Synthesis and reactions of fac-Re(bpy)(CO)3(CH2OR) (R = H, acetyl; bpy = 2,2′-bipyridyl)

Organometallics

Volumn 17, Issue 13, 1998, Pages 2689-2691

  Gibson, Dorothy H ^a   Sleadd, Bradley A ^a   Yin, Xiaolong ^a   Vij, Ashwani ^b  

^a UNIVERSITY OF LOUISVILLE   (United States)

^b UNIVERSITY OF IDAHO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001109512     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980102m     Document Type: Article

References (47)

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16. See, for example: (a) Ishida, H.; Tanaka, K.; Morimoto, M.; Tanaka, T. Organometallics 1986, 5, 724. (b) Tanaka, H.; Nagao, H.; Peng, S.-M.; Tanaka, K. Organometallics 1992, 11, 1450. (c) Tanaka, H.; Tzeng, B.-C.; Nagao, H.; Peng, S.-M.; Tanaka, K. Inorg. Chem. 1993, 32, 1508. (d) Toyohara, K.; Nagao, H.; Adachi, T.; Yoshida, T.; Tanaka, K. Chem. Lett. 1996, 27. (e) Hankka, M.; Kiviaho, J.; Ahlgren, M.; Pakkanen, T. A. Organometallics 1995, 14, 825.
17. See, for example: (a) Ishida, H.; Tanaka, K.; Morimoto, M.; Tanaka, T. Organometallics 1986, 5, 724. (b) Tanaka, H.; Nagao, H.; Peng, S.-M.; Tanaka, K. Organometallics 1992, 11, 1450. (c) Tanaka, H.; Tzeng, B.-C.; Nagao, H.; Peng, S.-M.; Tanaka, K. Inorg. Chem. 1993, 32, 1508. (d) Toyohara, K.; Nagao, H.; Adachi, T.; Yoshida, T.; Tanaka, K. Chem. Lett. 1996, 27. (e) Hankka, M.; Kiviaho, J.; Ahlgren, M.; Pakkanen, T. A. Organometallics 1995, 14, 825.
18. See, for example: (a) Ishida, H.; Tanaka, K.; Morimoto, M.; Tanaka, T. Organometallics 1986, 5, 724. (b) Tanaka, H.; Nagao, H.; Peng, S.-M.; Tanaka, K. Organometallics 1992, 11, 1450. (c) Tanaka, H.; Tzeng, B.-C.; Nagao, H.; Peng, S.-M.; Tanaka, K. Inorg. Chem. 1993, 32, 1508. (d) Toyohara, K.; Nagao, H.; Adachi, T.; Yoshida, T.; Tanaka, K. Chem. Lett. 1996, 27. (e) Hankka, M.; Kiviaho, J.; Ahlgren, M.; Pakkanen, T. A. Organometallics 1995, 14, 825.
19. See, for example: (a) Ishida, H.; Tanaka, K.; Morimoto, M.; Tanaka, T. Organometallics 1986, 5, 724. (b) Tanaka, H.; Nagao, H.; Peng, S.-M.; Tanaka, K. Organometallics 1992, 11, 1450. (c) Tanaka, H.; Tzeng, B.-C.; Nagao, H.; Peng, S.-M.; Tanaka, K. Inorg. Chem. 1993, 32, 1508. (d) Toyohara, K.; Nagao, H.; Adachi, T.; Yoshida, T.; Tanaka, K. Chem. Lett. 1996, 27. (e) Hankka, M.; Kiviaho, J.; Ahlgren, M.; Pakkanen, T. A. Organometallics 1995, 14, 825.
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23. 3OD): δ 203.98, 194.44, 156.59, 153.74, 139.24, 127.80, 124.68, 70.05.
24. 3CN): δ 203.06, 194.37, 171.70, 156.29, 153.89, 139.52, 127.96, 124.40, 69.33, 20.98.
25. 1/n; a = 9.7402(2) A, b = 15.8826(4) A°, c = 11.2409(2) A°, α= 90°, β= 107.905(1)°, γ= 90°. Final R indices (I > 2σ(I)): R1 = 0.0390, wR2 = 0.0768.
26. Additional commentary about the structure and ORTEP packing diagrams are available in the Supporting Information.
27. 3OD): δ 199.97, 194.26, 157.50, 154.07, 141.24, 128.60, 125.07, 61.60.
28. 12
29. SHELXTL 5.03 (PC-version), Program Library for Structure Solution and Molecular Graphics; Siemens Analytical Instruments Division: Madison, WI, 1995.
30. 4, the formaldehyde hemiacetal is present in low yield (diminished by partial removal with solvent).
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40. 4; after filtration, the filtrate was concentrated to 20 mL. Hexane was then added to effect precipitation of 0.34 g (83% yield) of 5.
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42. 1H NMR showed an acetoxy methyl resonance at δ 1.91 and resonances for bipyridyl protons which are distinct from 6; the ratio of the two compounds was 2:1 of the unknown to 6). Continued photolysis, or evaporation of solvent and redissolution, resulted in conversion of the second compound to 6. Samples were too dilute to provide meaningful IR spectral data.
43. 2 had identical spectral properties.
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