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Volumn 60, Issue , 2015, Pages 77-87

Novel synthesis of branched polypropylene via solid-state shear pulverization

Author keywords

Long chain branching; Polypropylene; Solid state shear pulverization

Indexed keywords

CHAINS; COMMINUTION; EXTRUSION; MELT SPINNING; NON NEWTONIAN FLOW; ORGANOMETALLICS; POLYMER BLENDS; POLYPROPYLENES; REACTION KINETICS; SHEAR FLOW; SHEAR THINNING; TENSILE STRENGTH;

EID: 84961291069     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2015.01.016     Document Type: Article
Times cited : (25)

References (94)
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    • Yu, Q.1    Zhu, S.2
  • 42
    • 0003451399 scopus 로고
    • Induced decomposition of BPO can occur when a benzoate radical (resulting from either spontaneous decomposition or induced decomposition of BPO) reacts with BPO to yield carbon dioxide, phenyl benzoate, and a benzoate radical. Consequently, induced decomposition increases with increasing BPO concentration and results in loss of reactivity of radicals that would otherwise be produced from the spontaneous decomposition of BPO. See
    • Induced decomposition of BPO can occur when a benzoate radical (resulting from either spontaneous decomposition or induced decomposition of BPO) reacts with BPO to yield carbon dioxide, phenyl benzoate, and a benzoate radical. Consequently, induced decomposition increases with increasing BPO concentration and results in loss of reactivity of radicals that would otherwise be produced from the spontaneous decomposition of BPO. See K. Nozaki, and P.D. Bartlett J Am Chem Soc 68 1946 1686 1692
    • (1946) J Am Chem Soc , vol.68 , pp. 1686-1692
    • Nozaki, K.1    Bartlett, P.D.2
  • 45
    • 84961344284 scopus 로고    scopus 로고
    • Akzo Nobel N.V. [accessed 17.08.14]
    • Akzo Nobel N.V. High melt strength polypropylene https://www.akzonobel.com/polymer/your-industry/polymer-modification/high-meltstrength-polypropylene-hmspp/ [accessed 17.08.14].
    • High Melt Strength Polypropylene
  • 85
    • 34547111261 scopus 로고    scopus 로고
    • We discount the possibility of branching by bimolecular ester-ester reactions resulting in formation of an ether with water as side product during SSSP or melt extrusion because such reactions have not been described in the literature. Instead, preparation of ethers from esters generally is done by direct reduction of the carbonyl group of esters. See, for example, [and references therein]
    • We discount the possibility of branching by bimolecular ester-ester reactions resulting in formation of an ether with water as side product during SSSP or melt extrusion because such reactions have not been described in the literature. Instead, preparation of ethers from esters generally is done by direct reduction of the carbonyl group of esters. See, for example N. Sakai, T. Moriya, and T. Konakahara J Org Chem 72 2007 5920 5922 [and references therein]
    • (2007) J Org Chem , vol.72 , pp. 5920-5922
    • Sakai, N.1    Moriya, T.2    Konakahara, T.3
  • 94
    • 84885223883 scopus 로고    scopus 로고
    • The residual BPO content was determined using information about the grafting yeild obtained for each sample and reported in Ref. [57] The calculations were based on the assumptions that all PP macroradicals were formed solely by chain transfer with BPO radicals and that no induced decomposition of BPO occurs
    • The residual BPO content was determined using information about the grafting yeild obtained for each sample and reported in Ref. [57] M.F. Diop, and J.M. Torkelson Macromolecules 46 2013 7834 7844 The calculations were based on the assumptions that all PP macroradicals were formed solely by chain transfer with BPO radicals and that no induced decomposition of BPO occurs
    • (2013) Macromolecules , vol.46 , pp. 7834-7844
    • Diop, M.F.1    Torkelson, J.M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.