Kinetic and thermodynamic studies of the reactivity of (trimethylsilyl) diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo-N2CH2SiMe3 bond strength and experimental determination of the enthalpy of formation of (trimethylsilyl)diazomethane

Organometallics

Volumn 27, Issue 19, 2008, Pages 4873-4884

  Fortman, George C ^a   Isrow, Derek ^a   McDonough, James E ^a   Von Ragué Schleyer, Paul ^b   Schaefer III, Henry F ^b   Scott, Brian ^c   Kubas, Gregory J ^c   Kégl, Tamás ^d   Ungváry, Ferenc ^d   Hoff, Carl D ^a  

^a University of Miami   (United States)

^b UNIVERSITY OF GEORGIA   (United States)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

^d UNIVERSITY OF PANNONIA   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

BOND STRENGTH (MATERIALS); COORDINATION REACTIONS; CRYSTAL STRUCTURE; ENTHALPY; HEPTANE; MOLYBDENUM; REACTION RATES; STRENGTH OF MATERIALS; TOLUENE;

BOND STRENGTHS; COMPUTATIONAL DATUM; CONTACT ION PAIRS; CYCLOHEXYL; DIAZOMETHANE; ELECTRON DONORS; ENTHALPY OF FORMATIONS; EXPERIMENTAL DETERMINATIONS; HEAT OF HYDROGENATIONS; HETEROLYTIC CLEAVAGES; HOMOLYTIC CLEAVAGES; KINETIC; ORGANIC REACTIONS; OVERALL REACTIONS; RATE LAWS; REASONABLE AGREEMENTS; SCRAMBLING; SOLUTION CALORIMETRIES; SPACE GROUPS; STOICHIOMETRIC REACTIONS; THEORETICAL CALCULATIONS; TRIMETHYLSILYL; X-RAY CRYSTAL STRUCTURES;

RATE CONSTANTS;

EID: 84962467000     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800336p     Document Type: Article

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