Rhodium-catalyzed hydro(deuterio)formylation of vinylidenic olefins containing a phenyl and a pyridyl group: Crucial role of the β-hydride elimination in determining regio- and chemoselectivity

Inorganica Chimica Acta

Volumn 357, Issue 10, 2004, Pages 3079-3083

  Lazzaroni, Raffaello ^a   Settambolo, Roberta ^b   Prota, Giovanni ^a   Botteghi, Carlo ^c   Paganelli, Stefano ^c   Marchetti, Mauro ^b  

^a UNIVERSITY OF PISA   (Italy)

^b CNR   (Italy)

^c CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

Author keywords

Deuterioformylation; Hydroformylation; Rhodium catalyst; Tertiary alkyl rhodium intermediate; Vinylidenic olefin

Indexed keywords

HYDROFORMYLATION; OLEFINS; PHOSPHORUS COMPOUNDS; REACTION INTERMEDIATES; RHODIUM COMPOUNDS; SUBSTRATES;

CHEMO-AND REGIOSELECTIVITIES; CRUDE REACTION MIXTURES; DEUTERIOFORMYLATION; MIGRATORY INSERTION; RHODIUM CATALYSTS; SUBSTRATE CONVERSION; TERTIARY ALKYL RHODIUM INTERMEDIATE; VINYLIDENIC;

CATALYSTS;

ALKENE DERIVATIVE; ALKYL GROUP; BENZENE DERIVATIVE; NITROGEN; PHOSPHINE DERIVATIVE; PYRIDINE DERIVATIVE; RHODIUM; VINYL DERIVATIVE;

ALKYLATION; ARTICLE; ATOM; CATALYSIS; CATALYST; DEUTERON NUCLEAR MAGNETIC RESONANCE; ELIMINATION REACTION; HYDROFORMYLATION; OXIDATION; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 3242706764     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2004.03.015     Document Type: Article

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