Reacto-Diffusive Length of N2O5 in Aqueous Sulfate- and Chloride-Containing Aerosol Particles

Journal of Physical Chemistry A

Volumn 120, Issue 7, 2016, Pages 1039-1045

  Gaston, Cassandra J ^a   Thornton, Joel A ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOLS; AIR QUALITY; CHEMICAL REACTIONS; PARTICLE SIZE; PHYSICAL CHEMISTRY; SODIUM; SODIUM CHLORIDE; SODIUM SULFATE; SULFUR COMPOUNDS;

AEROSOL PARTICLES; AMMONIUM BISULFATE; ATMOSPHERIC MODEL; CHEMICAL EQUATIONS; DINITROGEN PENTOXIDE; DISTRIBUTION OF PARTICLES; HETEROGENEOUS REACTIONS; RATE OF CHEMICAL REACTION;

SURFACE REACTIONS;

EID: 84959441140     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/acs.jpca.5b11914     Document Type: Article

References (50)

1. Abbatt, J. P. D.; Lee, A. K. Y.; Thornton, J. A. Quantifying trace gas uptake to tropospheric aerosol: recent advances and remaining challenges Chem. Soc. Rev. 2012, 41, 6555 10.1039/c2cs35052a
2. 3, and OH J. Geophys. Res. 1993, 98, 7149-7163 10.1029/92JD02979
3. Shindell, D. T.; Faluvegi, G.; Koch, D. M.; Schmidt, G. A.; Unger, N.; Bauer, S. E. Improved attribution of climate forcing to emissions Science 2009, 326, 716-718 10.1126/science.1174760
4. 17O) of atmospheric nitrate Atmos. Chem. Phys. 2009, 9, 5043-5056 10.5194/acp-9-5043-2009
5. Liao, H.; Seinfeld, J. H. Global impacts of gas-phase chemistry-aerosol interactions on direct radiative forcing by anthropogenic aerosols and ozone J. Geophys. Res. 2005, 110, D18208 10.1029/2005JD005907
6. Finlayson-Pitts, B. J.; Pitts, J. N. Atmospheric chemistry of tropospheric ozone formation-Scientific and regulatory implications Air Waste 1993, 43, 1091-1100 10.1080/1073161X.1993.10467187
7. Finlayson-Pitts, B. J.; Pitts, J. N. Chemistry of the upper and lower atmosphere: Theory, experiments and applications; Academic Press: San Diego, 2000.
8. 5: A review Aerosol Sci. Technol. 2011, 45, 665-695 10.1080/02786826.2010.551672
9. 5 on aqueous aerosols J. Geophys. Res. 1988, 93, 15889-15896 10.1029/JD093iD12p15889
10. 5 with NaCl solution: Bulk and aerosol experiments J. Geophys. Res. 1997, 102, 3795-3804 10.1029/96JD03057
11. 5 on submicron sulfate aerosols Phys. Chem. Chem. Phys. 2003, 5, 3453-3463 10.1039/b301827j
12. 5 to internally mixed inorganic and organic particles: The role of organic carbon oxidation state and inferred organic phase separations Atmos. Chem. Phys. 2014, 14, 5693-5707 10.5194/acp-14-5693-2014
13. 5 hydrolysis on sulfuric acid and ammonium sulfate aerosols at room temperature J. Phys. Chem. A 1997, 101, 871-878 10.1021/jp9627436
14. 4 aerosols J. Phys. Chem. A 2001, 105, 6465-6470 10.1021/jp010490x
15. 5 reaction on submicron sea salt aerosol: Kinetics, products, and the effect of surface active organics J. Phys. Chem. A 2005, 109, 10004-10012 10.1021/jp054183t
16. 5 reactivity on aqueous particles: the competing effects of particle liquid water, nitrate and chloride Atmos. Chem. Phys. 2009, 9, 8351-8363 10.5194/acp-9-8351-2009
17. Mentel, T. F.; Sohn, M.; Wahner, A. Nitrate effect in the heterogeneous hydrolysis of dinitrogen pentoxide on aqueous aerosols Phys. Chem. Chem. Phys. 1999, 1, 5451-5457 10.1039/a905338g
18. 2 in acidic atmospheric aerosol Science 2008, 321, 1059-1059 10.1126/science.1158777
19. 5 on sodium nitrate aerosol J. Geophys. Res. 1998, 103, 31103-31112 10.1029/1998JD100022
20. 5 by ammonium sulfate aerosol Atmospheric Science Letters 2009, 10, 159-163 10.1002/asl.225
21. 5 on submicron sulfuric acid aerosols J. Phys. Chem. A 2000, 104, 3984-3990 10.1021/jp9939625
22. 5 hydrolysis on sub-micron organic aerosols: the effect of relative humidity, particle phase, and particle size Phys. Chem. Chem. Phys. 2003, 5, 4593-4603 10.1039/b307498f
23. 5 by aerosols containing dicarboxylic acids. Effect of particle phase, composition, and nitrate content J. Phys. Chem. A 2009, 113, 5082-5090 10.1021/jp8096814
24. 2 Nature 1989, 337, 241-244 10.1038/337241a0
25. - containing substrates Geophys. Res. Lett. 2009, 36, L20808 10.1029/2009GL040448
26. Osthoff, H. D.; Roberts, J. M.; Ravishankara, A. R.; Williams, E. J.; Lerner, B. M.; Sommariva, R.; Bates, T. S.; Coffman, D.; Quinn, P. K.; Dibb, J. E. High levels of nitryl chloride in the polluted subtropical marine boundary layer Nat. Geosci. 2008, 1, 324-328 10.1038/ngeo177
27. Riedel, T. P.; Bertram, T. H.; Crisp, T. A.; Williams, E.; Lerner, B.; Vlasenko, A.; Li, S.-M.; Gilman, J.; de Gouw, J.; Bon, D. M. Nitryl chloride and molecular chlorine in the coastal marine boundary layer Environ. Sci. Technol. 2012, 46, 10463 10.1021/es204632r
28. Thornton, J. A.; Kercher, J. P.; Riedel, T. P.; Wagner, N. L.; Cozic, J.; Holloway, J. S.; Dube, W. P.; Wolfe, G. M.; Quinn, P. K.; Middlebrook, A. M. A large atomic chlorine source inferred from mid-continental reactive nitrogen chemistry Nature 2010, 464, 271-274 10.1038/nature08905
29. Simpson, W. R.; Brown, S. S.; Saiz-Lopez, A.; Thornton, J. A.; von Glasow, R. Tropospheric halogen chemistry: Sources, cycling, and impacts Chem. Rev. 2015, 115, 4035-4062 10.1021/cr5006638
30. Saiz-Lopez, A.; von Glasow, R. Reactive halogen chemistry in the troposphere Chem. Soc. Rev. 2012, 41, 6448-6472 10.1039/c2cs35208g
31. Knipping, E. M.; Dabdub, D. Impact of chlorine emissions from sea-salt aerosol on coastal urban ozone Environ. Sci. Technol. 2003, 37, 275-284 10.1021/es025793z
32. 5 J. Phys. Chem. A 2006, 110, 10435-10443 10.1021/jp062403c
33. 5 reaction probabilities on the surface of particles containing ammonium, sulfate, and nitrate Atmos. Chem. Phys. 2008, 8, 5295-5311 10.5194/acp-8-5295-2008
34. Hanson, D. R.; Ravishankara, A. R.; Solomon, S. Heterogeneous reactions in sulfuric-acid aerosols-a framework for model-calculations J. Geophys. Res. 1994, 99, 3615-3629 10.1029/93JD02932
35. Murphy, D. M.; Cziczo, D. J.; Froyd, K. D.; Hudson, P. K.; Matthew, B. M.; Middlebrook, A. M.; Peltier, R. E.; Sullivan, A.; Thomson, D. S.; Weber, R. J. Single-particle mass spectrometry of tropospheric aerosol particles J. Geophys. Res. 2006, 111, D23S32 10.1029/2006JD007340
36. Poschl, U. Atmospheric aerosols: Composition, transformation, climate and health effects Angew. Chem., Int. Ed. 2005, 44, 7520-7540 10.1002/anie.200501122
37. 5 by chemical ionization mass spectrometry Atmos. Meas. Tech. 2009, 2, 193-204 10.5194/amt-2-193-2009
38. 5 reactions on halide-doped ice surfaces Atmos. Chem. Phys. 2012, 12, 5237-5247 10.5194/acp-12-5237-2012
39. 5 to aqueous aerosol Atmos. Chem. Phys. 2006, 6, 1635-1644 10.5194/acp-6-1635-2006
40. 5 reactivity on ambient aerosol particles Geophys. Res. Lett. 2009, 36, L19803 10.1029/2009GL040248
41. 5 reactivity measurements at a polluted coastal site Atmos. Chem. Phys. 2012, 12, 2959-2968 10.5194/acp-12-2959-2012
42. 5 reactivity on ambient particles Atmos. Meas. Tech. 2009, 2, 231-242 10.5194/amt-2-231-2009
43. Gaston, C. J.; Riedel, T. P.; Zhang, Z.; Gold, A.; Surratt, J. D.; Thornton, J. A. Reactive uptake of an isoprene-derived epoxydiol to submicron aerosol particles Environ. Sci. Technol. 2014, 48, 11178-11186 10.1021/es5034266
44. Fuchs, N. A.; Sutugin, A. G. In Topics in current aerosol research; Hidy, G. M.; Brock, J. R., Eds.; Pergamon Press: New York, 1971; pp 1-60.
45. Brown, R. L. Tubular flow reactors with 1st-order kinetics J. Res. Natl. Bur. Stand. 1978, 83, 1-8 10.6028/jres.083.001
46. 5 hydrolysis on secondary organic aerosol and mixed ammonium bisulfate-secondary organic aerosol particles J. Phys. Chem. A 2010, 114, 13113-13121 10.1021/jp107721v
47. 2 measurements from a tall tower in a polluted continental setting J. Geophys. Res.-[Atmos.] 2013, 118, 8702-8715 10.1002/jgrd.50637
48. 2O at 298.15 K J. Phys. Chem. A 1998, 102, 2155-2171 10.1021/jp973043j
49. 2O at tropospheric temperatures J. Phys. Chem. A 1998, 102, 2137-2154 10.1021/jp973042r
50. Kim, M. J.; Farmer, D. K.; Bertram, T. H. A controlling role for the air-sea interface in the chemical processing of reactive nitrogen in the coastal marine boundary layer Proc. Natl. Acad. Sci. U. S. A. 2014, 111, 3943-3948 10.1073/pnas.1318694111