Rhodium-catalyzed deuterioformylation of the ketal-masked β-isophorone: Evidence for a tertiary alkyl rhodium intermediate as a precursor of the main reaction product acetaldehyde derivative

Inorganica Chimica Acta

Volumn 362, Issue 5, 2009, Pages 1641-1644

  Lazzaroni, R ^a   Settambolo, R ^b   Marchetti, M ^b   Paganelli, S ^c   Alagona, G ^b   Ghio, C ^b  

^a UNIVERSITY OF PISA   (Italy)

^b CNR   (Italy)

^c CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

Author keywords

Deuterioformylation; Isomerization; Regioselectivity; Tertiary rhodium alkyl; Elimination

Indexed keywords

ACETALDEHYDE; CATALYSIS; ISOMERIZATION; ISOMERS; REGIOSELECTIVITY;

DEUTERIOFORMYLATION; ISOPHORONES; RHODIUM-CATALYZED; SYN-GAS; TERTIARY RHODIUM ALKYL; THEORETICAL CALCULATIONS;

REACTION INTERMEDIATES;

EID: 60849136312     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2008.07.006     Document Type: Article

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