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Volumn 4, Issue , 2008, Pages 88-126

Homogeneous Redox Catalysis in CO2 Fixation

Author keywords

[No Author keywords available]

Indexed keywords

CO2 FIXATION; REDOX CATALYSIS;

EID: 84955375764     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527618248.ch49     Document Type: Chapter
Times cited : (14)

References (107)
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    • 0003471303 scopus 로고    scopus 로고
    • Greenhouse Gas Carbon Dioxide Mitigation
    • Lewis, Boca Raton, FL
    • M. M. Halmann, M. Steinberg, Greenhouse Gas Carbon Dioxide Mitigation, Lewis, Boca Raton, FL, 1999.
    • (1999)
    • Halmann, M.M.1    Steinberg, M.2
  • 2
    • 0012459907 scopus 로고    scopus 로고
    • Advances in Chemical Conversions for Mitigating Carbon Dioxide, Studies in Surface Science and Catalysis
    • Elsevier, Amsterdam
    • T. Inui, M. Anpo, K. Izui, S. Yanagida, T. Yamaguchi (Eds.), Advances in Chemical Conversions for Mitigating Carbon Dioxide, Studies in Surface Science and Catalysis, Vol. 114, Elsevier, Amsterdam, 1998.
    • (1998) , vol.114
    • Inui, T.1    Anpo, M.2    Izui, K.3    Yanagida, S.4    Yamaguchi, T.5
  • 27
    • 33750426563 scopus 로고    scopus 로고
    • Advances in Chemical Conversions for Mitigating Carbon Dioxide, Studies in Surface Science and Catalysis
    • (Eds. T. Inui, M. Anpo, K. Izui, S. Yanagida, T. Yamaguchi), Elsevier, Amsterdam
    • E. Fujita, B. S. Brunschwig, D. Cabelli, M. W. Renner, L. R. Furenlid, T. Ogata, Y. Wada, S. Yanagida, in Advances in Chemical Conversions for Mitigating Carbon Dioxide, Studies in Surface Science and Catalysis, Vol. 114 (Eds. T. Inui, M. Anpo, K. Izui, S. Yanagida, T. Yamaguchi), Elsevier, Amsterdam, 1998, pp. 97-106.
    • (1998) , vol.114 , pp. 97-106
    • Fujita, E.1    Brunschwig, B.S.2    Cabelli, D.3    Renner, M.W.4    Furenlid, L.R.5    Ogata, T.6    Wada, Y.7    Yanagida, S.8
  • 67
    • 84955390768 scopus 로고    scopus 로고
    • personal communication
    • O. Ishitani, personal communication, 1999.
    • (1999)
    • Ishitani, O.1
  • 87
    • 84955367836 scopus 로고    scopus 로고
    • For the complexes considered here, we expect the nuclear configuration of the singlet and triplet MLCT states to be similar. Hence the Stokes shift between the two states is small
    • For the complexes considered here, we expect the nuclear configuration of the singlet and triplet MLCT states to be similar. Hence the Stokes shift between the two states is small.
  • 88
    • 84955395392 scopus 로고    scopus 로고
    • The singlet-triplet and ground-excited state energy differences and the absorption and emission energies are treated as unsigned quantities and taken as positive
    • The singlet-triplet and ground-excited state energy differences and the absorption and emission energies are treated as unsigned quantities and taken as positive.
  • 90
    • 84955346028 scopus 로고    scopus 로고
    • The spherical cavity model requires parameters for the solvent and the cavity to calculate the reorganization energy. The dimensions of the molecule have been obtained from models created in MacSparten. The cavity radius was calculated as where di are the three principle diameters of the molecule (including van der Waals end radius for each atom) and are 7.8, 11.26 and 11.26, respectively, with r = 5.0 Å. The Re atom is placed off center by 1.3 Å and the electron transfer distance is 3.5 Å. The optical (square of the refractive index) and static dielectric constants of the solvent were used.
    • The spherical cavity model requires parameters for the solvent and the cavity to calculate the reorganization energy. The dimensions of the molecule have been obtained from models created in MacSparten. The cavity radius was calculated as where di are the three principle diameters of the molecule (including van der Waals end radius for each atom) and are 7.8, 11.26 and 11.26, respectively, with r = 5.0 Å. The Re atom is placed off center by 1.3 Å and the electron transfer distance is 3.5 Å. The optical (square of the refractive index) and static dielectric constants of the solvent were used.


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