High linear regioselectivity in the rhodium-catalyzed hydro(deuterio) formylation of 3,4,4-trimethylpent-1-ene: The role of β-hydride elimination

Journal of Molecular Catalysis A: Chemical

Volumn 356, Issue , 2012, Pages 1-13

  Lazzaroni, Raffaello ^a   Settambolo, Roberta ^b   Alagona, Giuliano ^b   Ghio, Caterina ^b  

^a UNIVERSITY OF PISA   (Italy)

^b CNR   (Italy)

Author keywords

3,4,4 Trimethylpent 1 ene; 3,4 Dimethylpent 1 ene; 3 Methylbut 1 ene; 3 Methylpent 1 ene; B3P86 6 31G*; Deuterioformylation; DFT; ECP LanL2DZ; Hydroformylation; Regioselectivity

Indexed keywords

ALDEHYDES; CATALYSIS; COORDINATION REACTIONS; CORE LEVELS; DEUTERIUM; EXPERIMENTS; FREE ENERGY; HYDRIDES; HYDROFORMYLATION; HYDROXYLATION; ISOMERS; OLEFINS; ORGANIC COMPOUNDS; REGIOSELECTIVITY; RHODIUM; SUBSTRATES; THERMOMECHANICAL PULPING PROCESS;

3,4,4-TRIMETHYLPENT-1-ENE; 3,4-DIMETHYLPENT-1-ENE; 3-METHYLBUT-1-ENE; 3-METHYLPENT-1-ENE; DEUTERIOFORMYLATION; DFT; ECP/LANL2DZ;

REACTION INTERMEDIATES;

EID: 84962415054     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2011.12.021     Document Type: Article

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