Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments

Chemical Geology

Volumn 393-394, Issue , 2015, Pages 26-35

  Bia, G ^a   Borgnino, L ^a   Gaiero, D ^a   Garcia M G ^a  

^a UNIVERSIDAD NACIONAL DE CÓRDOBA   (Argentina)

Author keywords

Al silicate glass; As solid speciation; South America; XPS

Indexed keywords

ALUMINUM; ARSENIC; CHEMICAL ANALYSIS; GLASS; IRON COMPOUNDS; SILICATES; VOLCANOES; X RAY PHOTOELECTRON SPECTROSCOPY;

AQUATIC ENVIRONMENTS; BATCH EXPERIMENTS; CHEMICAL COMPOSITIONS; INTEGRATED ANALYSIS; MINERALOGICAL CHARACTERIZATION; NEAR SURFACE REGIONS; SILICATE GLASS; SOUTH AMERICA;

ARSENIC COMPOUNDS;

ARSENIC; CHEMICAL COMPOSITION; ELEMENT MOBILITY; MINERALOGY; SPECIATION (CHEMISTRY); VOLCANIC ASH; X-RAY SPECTROSCOPY;

AISEN; ANDES; CHAITEN VOLCANO; CHILE; LOS LAGOS; MOUNT HUDSON; PUYEHUE; SOUTHERN VOLCANIC ZONE;

EID: 84949117111     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2014.10.007     Document Type: Article

References (67)

1. Abraitis P.K., Pattrick R.A.D., Vaughan D.J. Variations in the compositional, textural and electrical properties of natural pyrite: a review. Int. J. Miner. Process. 2004, 74:41-59.
2. Africano F., Bernard A. Acid alteration in the fumarolic environment of Usu volcano, Hokkaido, Japan. J. Volcanol. Geotherm. Res. 2000, 97:475-495.
3. Allard P., Aiuppa A., Loyer H., Carrot F., Gaudry A., Pinte G., Michel A., Dongarra G. Acid gas and metal emission rates during long-lived basalt degassing at Stromboli volcano. Geophys. Res. Lett. 2000, 27:1207-1210.
4. Aradóttir E.S.P., Sigfússon B., Sonnenthal E.L., Björnsson G., Jónsson H. Dynamics of basaltic glass dissolution - capturing microscopic effects in continuum scale models. Geochim. Cosmochim. Acta 2013, 121:311-327.
5. 2-bearing solutions. Chem. Geol. 2010, 273:272-285.
6. Berger G., Schott J., Loubet M. Fundamental processes controlling the 1st stage of alteration of a basalt glass by seawater - an experimental study between 200 and 320°C. Chem. Geol. 1987, 71:297-312.
7. Biesinger M.C., Payne B.P., Grosvenor A.P., Lau L.W.M., Gerson A.R., Smart R.St.C. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl. Surf. Sci. 2011, 257:2717-2730.
8. Borisova A.Y., Pokrovski G.S., Pichavant M., Freydier R., Candaudap F. Arsenic enrichment in hydrous peraluminous melts: Insights from femtosecond laser ablation-inductively coupled plasma-quadrupole mass spectrometry, and in situ X-ray absorption fine structure spectroscopy. Am. Mineral. 2010, 95:1095-1104.
9. Carn S.A., Pallister J.S., Lara L., Ewert J.W., Prata A.J., Thomas R.J., Villarosa G. The unexpected awakening of Chaitén Volcano, Chile. EOS Trans. Am. Geophys. Union 2009, 90:205-212.
10. Chouinard A., Paquette J., Williams-Jones A.E. Crystallographic controls on trace-element incorporation in auriferous pyrite from the Pascua epithermal high-sulfidation deposit, Chile-Argentina. Can. Mineral. 2005, 43:951-963.
11. Costa M.C., Botelho do Rogo A.M., Abrantes L.M. Characterisation of a natural and an electro-oxidised arsenopyrite: a study on electrochemical and X-ray photoelectron spectroscopy. Int. J. Miner. Process. 2002, 65:83-108.
12. Courtin-Nomade A., Bril H., Bény J., Kunz M., Tamura N. Sulfide oxidation observed using micro-Raman spectroscopy and micro-X-ray diffraction: the importance of water/rock ratios and pH conditions. Am. Mineral. 2010, 95:582-591.
13. Crovisier J.L., Advocat T., Dussossoy J.L. Nature and role of natural alteration gels formed on the surface of ancient volcanic glasses (natural analogues of waste containment glasses). J. Nucl. Mater. 2003, 321:91-109.
14. Daga R., Ribeiro Guevara S., Poire D.G., Arribére M. Characterization of tephras dispersed by the recent eruptions of volcanoes Calbuco (1961), Chaitén (2008) and Cordón Caulle Complex (1960 and 2011), in Northern Patagonia. J. S. Am. Earth Sci. 2014, 49:1-14.
15. Daux V., Guy C., Advocat T., Crovisier J.L., Stille P. Kinetic aspects of basaltic glass dissolution at 90°C: role of aqueous silicon and aluminium. Chem. Geol. 1997, 142:109-126.
16. Declercq J., Diedrich T., Perrot M., Gislason S.R., Oelkers E.H. Experimental determination of rhyolitic glass dissolution rates at 40-200°C and 2
17. Deditius A.P., Utsunomiya S., Renock D., Ewing R.C., Ramana C.V., Becker U., Kesler S.E. A proposed new type of arsenian pyrite: composition, nanostructure and geological significance. Geochim. Cosmochim. Acta 2008, 72:2919-2933.
18. Delmelle P., Lambert M., Dufrene Y., Gerin P., Oskarsson N. Gas/aerosol-ash interaction in volcanic plumes: new insights from surface analyses of fine ash particles. Earth Planet. Sci. Lett. 2007, 259:159-170.
19. Descostes M., Mercier F., Thromat N., Beaucaire C., Gautier-Soyer M. Use of XPS in the determination of chemical environment and oxidation state of iron and sulfur samples: constitution of a data basis in binding energies for Fe and S reference compounds and applications to the evidence of surface species of an oxidized pyrite in a carbonate medium. Appl. Surf. Sci. 2000, 165:288-302.
20. Eggleston C.M., Ehrhardt J.J., Stumm W. Surface structural controls on pyrite oxidation kinetics: an XPS-UPS, STM, and modeling study. Am. Mineral. 1996, 81:1036-1056.
21. Fleet M.E., Mumin A.H. Gold-bearing arsenian pyrite and marcasite and arsenopyrite from Carlin Trend gold deposits and laboratory synthesis. Am. Mineral. 1997, 82:182-193.
22. Fleet M.E., MacLean P.J., Barbier J. Oscillatory-zoned As-bearing pyrite from strata-bound and stratiform gold deposits: an indicator of ore fluid evolution. Econ. Geol. Monogr. 1989, 6:356-382.
23. Folch A., Jorba O., Viramonte J. Volcanic ash forecast application to the May 2008 Chaitén eruption. Nat. Hazards Earth Syst. Sci. 2008, 8:927-940.
24. Fullston D., Fornasiero D., Ralston J. Oxidation of synthetic and natural samples of enargite and tennantite: 2. X-ray photoelectron spectroscopic study. Langmuir 1999, 15:4530-4536.
25. Garcia M.G., Borgnino L., Bia G., Depetris P.J. Mechanisms of arsenic and fluoride release from Chacopampean sediments (Argentina). Int. J. Environ. Health 2014, 7:41-57.
26. Gislason S.R., Oelkers E.H. The mechanism, rate and consequence of basaltic glass dissolution: II. An experimental study of the dissolution rates of basalts as a function of pH at temperatures from 6°C to 150°C. Geochim. Cosmochim. Acta 2003, 67:3817-3832.
27. Gislason S.R., Hassenkam T., Nedel S., Bovet N., Eiriksdottir E.S., Alfredsson H.A., Hem C.P., Balogh Z.I., Dideriksen K., Oskarsson N., Sigfusson B., Larsen G., Stipp S.L.S. Characterization of Eyjafjallajökull volcanic ash particles and a protocol for rapid risk assessment. Proc. Natl. Acad. Sci. U. S. A. 2011, 108:7307-7312.
28. González-Ferrán O. Volcanes de Chile: Instituto Geográfico Militar, Santiago, Chile 1995, (639 pp.).
29. Gout R., Oelkers E.H., Schott J., Zwick A. The surface chemistry and structure of acid leached albite: new insights on the dissolution mechanism of the alkali feldspars. Geochim. Cosmochim. Acta 1997, 61:3013-3018.
30. Guy C., Schott J. Multisite surface reaction versus transport control during the hydrolysis of a complex oxide. Chem. Geol. 1989, 78:181-204.
31. James-Smith J., Cauzid J., Testemale D., Liu W., Hazemann J.-L., Proux O., Etschmann B., Philippot P., Banks D., Williams P., Brugger J. Arsenic speciation in fluid inclusions using micro-beam X-ray absorption spectroscopy. Am. Mineral. 2010, 95:921-932.
32. Jones M.T., Gislason S.R. Rapid releases of metal salts and nutrients following the deposition of volcanic ash into aqueous environments. Geochim. Cosmochim. Acta 2008, 72:3661-3680.
33. Kim E.J., Yoo J.-C., Baek K. Arsenic speciation and bioaccessibility in arsenic-contaminated soils: sequential extraction and mineralogical investigation. Environ. Pollut. 2014, 186:29-35.
34. Kolker A., Haack S.K., Cannon W.F., Westjohn D.B., Kim M.J., Nriagu J., Woodruff L.G. Arsenic in southeastern Michigan. Arsenic in Ground Water 2003, 281-294. Kluwer Academic Publishers, Boston. A.H. Welch, K.G. Stollenwerk (Eds.).
35. Lara L.E. The 2008 eruption of Chaiten Volcano, Chile: a preliminary report. Andean Geol. 2009, 36:125-129.
36. Le Maitre R.W. A proposal by the IUGS Subcommission on the Systematics of Igneous Rocks for a chemical classification of volcanic rocks based on the total alkali silica (TAS) diagram. Aust. J. Earth Sci. 1984, 31(2):243-255.
37. Martin R.S., Watt S.F.L., Pyle D.M., Mather T.A., Matthews N.E. Environmental effects of ashfall in Argentina from the 2008 Chaitén volcanic eruption. J. Volcanol. Geotherm. Res. 2009, 184:462-472.
38. Martin R.S., Wheeler J.C., Ilyinskaya E., Braban C.F., Oppenheimer C. The uptake of halogen (HF, HCl, HBr and HI) and nitric (HNO3) acids into acidic sulphate particles in quiescent volcanic plumes. Chem. Geol. 2012, 296-297:19-25.
39. McIntyre N.S., Zetaruk D.G. X-ray photoelectron spectroscopic studies of iron oxides. Anal. Chem. 1977, 49:1521-1529.
40. Mills P., Sullivan J.L. A study of the core level electrons in iron and its three oxides by means of X-ray photoelectron spectroscopy. J. Phys. D. Appl. Phys. 1983, 16:723-732.
41. Nesbitt H.W., Muir I.J. Oxidation states and speciation of secondary products on pyrite and arsenopyrite reacted with mine waste waters and air. Mineral. Petrol. 1998, 62:123-144.
42. Nesbitt H.W., Muir I.J., Pratt A.R. Oxidation of arsenopyrite by air and air-saturated, distilled water and implications for mechanisms of oxidation. Geochim. Cosmochim. Acta 1995, 59:1773-1786.
43. Nicolli H.B., Bundschuh J., Blanco M.del C., Tujchneider O.C., Panarello H.O., Dapeña C., Rusansky J.E. Arsenic and associated trace-elements in groundwater from the Chaco-Pampean plain, Argentina: results from 100years of research. Sci. Total Environ. 2012, 429:36-56.
44. Oelkers E.H., Gislason S.R. The mechanism, rates, and consequences of basaltic glass dissolution: I. An experimental study of the dissolution rates of basaltic glass as a function of aqueous Al, Si, and oxalic acid concentration at 25°C and pH=3 and 11. Geochim. Cosmochim. Acta 2001, 65:3703-3719.
45. Oelkers E.H., Golubev S.V., Chairat C., Pokrovsky O.S., Schott J. The surface chemistry of multi-oxide silicates. Geochim. Cosmochim. Acta 2009, 73:4617-4634.
46. Oskarsson N. The interaction between volcanic gases and tephra: fluorine adhering to tephra of the 1970 Hekla eruption. J. Volcanol. Geotherm. Res. 1980, 8:51-266.
47. Pals D.W., Spry P.G., Chryssoulis S. Invisible gold and tellurium in arsenic-rich pyrite from the Emperor gold deposit, Fiji: implications for gold distribution and deposition. Econ. Geol. 2003, 98:479-493.
48. Pokrovski G.S., Zakirov I.V., Roux J., Testemale D., Hazemann J.L., Bychkov A.Y., Golikova G.V. Experimental study of arsenic speciation in vapor phase to 500°C: implications for As transport and fractionation in low-density crustal fluids and volcanic gases. Geochim. Cosmochim. Acta 2002, 66:3453-3480.
49. Reich M., Kesler S.E., Utsunomiya S., Palenik C.S., Chryssoulis S.L., Ewing R.C. Solubility of gold in arsenian pyrite. Geochim. Cosmochim. Acta 2005, 69:2781-2796.
50. Rose W.I. Scavenging of volcanic aerosol by ash: atmospheric and volcanologic implications. Geology 1977, 5:621-624.
51. Rose W.I., Chuan R.L., Cadle R.D., Wood D.C. Small particles in volcanic eruption clouds. Am. J. Sci. 1980, 280:671-696.
52. Ruggieri F., Saavedra J., Fernandez-Turiel J.L., Gimeno D., Garcia-Valles M. Environmental geochemistry of ancient volcanic ashes. J. Hazard. Mater. 2010, 183:353-365.
53. Savage K.S., Tingle T.N., O'Day P.A., Waychunas G.A., Bird D.K. Arsenic speciation in pyrite and secondary weathering phases, Mother Lode gold district. Tuolumne County, California. Appl. Geochem. 2000, 15:1219-1244.
54. Scasso R., Corbella H., Tiberi P. Sedimentological analysis of the tephra from the 12-15 August 1991 eruption of Hudson volcano. Bull. Volcanol. 1994, 56:121-132.
55. Schaufuss A.G., Nesbitt H.W., Sciani M.J., Hoecsht H., Bancroft M.G., Szargan R. Reactivity of surface sites on fractured arsenopyrite (FeAsS) toward oxygen. Am. Mineral. 2000, 85:1754-1766.
56. Simon G., Huang H., Penner-Hahn J.E., Kesler S.E., Kao L.-S. Oxidation state of gold and arsenic in gold-bearing arsenian pyrite. Am. Mineral. 1999, 84:1071-1079.
57. Stewart C., Johnston D.M., Leonard G.S., Horwell C.J., Thordarson T., Cronin S.J. Contamination of water supplies by volcanic ashfall: a literature review and simple impact modeling. J. Volcanol. Geotherm. Res. 2006, 158:296-306.
58. Taylor P.S., Stoiber R.E. Soluble material on ash from active Central American volcanoes. Geol. Soc. Am. Bull. 1973, 84:1031-1041.
59. 3 molecule in high temperature aqueous solutions: an X-ray absorption investigation. J. Chem. Phys. 2004, 121:8973-8982.
60. Thomassin J.H., Touray J.C. Early stages of water-basaltic glass interaction - X-ray photo-electrons spectroscopy (XPS) and scanning electron-microscopy (SEM) investigations. Bull. Miner. 1979, 102:594-599.
61. Tilling R.I. Volcanism and associated hazards: the Andean perspective. Adv. Geosci. 2009, 22:125-137.
62. Watt S.F.L., Pyle D.M., Mather T.A., Martin R.S., Matthews N.E. Fallout and distribution of volcanic ash over Argentina following the May 2008 explosive eruption of Chaitén, Chile. J. Geophys. Res. 2009, 114:B04207. 10.1029/2008JB006219.
63. Wells J.D., Mullens T.E. Gold-bearing arsenian pyrite determined by microprobe analysis, Cortez and Carlin gold mines, Nevada. Econ. Geol. 1973, 68:187-201.
64. Witham C.S., Oppenheimer C., Horwell C.J. Volcanic ash-leachates: a review and recommendations for sampling methods. J. Volcanol. Geotherm. Res. 2005, 141:299-326.
65. Wolff-Boenisch D., Gislason S.R., Oelkers E.H., Putnis C.V. The dissolution rates of natural glasses as a function of their composition at pH4 and 10.6, and temperatures from 25 to 74°C. Geochim. Cosmochim. Acta 2004, 68:4843-4858.
66. Wolff-Boenisch D., Gislason S.R., Oelkers E.H. The effect of fluoride on the dissolution rates of natural glasses at pH4 and 25°C. Geochim. Cosmochim. Acta 2004, 68:4571-4582.
67. Zachariáš J., Frýda J., Paterová B., Mihalievič M. Arsenopyrite and As-bearing pyrite from the Roudný deposit, Bohemian Massif. Mineral. Mag. 2004, 68:31-46.