; Alivisatos, A. P. Hetero-Epitaxial Anion Exchange Yields Single-Crystalline Hollow Nanoparticles J. Am. Chem. Soc. 2009, 131, 13943-13945 10.1021/ja905732q
48. Zhang, F.; Shi, Y.; Sun, X.; Zhao, D.; Stucky, G. D. Formation of Hollow Upconversion Rare-Earth Fluoride Nanospheres: Nanoscale Kirkendall Effect During Ion Exchange Chem. Mater. 2009, 21, 5237-5243 10.1021/cm902231s
49. Dloczik, L.; Könenkamp, R. Nanostructure Transfer in Semiconductors by Ion Exchange Nano Lett. 2003, 3, 651-653 10.1021/nl0340879
50. Dawood, F.; Schaak, R. E. ZnO-Templated Synthesis of Wurtzite-Type ZnS and ZnSe Nanoparticles J. Am. Chem. Soc. 2009, 131, 424-425 10.1021/ja808455u
51. 16 nanorods J. Colloid Interface Sci. 2014, 422, 30-37 10.1016/j.jcis.2014.02.009
52. 3 Nanoparticles in Flowing Ammonia J. Am. Ceram. Soc. 2006, 89, 415-421 10.1111/j.1551-2916.2005.00715.x
53. Mizusaki, J.; Arai, K.; Fueki, K. Ionic conduction of the perovskite-type halides Solid State Ionics 1983, 11, 203-211 10.1016/0167-2738(83)90025-5
54. 3 perovskite solar cells: the role of a compensated electric field Energy Environ. Sci. 2015, 8, 995-1004 10.1039/C4EE03664F
55. Stranks, S. D.; Snaith, H. J. Metal-halide perovskites for photovoltaic and light-emitting devices Nat. Nanotechnol. 2015, 10, 391-402 10.1038/nnano.2015.90
56. Akkerman, Q. A.; D'Innocenzo, V.; Accornero, S.; Scarpellini, A.; Petrozza, A.; Prato, M.; Manna, L. Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions J. Am. Chem. Soc. 2015, 137, 10276-10281 10.1021/jacs.5b05602
57. 3, X = Cl, Br, I) Nano Lett. 2015, 15, 5635-5640 10.1021/acs.nanolett.5b02404
58. Pellet, N.; Teuscher, J.; Maier, J.; Grätzel, M. Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange Chem. Mater. 2015, 27, 2181-2188 10.1021/acs.chemmater.5b00281
59. Solis-Ibarra, D.; Smith, I. C.; Karunadasa, H. I. Post-synthetic halide conversion and selective halogen capture in hybrid perovskites Chem. Sci. 2015, 6, 4054-4059 10.1039/C5SC01135C
60. Luo, Y. R. Comprehensive Handbook of Chemical Bond Energies; CRC Press: Boca Raton, FL, 2007.
61. Lide, D. R. CRC Handbook of Chemistry and Physics, 84th ed.; Taylor & Francis: London, 2003.
62. Mu, L.; Feng, C.; He, H. Topological research on lattice energies for inorganic compounds MATCH Commun. Math. Comput. Chem. 2006, 56, 97-111
63. Sheng, Y.; Wei, J.; Liu, B.; Peng, L. A facile route to synthesize CdZnSe core-shell-like alloyed quantum dots via cation exchange reaction in aqueous system Mater. Res. Bull. 2014, 57, 67-71 10.1016/j.materresbull.2014.05.033
64. 1-xSe alloy nanocrystals via cation exchange reaction Nanotechnology 2007, 18, 385606 10.1088/0957-4484/18/38/385606
65. 2-xS Core/Shell Nanocrystals J. Am. Chem. Soc. 2015, 137, 12195-12198 10.1021/jacs.5b06379
66. Wark, S. E.; Hsia, C.-H.; Son, D. H. Effects of Ion Solvation and Volume Change of Reaction on the Equilibrium and Morphology in Cation-Exchange Reaction of Nanocrystals J. Am. Chem. Soc. 2008, 130, 9550-9555 10.1021/ja802187c
67. Parr, R. G.; Pearson, R. G. Absolute hardness: companion parameter to absolute electronegativity J. Am. Chem. Soc. 1983, 105, 7512-7516 10.1021/ja00364a005
68. Pearson, R. G. Absolute electronegativity and hardness: application to inorganic chemistry Inorg. Chem. 1988, 27, 734-740 10.1021/ic00277a030
69. Lange, N. A.; Dean, J. A. Lange's Handbook of chemistry; McGraw-Hill: New York, 1979.
70. Sadtler, B.; Demchenko, D. O.; Zheng, H.; Hughes, S. M.; Merkle, M. G.; Dahmen, U.; Wang, L.-W.; Alivisatos, A. P. Selective facet reactivity during cation exchange in cadmium sulfide nanorods J. Am. Chem. Soc. 2009, 131, 5285-5293 10.1021/ja809854q
71. Robinson, R. D.; Sadtler, B.; Demchenko, D. O.; Erdonmez, C. K.; Wang, L.-W.; Alivisatos, A. P. Spontaneous superlattice formation in nanorods through partial cation exchange Science 2007, 317, 355-358 10.1126/science.1142593
72. Mukherjee, B.; Peterson, A.; Subramanian, V. 1D CdS/PbS heterostructured nanowire synthesis using cation exchange Chem. Commun. 2012, 48, 2415-2417 10.1039/c2cc16254g
73. Miszta, K.; Dorfs, D.; Genovese, A.; Kim, M. R.; Manna, L. Cation exchange reactions in colloidal branched nanocrystals ACS Nano 2011, 5, 7176-7183 10.1021/nn201988w
74. 2S Nanorod Array Solar Cells Nano Lett. 2015, 15, 4096-4101 10.1021/acs.nanolett.5b01203
75. 2Se Gels and Aerogels by Cation Exchange Reactions J. Am. Chem. Soc. 2009, 131, 2800-2801 10.1021/ja900042y
76. Li, J.; Zhang, T.; Ge, J.; Yin, Y.; Zhong, W. Fluorescence Signal Amplification by Cation Exchange in Ionic Nanocrystals Angew. Chem., Int. Ed. 2009, 48, 1588-1591 10.1002/anie.200805710
77. Lubeck, C. R.; Han, T. Y. J.; Gash, A. E.; Satcher, J. H.; Doyle, F. M. Synthesis of Mesostructured Copper Sulfide by Cation Exchange and Liquid-Crystal Templating Adv. Mater. 2006, 18, 781-784 10.1002/adma.200501653
78. Dorn, A.; Allen, P. M.; Harris, D. K.; Bawendi, M. G. In Situ Electrical Monitoring of Cation Exchange in Nanowires Nano Lett. 2010, 10, 3948-3951 10.1021/nl102560b
79. Jain, P. K.; Amirav, L.; Aloni, S.; Alivisatos, A. P. Nanoheterostructure Cation Exchange: Anionic Framework Conservation J. Am. Chem. Soc. 2010, 132, 9997-9999 10.1021/ja104126u
80. Jain, P. K.; Beberwyck, B. J.; Fong, L.-K.; Polking, M. J.; Alivisatos, A. P. Highly Luminescent Nanocrystals From Removal of Impurity Atoms Residual From Ion-Exchange Synthesis Angew. Chem., Int. Ed. 2012, 51, 2387-2390 10.1002/anie.201107452
81. Rivest, J. B.; Buonsanti, R.; Pick, T. E.; Zhu, L.; Lim, E.; Clavero, C.; Schaible, E.; Helms, B. A.; Milliron, D. J. Evolution of Ordered Metal Chalcogenide Architectures through Chemical Transformations J. Am. Chem. Soc. 2013, 135, 7446-7449 10.1021/ja403071w
82. Yao, J.; Han, X.; Zeng, S.; Zhong, W. Detection of Femtomolar Proteins by Nonfluorescent ZnS Nanocrystal Clusters Anal. Chem. 2012, 84, 1645-1652 10.1021/ac202910y
83. 2 generation ACS Appl. Mater. Interfaces 2014, 6, 9078-9084 10.1021/am5020953
84. 2+ ions J. Nanopart. Res. 2014, 16, 1-12 10.1007/s11051-014-2762-y
85. Shi, Y.; Chen, J.; Shen, P. ZnS micro-spheres and flowers: Chemically controlled synthesis and template use in fabricating MS(shell)/ZnS(core) and MS (M = Pb, Cu) hollow microspheres J. Alloys Compd. 2007, 441, 337-343 10.1016/j.jallcom.2006.09.104
86. Qu, Z.; Yan, L.; Li, L.; Xu, J.; Liu, M.; Li, Z.; Yan, N. Ultraeffective ZnS Nanocrystals Sorbent for Mercury(II) Removal Based on Size-Dependent Cation Exchange ACS Appl. Mater. Interfaces 2014, 6, 18026-18032 10.1021/am504896w
87. 2S/Ag Heterodimers J. Am. Chem. Soc. 2010, 132, 10771-10785 10.1021/ja102105q
88. Justo, Y.; Goris, B.; Kamal, J. S.; Geiregat, P.; Bals, S.; Hens, Z. Multiple Dot-in-Rod PbS/CdS Heterostructures with High Photoluminescence Quantum Yield in the Near-Infrared J. Am. Chem. Soc. 2012, 134, 5484-5487 10.1021/ja300337d
89. Haibao, S.; Chunlei, W.; Shuhong, X.; Yuan, J.; Yujie, S.; Fan, B.; Zhuyuan, W.; Yiping, C. Hydrazine-promoted sequential cation exchange: a novel synthesis method for doped ternary semiconductor nanocrystals with tunable emission Nanotechnology 2014, 25, 025603 10.1088/0957-4484/25/2/025603
90. Prudnikau, A.; Artemyev, M.; Molinari, M.; Troyon, M.; Sukhanova, A.; Nabiev, I.; Baranov, A. V.; Cherevkov, S. a.; Fedorov, A. V. Chemical substitution of Cd ions by Hg in CdSe nanorods and nanodots: Spectroscopic and structural examination Mater. Sci. Eng., B 2012, 177, 744-749 10.1016/j.mseb.2011.12.038
91. 3 nanoparticles and their application for a flexible UV photodetector Nanotechnology 2011, 22, 465604 10.1088/0957-4484/22/46/465604
92. Li, H.; Zanella, M.; Genovese, A.; Povia, M.; Falqui, A.; Giannini, C.; Manna, L. Sequential Cation Exchange in Nanocrystals: Preservation of Crystal Phase and Formation of Metastable Phases Nano Lett. 2011, 11, 4964-4970 10.1021/nl202927a
93. Li, H.; Brescia, R.; Krahne, R.; Bertoni, G.; Alcocer, M. J. P.; D'Andrea, C.; Scotognella, F.; Tassone, F.; Zanella, M.; De Giorgi, M. et al. Blue-UV-Emitting ZnSe(Dot)/ZnS(Rod) Core/Shell Nanocrystals Prepared from CdSe/CdS Nanocrystals by Sequential Cation Exchange ACS Nano 2012, 6, 1637-1647 10.1021/nn204601n
94. (1-x)Te Alloy Colloidal Quantum Dots: Tuning Optical Properties from the Visible to Near-Infrared by Ion Exchange Part. Part. Syst. Charact. 2013, 30, 346-354 10.1002/ppsc.201200139
95. + ions Luminescence 2013, 28, 287-293 10.1002/bio.2379
96. Smith, A. M.; Nie, S. Bright and Compact Alloyed Quantum Dots with Broadly Tunable Near-Infrared Absorption and Fluorescence Spectra through Mercury Cation Exchange J. Am. Chem. Soc. 2011, 133, 24-26 10.1021/ja108482a
97. Kriegel, I.; Rodríguez-Fernández, J.; Wisnet, A.; Zhang, H.; Waurisch, C.; Eychmüller, A.; Dubavik, A.; Govorov, A. O.; Feldmann, J. Shedding Light on Vacancy-Doped Copper Chalcogenides: Shape-Controlled Synthesis, Optical Properties, and Modeling of Copper Telluride Nanocrystals with Near-Infrared Plasmon Resonances ACS Nano 2013, 7, 4367-4377 10.1021/nn400894d
98. Jeong, U.; Kim, J.-U.; Xia, Y.; Li, Z.-Y. Monodispersed Spherical Colloids of Se@CdSe: Synthesis and Use as Building Blocks in Fabricating Photonic Crystals Nano Lett. 2005, 5, 937-942 10.1021/nl050482i
99. Jeong, U.; Xia, Y.; Yin, Y. Large-scale synthesis of single-crystal CdSe nanowires through a cation-exchange route Chem. Phys. Lett. 2005, 416, 246-250 10.1016/j.cplett.2005.09.106
100. Acharya, S.; Pradhan, N. Insertion/Ejection of Dopant Ions in Composition Tunable Semiconductor Nanocrystals J. Phys. Chem. C 2011, 115, 19513-19519 10.1021/jp2052147
101. Adel, P.; Wolf, A.; Kodanek, T.; Dorfs, D. Segmented CdSe@CdS/ZnS Nanorods Synthesized via a Partial Ion Exchange Sequence Chem. Mater. 2014, 26, 3121-3127 10.1021/cm500431m
102. 2S to Ternary Cu-In-S and Quaternary Cu-In-Zn-S Nanocrystals with Tunable Composition via Partial Cation Exchange ACS Nano 2015, 9, 521-531 10.1021/nn505786d
103. 2-xS Nanocrystals Chem. Mater. 2015, 27, 621-628 10.1021/cm504340h
104. 3-xP Nanocrystals as a Material Platform for Near-Infrared Plasmonics and Cation Exchange Reactions Chem. Mater. 2015, 27, 1120-1128 10.1021/cm5044792
105. 1-y) alloy nanocrystals with controllable crystal phase: synthesis, plasmonic properties, cation exchange and electrochemical lithiation J. Mater. Chem. 2012, 22, 13023-13031 10.1039/c2jm30788j
106. Zhang, J.; Tang, Y.; Lee, K.; Ouyang, M. Nonepitaxial Growth of Hybrid Core-Shell Nanostructures with Large Lattice Mismatches Science 2010, 327, 1634-1638 10.1126/science.1184769
107. Ha, D.-H.; Caldwell, A. H.; Ward, M. J.; Honrao, S.; Mathew, K.; Hovden, R.; Koker, M. K. A.; Muller, D. A.; Hennig, R. G.; Robinson, R. D. Solid-Solid Phase Transformations Induced through Cation Exchange and Strain in 2D Heterostructured Copper Sulfide Nanocrystals Nano Lett. 2014, 14, 7090-7099 10.1021/nl5035607
108. Lesnyak, V.; George, C.; Genovese, A.; Prato, M.; Casu, A.; Ayyappan, S.; Scarpellini, A.; Manna, L. Alloyed Copper Chalcogenide Nanoplatelets via Partial Cation Exchange Reactions ACS Nano 2014, 8, 8407-8418 10.1021/nn502906z
109. Li, H.; Brescia, R.; Povia, M.; Prato, M.; Bertoni, G.; Manna, L.; Moreels, I. Synthesis of Uniform Disk-Shaped Copper Telluride Nanocrystals and Cation Exchange to Cadmium Telluride Quantum Disks with Stable Red Emission J. Am. Chem. Soc. 2013, 135, 12270-12278 10.1021/ja404694k
110. Mu, L.; Wang, F.; Sadtler, B.; Loomis, R. A.; Buhro, W. E. Influence of the Nanoscale Kirkendall Effect on the Morphology of Copper Indium Disulfide Nanoplatelets Synthesized by Ion Exchange ACS Nano 2015, 9, 7419-7428 10.1021/acsnano.5b02427
111. xSe nanorods of varying compositions Appl. Catal., A 2014, 476, 140-147 10.1016/j.apcata.2014.02.023
112. Lambright, S.; Butaeva, E.; Razgoniaeva, N.; Hopkins, T.; Smith, B.; Perera, D.; Corbin, J.; Khon, E.; Thomas, R.; Moroz, P. et al. Enhanced Lifetime of Excitons in Nonepitaxial Au/CdS Core/Shell Nanocrystals ACS Nano 2014, 8, 352-361 10.1021/nn404264w
113. 2 Nanocrystals by Partial Cation Exchange Chem. Mater. 2012, 24, 2400-2406 10.1021/cm301211e
114. Gui, J.; Ji, M.; Liu, J.; Xu, M.; Zhang, J.; Zhu, H. Phosphine-Initiated Cation Exchange for Precisely Tailoring Composition and Properties of Semiconductor Nanostructures: Old Concept, New Applications Angew. Chem., Int. Ed. 2015, 54, 3683-3687 10.1002/anie.201410053
115. Sahu, A.; Kang, M. S.; Kompch, A.; Notthoff, C.; Wills, A. W.; Deng, D.; Winterer, M.; Frisbie, C. D.; Norris, D. J. Electronic Impurity Doping in CdSe Nanocrystals Nano Lett. 2012, 12, 2587-2594 10.1021/nl300880g
116. Kovalenko, M. V.; Schaller, R. D.; Jarzab, D.; Loi, M. A.; Talapin, D. V. Inorganically Functionalized PbS-CdS Colloidal Nanocrystals: Integration into Amorphous Chalcogenide Glass and Luminescent Properties J. Am. Chem. Soc. 2012, 134, 2457-2460 10.1021/ja2087689
117. Luther, J. M.; Zheng, H.; Sadtler, B.; Alivisatos, a. P. Synthesis of PbS nanorods and other ionic nanocrystals of complex morphology by sequential cation exchange reactions J. Am. Chem. Soc. 2009, 131, 16851-16857 10.1021/ja906503w
118. Zhang, J.; Chernomordik, B. D.; Crisp, R. W.; Kroupa, D. M.; Luther, J. M.; Miller, E. M.; Gao, J.; Beard, M. C. Preparation of Cd/Pb Chalcogenide Heterostructured Janus Particles via Controllable Cation Exchange ACS Nano 2015, 9, 7151-7163 10.1021/acsnano.5b01859
119. Tolman, C. A. Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis Chem. Rev. 1977, 77, 313-348 10.1021/cr60307a002
120. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: New York, 2014.
121. Lee, D.; Kim, W. D.; Lee, S.; Bae, W. K.; Lee, S.; Lee, D. C. Direct Cd-to-Pb Exchange of CdSe Nanorods into PbSe/CdSe Axial Heterojunction Nanorods Chem. Mater. 2015, 27, 5295-5304 10.1021/acs.chemmater.5b01548
122. Pietryga, J. M.; Werder, D. J.; Williams, D. J.; Casson, J. L.; Schaller, R. D.; Klimov, V. I.; Hollingsworth, J. a. Utilizing the lability of lead selenide to produce heterostructured nanocrystals with bright, stable infrared emission J. Am. Chem. Soc. 2008, 130, 4879-4885 10.1021/ja710437r
123. De Geyter, B.; Justo, Y.; Moreels, I.; Lambert, K.; Smet, P. F.; Van Thourhout, D.; Houtepen, A. J.; Grodzinska, D.; de Mello Donega, C.; Meijerink, A. et al. The Different Nature of Band Edge Absorption and Emission in Colloidal PbSe/CdSe Core/Shell Quantum Dots ACS Nano 2011, 5, 58-66 10.1021/nn102980e
124. Grodzińska, D.; Evers, W. H.; Dorland, R.; van Rijssel, J.; van Huis, M. A.; Meijerink, A.; de Mello Donegá, C.; Vanmaekelbergh, D. Two-Fold Emission From the S-Shell of PbSe/CdSe Core/Shell Quantum Dots Small 2011, 7, 3493-3501 10.1002/smll.201101819
125. Grodzinska, D.; Pietra, F.; van Huis, M. A.; Vanmaekelbergh, D.; de Mello Donega, C. Thermally induced atomic reconstruction of PbSe/CdSe core/shell quantum dots into PbSe/CdSe bi-hemisphere hetero-nanocrystals J. Mater. Chem. 2011, 21, 11556-11565 10.1039/c0jm04458j
126. Lin, Q.; Makarov, N. S.; Koh, W.-k.; Velizhanin, K. A.; Cirloganu, C. M.; Luo, H.; Klimov, V. I.; Pietryga, J. M. Design and Synthesis of Heterostructured Quantum Dots with Dual Emission in the Visible and Infrared ACS Nano 2015, 9, 539-547 10.1021/nn505793y
127. Lambert, K.; Geyter, B. D.; Moreels, I.; Hens, Z. PbTe|CdTe Core|Shell Particles by Cation Exchange, a HR-TEM study Chem. Mater. 2009, 21, 778-780 10.1021/cm8029399
128. Eilers, J.; Groeneveld, E.; de Mello Donegá, C.; Meijerink, A. Optical Properties of Mn-Doped ZnTe Magic Size Nanocrystals J. Phys. Chem. Lett. 2012, 3, 1663-1667 10.1021/jz300300g
129. Groeneveld, E.; van Berkum, S.; van Schooneveld, M. M.; Gloter, A.; Meeldijk, J. D.; van den Heuvel, D. J.; Gerritsen, H. C.; de Mello Donega, C. Highly Luminescent (Zn,Cd)Te/CdSe Colloidal Heteronanowires with Tunable Electron-Hole Overlap Nano Lett. 2012, 12, 749-757 10.1021/nl203695m
130. Kim, S.; Marshall, A. R.; Kroupa, D. M.; Miller, E. M.; Luther, J. M.; Jeong, S.; Beard, M. C. Air-Stable and Efficient PbSe Quantum-Dot Solar Cells Based upon ZnSe to PbSe Cation-Exchanged Quantum Dots ACS Nano 2015, 9, 8157-8164 10.1021/acsnano.5b02326
131. Jeong, S.; Han, J. H.; Jang, J.-t.; Seo, J.-w.; Kim, J.-G.; Cheon, J. Transformative Two-Dimensional Layered Nanocrystals J. Am. Chem. Soc. 2011, 133, 14500-14503 10.1021/ja2049594
132. Narayanan, B.; Bhadbhade, M. M. X-Ray Structure Of Thermochromic Bis(N,N-Diethylethylenediamine)-Copper(II)Tetrafluoroborate J. Coord. Chem. 1998, 46, 115-123 10.1080/00958979808047201
133. Fabbrizzi, L.; Micheloni, M.; Paoletti, P. Continuous and discontinuous thermochromism of copper(II) and nickel(II) complexes with N,N-diethylethylenediamine Inorg. Chem. 1974, 13, 3019-3021 10.1021/ic50142a049
134. Grenthe, I.; Paoletti, P.; Sandstroem, M.; Glikberg, S. Thermochromism in copper(II) complexes. Structures of the red and blue-violet forms of bis(N,N-diethylethylenediamine)copper(II) perchlorate and the nonthermochromic violet bis(N-ethylethylenediamine)copper(II) perchlorate Inorg. Chem. 1979, 18, 2687-2692 10.1021/ic50200a010
135. Thayer, J. Organometallic Compounds and Living Organisms; Elsevier Science: Amsterdam, 2012.
136. Sines, I. T.; Schaak, R. E. Phase-Selective Chemical Extraction of Selenium and Sulfur from Nanoscale Metal Chalcogenides: A General Strategy for Synthesis, Purification, and Phase Targeting J. Am. Chem. Soc. 2011, 133, 1294-1297 10.1021/ja110374d
137. Lesnyak, V.; Brescia, R.; Messina, G. C.; Manna, L. Cu Vacancies Boost Cation Exchange Reactions in Copper Selenide Nanocrystals J. Am. Chem. Soc. 2015, 137, 9315-9323 10.1021/jacs.5b03868
138. Ethayaraja, M.; Bandyopadhyaya, R. Model for Core-Shell Nanoparticle Formation by Ion-Exchange Mechanism Ind. Eng. Chem. Res. 2008, 47, 5982-5985 10.1021/ie0715106
139. Mehrer, H. Diffusion in Solids: Fundamentals, Methods, Materials, Diffusion-Controlled Processes; Springer: Berlin, 2007.
140. Yalcin, A. O.; Fan, Z.; Goris, B.; Li, W.-F.; Koster, R. S.; Fang, C.-M.; van Blaaderen, A.; Casavola, M.; Tichelaar, F. D.; Bals, S. et al. Atomic Resolution Monitoring of Cation Exchange in CdSe-PbSe Heteronanocrystals during Epitaxial Solid-Solid-Vapor Growth Nano Lett. 2014, 14, 3661-3667 10.1021/nl501441w
141. Bals, S.; Casavola, M.; van Huis, M. A.; Van Aert, S.; Batenburg, K. J.; Van Tendeloo, G.; Vanmaekelbergh, D. Three-Dimensional Atomic Imaging of Colloidal Core-Shell Nanocrystals Nano Lett. 2011, 11, 3420-3424 10.1021/nl201826e
142. 2-xSe Nanocrystals J. Am. Chem. Soc. 2011, 133, 11175-11180 10.1021/ja2016284
143. Luther, J. M.; Jain, P. K.; Ewers, T.; Alivisatos, A. P. Localized surface plasmon resonances arising from free carriers in doped quantum dots Nat. Mater. 2011, 10, 361-366 10.1038/nmat3004
144. Beberwyck, B. J.; Alivisatos, A. P. Ion Exchange Synthesis of III-V Nanocrystals J. Am. Chem. Soc. 2012, 134, 19977-19980 10.1021/ja309416c
145. Bothe, C.; Kornowski, A.; Tornatzky, H.; Schmidtke, C.; Lange, H.; Maultzsch, J.; Weller, H. Solid-State Chemistry on the Nanoscale: Ion Transport through Interstitial Sites or Vacancies? Angew. Chem., Int. Ed. 2015, 54, 14183-14186 10.1002/anie.201507263
146. White, S. L.; Smith, J. G.; Behl, M.; Jain, P. K. Co-operativity in a nanocrystalline solid-state transition Nat. Commun. 2013, 4, 2933 10.1038/ncomms3933
147. Routzahn, A. L.; Jain, P. K. Luminescence Blinking of a Reacting Quantum Dot Nano Lett. 2015, 15, 2504-2509 10.1021/acs.nanolett.5b00068
148. Ott, F. D.; Spiegel, L. L.; Norris, D. J.; Erwin, S. C. Microscopic Theory of Cation Exchange in CdSe Nanocrystals Phys. Rev. Lett. 2014, 113, 156803 10.1103/PhysRevLett.113.156803
149. 2-xSe Nanocrystals J. Am. Chem. Soc. 2014, 136, 16277-16284 10.1021/ja508161c
150. 1-xSe Nanorods Fabricated by Ion Exchange in an Aqueous Medium ChemPhysChem 2013, 14, 2853-2858 10.1002/cphc.201300084
151. Xie, Y.; Bertoni, G.; Riedinger, A.; Sathya, A.; Prato, M.; Marras, S.; Tu, R.; Pellegrino, T.; Manna, L. Nanoscale Transformations in Covellite (CuS) Nanocrystals in the Presence of Divalent Metal Cations in a Mild Reducing Environment Chem. Mater. 2015, 27, 7531-7537 10.1021/acs.chemmater.5b03892
152. Batsanov, S. S.; Batsanov, A. S. Introduction to Structural Chemistry; Springer: The Netherlands, 2012.
153. Ning, J.; Xiao, G.; Wang, L.; Zou, B.; Liu, B.; Zou, G. Facile synthesis of magnetic metal (Mn, Fe, Co, and Ni) oxides nanocrystals via a cation-exchange reaction Nanoscale 2011, 3, 741-745 10.1039/C0NR00684J
154. 2-xSe Nanosheets via Cation Exchange J. Phys. Chem. Lett. 2014, 5, 3608-3613 10.1021/jz5019288
155. Li, X.; Chen, K.; Huang, L.; Lu, D.; Liang, J.; Han, H. Sensitive immunoassay for porcine pseudorabies antibody based on fluorescence signal amplification induced by cation exchange in CdSe nanocrystals Microchim. Acta 2013, 180, 303-310 10.1007/s00604-012-0934-y
156. Zhang, J.; Gao, J.; Church, C. P.; Miller, E. M.; Luther, J. M.; Klimov, V. I.; Beard, M. C. PbSe Quantum Dot Solar Cells with More than 6% Efficiency Fabricated in Ambient Atmosphere Nano Lett. 2014, 14, 6010-6015 10.1021/nl503085v
157. Li, W.; Zamani, R.; Ibáñez, M.; Cadavid, D.; Shavel, A.; Morante, J. R.; Arbiol, J.; Cabot, A. Metal Ions To Control the Morphology of Semiconductor Nanoparticles: Copper Selenide Nanocubes J. Am. Chem. Soc. 2013, 135, 4664-4667 10.1021/ja400472m
158. Kovalenko, M. V.; Talapin, D. V.; Loi, M. A.; Cordella, F.; Hesser, G.; Bodnarchuk, M. I.; Heiss, W. Quasi-Seeded Growth of Ligand-Tailored PbSe Nanocrystals through Cation-Exchange-Mediated Nucleation Angew. Chem., Int. Ed. 2008, 47, 3029-3033 10.1002/anie.200705604
159. Shao, H.; Wang, C.; Xu, S.; Wang, Z.; Yin, H.; Cui, Y. Fast Doping of Cu into ZnSe NCs by Hydrazine Promoted Cation Exchange in Aqueous Solution at Room Temperature J. Fluoresc. 2015, 25, 305-310 10.1007/s10895-015-1509-1
160. Bouet, C.; Laufer, D.; Mahler, B.; Nadal, B.; Heuclin, H.; Pedetti, S.; Patriarche, G.; Dubertret, B. Synthesis of Zinc and Lead Chalcogenide Core and Core/Shell Nanoplatelets Using Sequential Cation Exchange Reactions Chem. Mater. 2014, 26, 3002-3008 10.1021/cm5008608
161. Zhang, D.; Wong, A. B.; Yu, Y.; Brittman, S.; Sun, J.; Fu, A.; Beberwyck, B.; Alivisatos, A. P.; Yang, P. Phase-Selective Cation-Exchange Chemistry in Sulfide Nanowire Systems J. Am. Chem. Soc. 2014, 136, 17430-17433 10.1021/ja511010q
162. Tan, C.-S.; Hsiao, C.-H.; Wang, S.-C.; Liu, P.-H.; Lu, M.-Y.; Huang, M. H.; Ouyang, H.; Chen, L.-J. Sequential Cation Exchange Generated Superlattice Nanowires Forming Multiple p-n Heterojunctions ACS Nano 2014, 8, 9422-9426 10.1021/nn5035247
163. 2 reduction J. Am. Chem. Soc. 2015, 137, 14007-14010 10.1021/jacs.5b06778
164. Jang, S. Y.; Song, Y. M.; Kim, H. S.; Cho, Y. J.; Seo, Y. S.; Jung, G. B.; Lee, C.-W.; Park, J.; Jung, M.; Kim, J. et al. Three Synthetic Routes to Single-Crystalline PbS Nanowires with Controlled Growth Direction and Their Electrical Transport Properties ACS Nano 2010, 4, 2391-2401 10.1021/nn100163k
165. 2S core/shell nanostructures Nanoscale 2014, 6, 8852-8857 10.1039/C4NR02114B
166. 1-x by the Cation-Exchange Reaction Part. Part. Syst. Charact. 2013, 30, 1024-1029 10.1002/ppsc.201300166
167. Miszta, K.; Greullet, F.; Marras, S.; Prato, M.; Toma, A.; Arciniegas, M.; Manna, L.; Krahne, R. Nanocrystal Film Patterning by Inhibiting Cation Exchange via Electron-Beam or X-ray Lithography Nano Lett. 2014, 14, 2116-2122 10.1021/nl500349j
168. 2 Dot Core/Rod Shell Heteronanorods by Sequential Cation Exchange ACS Nano 2015, 9, 11430-11438 10.1021/acsnano.5b05496
169. Dong, C.; van Veggel, F. C. J. M. Cation Exchange in Lanthanide Fluoride Nanoparticles ACS Nano 2009, 3, 123-130 10.1021/nn8004747
170. 2 precursors and the multi-color upconversion emissions J. Alloys Compd. 2014, 591, 370-376 10.1016/j.jallcom.2013.12.238
171. Li, M.; Yu, X.-F.; Liang, S.; Peng, X.-N.; Yang, Z.-J.; Wang, Y.-L.; Wang, Q.-Q. Synthesis of Au-CdS Core-Shell Hetero-Nanorods with Efficient Exciton-Plasmon Interactions Adv. Funct. Mater. 2011, 21, 1788-1794 10.1002/adfm.201002233
172. Yin, Y.; Rioux, R. M.; Erdonmez, C. K.; Hughes, S.; Somorjai, G. A.; Alivisatos, A. P. Formation of Hollow Nanocrystals Through the Nanoscale Kirkendall Effect Science 2004, 304, 711-714 10.1126/science.1096566
173. Tian, L.; Yang, X.; Lu, P.; Williams, I. D.; Wang, C.; Ou, S.; Liang, C.; Wu, M. Hollow Single-Crystal Spinel Nanocubes: The Case of Zinc Cobalt Oxide Grown by a Unique Kirkendall Effect Inorg. Chem. 2008, 47, 5522-5524 10.1021/ic702457b
174. Sytnyk, M.; Kirchschlager, R.; Bodnarchuk, M. I.; Primetzhofer, D.; Kriegner, D.; Enser, H.; Stangl, J.; Bauer, P.; Voith, M.; Hassel, A. W. et al. Tuning the Magnetic Properties of Metal Oxide Nanocrystal Heterostructures by Cation Exchange Nano Lett. 2013, 13, 586-593 10.1021/nl304115r
175. 3 Nanoplates and Their Application as Counter Electrodes in Dye-Sensitized Solar Cells Chem. Mater. 2015, 27, 5949-5956 10.1021/acs.chemmater.5b01971
176. Zhang, B.; Jung, Y.; Chung, H.-S.; Vugt, L. V.; Agarwal, R. Nanowire Transformation by Size-Dependent Cation Exchange Reactions Nano Lett. 2010, 10, 149-155 10.1021/nl903059c
177. xS quantum dots by cation exchange for controlled optical properties J. Mater. Chem. C 2015, 3, 3286-3293 10.1039/C4TC02795G
178. 2/ZnS Nanocrystals J. Phys. Chem. C 2013, 117, 648-656 10.1021/jp309202g
179. 2 Nanocrystals and Their Fluorescence Properties J. Phys. Chem. C 2012, 116, 9769-9773 10.1021/jp207711p
180. 4 Nanocrystals through Cation Exchange for Photovoltaic Devices Chem. Mater. 2014, 26, 5492-5498 10.1021/cm501424n
181. Tang, B.; Yang, F.; Lin, Y.; Zhuo, L.; Ge, J.; Cao, L. Synthesis and Characterization of Wavelength-Tunable, Water-Soluble, and Near-Infrared-Emitting CdHgTe Nanorods Chem. Mater. 2007, 19, 1212-1214 10.1021/cm062805x
182. 1-xTe nanocrystals Dalton Trans. 2012, 41, 12726-12732 10.1039/c2dt31602a
183. 4 (Ln = Y, Gd, Yb) nanocrystalsvia in situ cation-exchange reaction J. Mater. Chem. 2012, 22, 2254-2262 10.1039/C1JM14425A
184. 4 Core-Shell Nanoparticles with a Thin, Tunable, and Uniform Shell Chem. Mater. 2012, 24, 1297-1305 10.1021/cm2036844
185. Abel, K. A.; FitzGerald, P. A.; Wang, T.-Y.; Regier, T. Z.; Raudsepp, M.; Ringer, S. P.; Warr, G. G.; van Veggel, F. C. J. M. Probing the Structure of Colloidal Core/Shell Quantum Dots Formed by Cation Exchange J. Phys. Chem. C 2012, 116, 3968-3978 10.1021/jp2112928
186. Abel, K. A.; Qiao, H.; Young, J. F.; van Veggel, F. C. J. M. Four-Fold Enhancement of the Activation Energy for Nonradiative Decay of Excitons in PbSe/CdSe Core/Shell versus PbSe Colloidal Quantum Dots J. Phys. Chem. Lett. 2010, 1, 2334-2338 10.1021/jz1007565
187. 2-x Quantum Dots for Sensitized Solar Cells J. Phys. Chem. Lett. 2013, 4, 355-361 10.1021/jz302067r
188. Zhao, H.; Chaker, M.; Wu, N.; Ma, D. Towards controlled synthesis and better understanding of highly luminescent PbS/CdS core/shell quantum dots J. Mater. Chem. 2011, 21, 8898-8904 10.1039/c1jm11205h
189. Zhao, H.; Wang, D.; Zhang, T.; Chaker, M.; Ma, D. Two-step synthesis of high-quality water-soluble near-infrared emitting quantum dots via amphiphilic polymers Chem. Commun. 2010, 46, 5301-5303 10.1039/c0cc00067a
190. 2/ZnS core/shell quantum dots by cation exchange and their blue-shifted photoluminescence J. Mater. Chem. 2011, 21, 3745-3750 10.1039/c0jm03194a
191. Shemesh, Y.; Macdonald, J. E.; Menagen, G.; Banin, U. Synthesis and Photocatalytic Properties of a Family of CdS-PdX Hybrid Nanoparticles Angew. Chem., Int. Ed. 2011, 50, 1185-1189 10.1002/anie.201006407
192. 2-xTe nano-heterostructures J. Mater. Chem. C 2014, 2, 3189-3198 10.1039/c3tc32049a
193. 3+ nanocrystals and their strong luminescence enhanced by energy transfer of thenoyltrifluoroacetone ligands J. Alloys Compd. 2014, 590, 277-282 10.1016/j.jallcom.2013.12.112
194. 64Cu-Doped CdSe/ZnS Nanocrystals for in Vivo Tumor Imaging J. Am. Chem. Soc. 2014, 136, 1706-1709 10.1021/ja410438n
195. Kalb, A.; Leute, V. The miscibility gap of the system CdSe-HgSe Phys. Status Solidi A 1971, 5, K199-K201 10.1002/pssa.2210050352
196. 2Se and Cu Nanocrystals as Local Sources of Copper in Thermally Activated In Situ Cation Exchange ACS Nano 2016, 10.1021/acsnano.5b07219
197. Dalpian, G. M.; Chelikowsky, J. R. Self-Purification in Semiconductor Nanocrystals Phys. Rev. Lett. 2006, 96, 226802 10.1103/PhysRevLett.96.226802
198. 2S Nanorod Superlattices ACS Nano 2008, 2, 627-636 10.1021/nn700381y
199. Chen, X.; Lou, Y.; Samia, A. C.; Burda, C. Coherency Strain Effects on the Optical Response of Core/Shell Heteronanostructures Nano Lett. 2003, 3, 799-803 10.1021/nl034243b
200. Li, L.; Pandey, A.; Werder, D. J.; Khanal, B. P.; Pietryga, J. M.; Klimov, V. I. Efficient Synthesis of Highly Luminescent Copper Indium Sulfide-Based Core/Shell Nanocrystals with Surprisingly Long-Lived Emission J. Am. Chem. Soc. 2011, 133, 1176-1179 10.1021/ja108261h
201. Ostermann, J.; Merkl, J.-P.; Flessau, S.; Wolter, C.; Kornowksi, A.; Schmidtke, C.; Pietsch, A.; Kloust, H.; Feld, A.; Weller, H. Controlling the Physical and Biological Properties of Highly Fluorescent Aqueous Quantum Dots Using Block Copolymers of Different Size and Shape ACS Nano 2013, 7, 9156-9167 10.1021/nn4037859
202. Palazon, F.; Akkerman, Q. A.; Prato, M.; Manna, L. X-ray Lithography on Perovskite Nanocrystals Films: From Patterning with Anion-Exchange Reactions to Enhanced Stability in Air and Water ACS Nano 2016, 10, 1224-1230 10.1021/acsnano.5b06536
203. Powell, A. E.; Hodges, J. M.; Schaak, R. E. Preserving Both Anion and Cation Sublattice Features during a Nanocrystal Cation-Exchange Reaction: Synthesis of Metastable Wurtzite-Type CoS and MnS J. Am. Chem. Soc. 2016, 138, 471-474 10.1021/jacs.5b10624
204. 3P/CdSe Nanocrystal Heterostructures and Their Evolution upon Thermal Annealing ACS Nano 2013, 7, 3997-4005 10.1021/nn3060219