Synthesis of Ultrathin Si Nanosheets from Natural Clays for Lithium-Ion Battery Anodes

ACS Nano

Volumn 10, Issue 2, 2016, Pages 2843-2851

  Ryu, Jaegeon ^a   Hong, Dongki ^a   Choi, Sinho ^a   Park, Soojin ^a  

^a Ulsan National Institute of Science and Technology   (South Korea)

Author keywords

lithium ion battery anode; metallothermic reduction; molten salt induced exfoliation; Si nanosheets

Indexed keywords

ANODES; CARBON; ELECTRIC BATTERIES; ELECTRODES; FUSED SALTS; IONS; LITHIUM; LITHIUM ALLOYS; NANOSHEETS; POROUS SILICON; SECONDARY BATTERIES; SILICATES; SILICON;

CONTROL EXPERIMENTS; HIGH RATE CAPABILITY; HIGH REVERSIBLE CAPACITIES; LITHIUM-ION BATTERY ANODES; METALLOTHERMIC REDUCTION; MOLTEN SALT; NANOSHEET ELECTRODES; TWO-DIMENSIONAL STRUCTURES;

LITHIUM-ION BATTERIES;

EID: 84960192056     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/acsnano.5b07977     Document Type: Article

References (38)

1. Wu, H.; Cui, Y. Designing Nanostructured Si Anodes for High Energy Lithium Ion Batteries Nano Today 2012, 7, 414-429 10.1016/j.nantod.2012.08.004
2. Graetz, J.; Ahn, C. C.; Yazami, R.; Fultz, B. Highly Reversible Lithium Storage in Nanostructured Silicon Electrochem. Solid-State Lett. 2003, 6, A194-A197 10.1149/1.1596917
3. Park, C. M.; Kim, J. H.; Kim, H.; Sohn, H. J. Li-Alloy Based Anode Materials for Li Secondary Batteries Chem. Soc. Rev. 2010, 39, 3115-3141 10.1039/b919877f
4. Kasavajjula, U.; Wang, C. S.; Appleby, A. J. Nano- A nd Bulk-Silicon-Based Insertion Anodes for Lithium-Ion Secondary Cells J. Power Sources 2007, 163, 1003-1039 10.1016/j.jpowsour.2006.09.084
5. Szczech, J. R.; Jin, S. Nanostructured Silicon for High Capacity Lithium Battery Anodes Energy Environ. Sci. 2011, 4, 56-72 10.1039/C0EE00281J
6. Mukherjee, R.; Krishnan, R.; Lu, T. M.; Koratkar, N. Nanostructured Electrodes for High-Power Lithium Ion Batteries Nano Energy 2012, 1, 518-533 10.1016/j.nanoen.2012.04.001
7. Bruce, P. G.; Scrosati, B.; Tarascon, J. M. Nanomaterials for Rechargeable Lithium Batteries Angew. Chem., Int. Ed. 2008, 47, 2930-2946 10.1002/anie.200702505
8. Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk, W. Nanostructured Materials for Advanced Energy Conversion and Storage Devices Nat. Mater. 2005, 4, 366-377 10.1038/nmat1368
9. Dai, F.; Zai, J.; Yi, R.; Gordin, M. L.; Sohn, H.; Chen, S.; Wang, D. Bottom-Up Synthesis of High Surface Area Mesoporous Crystalline Silicon and Evaluation of Its Hydrogen Evolution Performance Nat. Commun. 2014, 5, 3605 10.1038/ncomms4605
10. Yi, R.; Dai, F.; Gordin, M. L.; Sohn, H.; Wang, D. Influence of Silicon Nanoscale Building Blocks Size and Carbon Coating on the Performance of Micro-Sized Si-C Composite Li-Ion Anodes Adv. Energy. Mater. 2013, 3, 1507-1515 10.1002/aenm.201300496
11. Wada, T.; Ichitsubo, T.; Yubuta, K.; Segawa, H.; Yoshida, H.; Kato, H. Bulk-Nanoporous-Silicon Negative Electrode with Extremely High Cyclability for Lithium-Ion Batteries Prepared Using a Top-Down Process Nano Lett. 2014, 14, 4505-4510 10.1021/nl501500g
12. Luo, W.; Wang, X.; Meyers, C.; Wannenmacher, N.; Sirisaksoontorn, W.; Lerner, M. M.; Ji, X. Efficient Fabrication of Nanoporous Si and Si/Ge Enabled by a Heat Scavenger in Magnesiothermic Reactions Sci. Rep. 2013, 3, 2222 10.1038/srep02222
13. Lin, Y. M.; Klavetter, K. C.; Abel, P. R.; Davy, N. C.; Snider, J. L.; Heller, A.; Mullins, C. B. High Performance Silicon Nanoparticle Anode in Fluoroethylene Carbonate-Based Electrolyte for Li-Ion Batteries Chem. Commun. 2012, 48, 7268-7270 10.1039/c2cc31712e
14. Ryou, M. H.; Kim, J.; Lee, I.; Kim, S.; Jeong, Y. K.; Hong, S.; Ryu, J. H.; Kim, T. S.; Park, J. K.; Lee, H. et al. Mussel-Inspired Adhesive Binders for High-Performance Silicon Nanoparticle Anodes in Lithium-Ion Batteries Adv. Mater. 2013, 25, 1571-1576 10.1002/adma.201203981
15. Zamfir, M. R.; Nguyen, H. T.; Moyen, E.; Lee, Y. H.; Pribat, D. Silicon Nanowires for Li-Based Battery Anodes: A Review J. Mater. Chem. A 2013, 1, 9566-9586 10.1039/c3ta11714f
16. Chan, C. K.; Peng, H. L.; Liu, G.; McIlwrath, K.; Zhang, X. F.; Huggins, R. A.; Cui, Y. High-Performance Lithium Battery Anodes Using Silicon Nanowires Nat. Nanotechnol. 2008, 3, 31-35 10.1038/nnano.2007.411
17. Park, M. H.; Kim, M. G.; Joo, J.; Kim, K.; Kim, J.; Ahn, S.; Cui, Y.; Cho, J. Silicon Nanotube Battery Anodes Nano Lett. 2009, 9, 3844-3847 10.1021/nl902058c
18. Wu, H.; Chan, G.; Choi, J. W.; Ryu, I.; Yao, Y.; McDowell, M. T.; Lee, S. W.; Jackson, A.; Yang, Y.; Hu, L. B. et al. Stable Cycling of Double-Walled Silicon Nanotube Battery Anodes through Solid-Electrolyte Interphase Control Nat. Nanotechnol. 2012, 7, 309-314 10.1038/nnano.2012.35
19. Lu, Z. Y.; Zhu, J. X.; Sim, D. H.; Zhou, W. W.; Ship, W. H.; Hng, H. H.; Yan, Q. Y. Synthesis of Ultrathin Silicon Nanosheets by Using Graphene Oxide as Template Chem. Mater. 2011, 23, 5293-5295 10.1021/cm202891p
20. Kim, W. S.; Hwa, Y.; Shin, J. H.; Yang, M.; Sohn, H. J.; Hong, S. H. Scalable Synthesis of Silicon Nanosheets from Sand as an Anode for Li-Ion Batteries Nanoscale 2014, 6, 4297-4302 10.1039/c3nr05354g
21. Kim, U.; Kim, I.; Park, Y.; Lee, K. Y.; Yim, S. Y.; Park, J. G.; Ahn, H. G.; Park, S. H.; Choi, H. J. Synthesis of Si Nanosheets by a Chemical Vapor Deposition Process and Their Blue Emissions ACS Nano 2011, 5, 2176-2181 10.1021/nn103385p
22. Kim, S. W.; Lee, J.; Sung, J. H.; Seo, D. J.; Kim, I.; Jo, M. H.; Kwon, B. W.; Choi, W. K.; Choi, H. J. Two-Dimensionally Grown Single-Crystal Silicon Nanosheets with Tunable Visible-Light Emissions ACS Nano 2014, 8, 6556-6562 10.1021/nn501683f
23. Sugiyama, Y.; Okamoto, H.; Mitsuoka, T.; Morikawa, T.; Nakanishi, K.; Ohta, T.; Nakano, H. Synthesis and Optical Properties of Monolayer Organosilicon Nanosheets J. Am. Chem. Soc. 2010, 132, 5946-5947 10.1021/ja100919d
24. Okamoto, H.; Kumai, Y.; Sugiyama, Y.; Mitsuoka, T.; Nakanishi, K.; Ohta, T.; Nozaki, H.; Yamaguchi, S.; Shirai, S.; Nakano, H. Silicon Nanosheets and Their Self-Assembled Regular Stacking Structure J. Am. Chem. Soc. 2010, 132, 2710-2718 10.1021/ja908827z
25. Guggenheim, S.; Martin, R. T. Definition of Clay and Clay Mineral-Joint Report of the AIPEA Nomenclature and CMS Nomenclature Committees Clays Clay Miner. 1995, 43, 255-256 10.1346/CCMN.1995.0430213
26. White, J. L. Reactions of Molten Salts with Layer-Lattice Silicates Nature 1954, 174, 799-800 10.1038/174799a0
27. Liu, X. L.; Gao, Y. F.; Jin, R. H.; Luo, H. J.; Peng, P.; Liu, Y. Scalable Synthesis of Si Nanostructures by Lowerature Magnesiothermic Reduction of Silica for Application in Lithium Ion Batteries Nano Energy 2014, 4, 31-38 10.1016/j.nanoen.2013.12.002
28. Liu, M. P.; Li, C. H.; Du, H. B.; You, X. Z. Facile Preparation of Silicon Hollow Spheres and Their Use in Electrochemical Capacitive Energy Storage Chem. Commun. 2012, 48, 4950-4952 10.1039/c2cc17083c
29. Yoo, J. K.; Kim, J.; Choi, M. J.; Park, Y. U.; Hong, J.; Baek, K. M.; Kang, K.; Jung, Y. S. Extremely High Yield Conversion from Low-Cost Sand to High-Capacity Si Electrodes for Li-Ion Batteries Adv. Energy Mater. 2014, 4, 1400622 10.1002/aenm.201400622
30. Ma, X. M.; Liu, M. X.; Gan, L. H.; Tripathi, P. K.; Zhao, Y. H.; Zhu, D. Z.; Xu, Z. J.; Chen, L. W. Novel Mesoporous Si@C Microspheres as Anodes for Lithium-Ion Batteries Phys. Chem. Chem. Phys. 2014, 16, 4135-4142 10.1039/c3cp54507e
31. Patterson, A. L. The Scherrer Formula for X-Ray Particle Size Determination Phys. Rev. 1939, 56, 978-982 10.1103/PhysRev.56.978
32. Wang, R. P.; Zhou, G. W.; Liu, Y. L.; Pan, S. H.; Zhang, H. Z.; Yu, D. P.; Zhang, Z. Raman Spectral Study of Silicon Nanowires: High-Order Scattering and Phonon Confinement Effects Phys. Rev. B: Condens. Matter Mater. Phys. 2000, 61, 16827-16832 10.1103/PhysRevB.61.16827
33. Nie, M. Y.; Abraham, D. P.; Chen, Y. J.; Bose, A.; Lucht, B. L. Silicon Solid Electrolyte Interphase (SEI) of Lithium Ion Battery Characterized by Microscopy and Spectroscopy J. Phys. Chem. C 2013, 117, 13403-13412 10.1021/jp404155y
34. Ogata, K.; Salager, E.; Kerr, C. J.; Fraser, A. E.; Ducati, C.; Morris, A. J.; Hofmann, S.; Grey, C. P. Revealing Lithium-Silicide Phase Transformations in Nano-Structured Silicon-Based Lithium Ion Batteries via In Situ NMR Spectroscopy Nat. Commun. 2014, 5, 3217 10.1038/ncomms4217
35. Obrovac, M. N.; Krause, L. J. Reversible Cycling of Crystalline Silicon Powder J. Electrochem. Soc. 2007, 154, A103-A108 10.1149/1.2402112
36. Chan, C. K.; Ruffo, R.; Hong, S. S.; Huggins, R. A.; Cui, Y. Structural and Electrochemical Study of the Reaction of Lithium with Silicon Nanowires J. Power Sources 2009, 189, 34-39 10.1016/j.jpowsour.2008.12.047
37. Datta, M. K.; Kumta, P. N. In Situ Electrochemical Synthesis of Lithiated Silicon-Carbon Based Composites Anode Materials for Lithium Ion Batteries J. Power Sources 2009, 194, 1043-1052 10.1016/j.jpowsour.2009.06.033
38. Liu, N. A.; Hu, L. B.; McDowell, M. T.; Jackson, A.; Cui, Y. Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries ACS Nano 2011, 5, 6487-6493 10.1021/nn2017167