Crystal structure of [Ru(bpy)2(CO)(η1-C(O)OH)]+ (bpy = 2,2′-bipyridine) as a key intermediate in CO2/CO conversion

Chemistry Letters

Volumn , Issue 1, 1996, Pages 27-28

  Toyohara, Kiyotsuna ^a   Nagao, Hirotaka ^a   Adachi, Tomohiro ^b   Yoshida, Toshikatsu ^b   Tanaka, Koji ^a  

^a GRADUATE UNIVERSITY FOR ADVANCED STUDIES   (Japan)

^b Osaka Prefecture University

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20544447483     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.27     Document Type: Article

References (13)

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12. 3, Z = 2, crystal size 0.20 × 0.20 × 0.10 mm. 7599 reflections (6° < θ < 60°), 7275 independent (Rini = 0.061). All measurements were made on a Rigaku AFC5R diffractometer with graphite monochromated Mo-Kα radiation. All calculations were carried out with TEXSAN. Hydrogen atoms were placed in idealized positions and included in the structure factor calculation. The final cycle of full-matrix least-squares refinement was based on 3861 observed reflections (I > 3.00σ(I)) and 352 variable parameters and converged with R = 0.058, Rw= 0.042.
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