Kinetic aspects of basaltic glass dissolution at 90°c: Role of aqueous silicon and aluminium

Chemical Geology

Volumn 142, Issue 1-2, 1997, Pages 109-126

  Daux, Valérie ^a,d   Christophe, Guy ^a   Advocat, Thierry ^b   Crovisier, Jean Louis ^c   Stille, Peter ^c  

^a CEA DIF   (France)

^b CEN Valrhô / SCD / SEMC ^*  (France)

^c CNRS   (France)

^d SORBONNE UNIVERSITÉ   (France)

Author keywords

Chemical affinity; Dissolution; Glass; Kinetic

Indexed keywords

EID: 0000501609     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(97)00079-X     Document Type: Article

References (93)

1. Aagaard, P., Helgeson, H.C., 1982. Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions, I. Theoretical considerations. Am. J. Sci. 282, 237-285.
2. Advocat, T., 1991. Les mécanismes de corrosion en phase aqueuse du verre nucléaire R7T7. Approche expérimentale. Essai de modélisation thermodynamique et cinétique. PhD thesis, Univ. Strasbourg, 228 pp. (registered at the Soc. Geol. France).
3. Advocat, T., Crovisier, J.L., Fritz, B., Vernaz, E., 1990. Thermokinetic model of borosilicate glass dissolution: contextual affinity. In: Oversby, V.M., Brown, P.W. (Eds.), Scientific Basis for Nuclear Waste Management XIII, Mater. Res. Soc. Symp. Proc. 176, Pittsburgh, Penn., pp. 241-248.
4. Allen, C., 1982. Stability and alteration of naturally occurring low-silica glasses: implications for the long term stability of waste form glasses. In: Lutze, W. (Ed.), Scientific Basis for Nuclear Waste Management V, Mater. Res. Soc. Symp. Proc. 11, Berlin, pp. 37-44.
5. Amrhein, C., Suarez, D.L., 1988. The use of a surface complexation model to describe the kinetics of ligand-promoted dissolution of anorthite. Geochim. Cosmochim. Acta 52, 2785-2793.
6. Amrhein, C., Suarez, D.L., 1992. Some factors affecting the dissolution kinetics of anorthite at 25°C. Geochim. Cosmochim. Acta 56, 1815-1826.
7. Anbeek, C., 1992. The dependence of dissolution rates on grain size for some fresh and weathered feldspars. Geochim. Cosmochim. Acta 56, 3957-3970.
8. Anbeek, C., 1993. The effect of natural weathering on dissolution rates. Geochim. Cosmochim. Acta 57, 4963-4975.
9. Bennett, P.C., 1991. Quartz dissolution in organic-rich aqueous systems. Geochim. Cosmochim. Acta 55, 1781-1797.
10. Berger, G., Schott, J., Loubet, M., 1987. Fundamental processes controlling the first stage of alteration of a basalt glass by seawater: an experimental study between 200°C and 320°C. Earth Planet. Sci. Lett. 84, 431-445.
11. Berger, G., Schott, J., Guy, C., 1988. Behavior of Li, Rb and Cs during basalt glass dissolution and chlorite, smectite and zeolite precipitation from seawater: experimental investigations and modelization between 50° and 300°C. Chem. Geol 71, 297-312.
12. Berger, G., Gadore, E., Schott, J., Dove, M.P., 1994a. Dissolution rate of quartz in Pb and Na electrolyte solutions. Effect of interaction pattern and reaction affinity. Geochim. Cosmochim. Acta 58, 541-552.
13. Berger, G., Claparols, C., Guy, C., Daux, V., 1994b. Dissolution rate of basalt glass in silica rich solution. Consequences for the long term. Geochim. Cosmochim. Acta 58, 4875-4886.
14. Berner, R.A., 1978. Rate control of mineral dissolution under earth surface conditions. Am. J. Sci. 278, 1235-1252.
15. Bertrand, C., Cattin, R., Guy, C., 1997. Reactive surface area determination of a rock in its natural environment: chemical approach and application to the Mururoa basaltic massif. Chem. Geol. (in press).
16. Blum, A.E., Lasaga, A.C., 1988. Role of surface speciation in the low-temperature dissolution of minerals. Nature 331, 431-433.
17. Blum, A.E., Lasaga, A.C., 1991. The role of surface speciation in the dissolution of albite. Geochim. Cosmochim. Acta 55, 2193-2201.
18. Bourcier, W.L., 1989. Improvements in the solid solution modelling capabilities of the EQ3/6 geochemical code. Lawrence Livermore National Laboratory, Livermore, California, UCID-20587.
19. Bourcier, W.L., Peiffer, D.W., Knauss, K.G., Mc Keegan, K.D., Smith, D.K., 1990. A kinetic model for borosilicate glass dissolution based on the dissolution affinity of a surface alteration layer. In: Oversby, V.M., Brown, P.W. (Eds.), Scientific Basis for Nuclear Waste Management XIII, Mater. Res. Soc. Symp. Proc. 176, Pittsburgh, Penn., pp. 120-127.
20. Brady, P.V., 1992. Silica surface chemistry at elevated temperatures. Geochim. Cosmochim. Acta 56, 2941-2946.
21. Brady, P.V., Walther, J.V., 1989. Controls on silicate dissolution rates in neutral and basic pH solutions at 25°C. Geochim. Cosmochim. Acta 53, 2823-2830.
22. Burch, T.E., Nagy, K.L., Lasaga, A.C., 1993. Free energy dependence of albite dissolution kinetics at 80°C and pH 8.8. Chem. Geol. 105, 137-162.
23. Caroll-Webb, S.A., Walther, J.V., 1988. A surface complex reaction model for the pH dependence of corundum and kaolinite dissolution. Geochim. Cosmochim. Acta 52, 2609-2623.
24. Casey, W.H., Westrich, H.R., 1992. Control of dissolution rates of orthosilicate minerals by metal-oxygen bonds. Nature (London) 355, 157-159.
25. Casey, W.H., Westrich, H.R., Holdren, G.R., 1991. Dissolution rates of plagioclase at pH = 2 and 3. Am. Mineral. 71, 211-217.
26. Chou, L., Wollast, R., 1985. Steady-state kinetics and dissolution mechanism of albite. Am. J. Sci. 285, 963-993.
27. Crovisier, J.L., Eberhart, J.P., 1985. Apport de la microscopie électronique à l'étude des couches d'altération formées à la surface des verres. J. Microsc. Spectrosc. Electron. 10, 171-180.
28. Crovisier, J.L., Thomassin, J.H., Juteau, T., Eberhart, J.P., Touray, J.C., Baillif, P., 1983. Experimental seawater-basaltic glass interaction at 50°C: study of early developed phases by electron microscopy and X-ray photoelectron spectrometry. Geochim. Cosmochim. Acta 47, 377-387.
29. Crovisier, J.L., Fritz, B., Grambow, B., Eberhart, J.P., 1985. Dissolution of basaltic glass in seawater: experiments and thermodynamic modelling. In: Werme, L.O. (Ed.), Scientific Basis for Nuclear Waste Management VIII, Mater. Res. Soc. Symp. Proc. 50, Stockholm, pp. 273-280.
30. Crovisier, J.L., Honnorez, J., Eberhart, J.P., 1987. Dissolution of basaltic glass in seawater: mechanism and rate. Geochim. Cosmochim. Acta 51, 2977-2990.
31. Crovisier, J.L., Atassi, H., Daux, V., Eberhart, J.P., 1990. Hydrolyse d'un verre basaltique tholéiitique à 60°C. Dissolution sélective puis congruente par élévation de pH. C.R. Acad. Sci. Paris 310, II, 941-946.
32. Crovisier, J.L., Honnorez, J., Fritz, B., Petit, J.C., 1992. Dissolution of subglacial volcanic glasses from Iceland: laboratory study and modelling. Appl. Geochem., Suppl. Iss. 1, 55-81.
33. Daux, V., Crovisier, J.L., Hemond, C., Petit, J.C., 1994. Geochemical evolution of a basaltic rock submitted to weathering: fate of the major elements, rare earth elements and thorium. Geochim. Cosmochim. Acta 58, 4941-4954.
34. Devidal, J.L., Dandurand, J.L., Schott, J., 1992. Dissolution and precipitation kinetics of kaolinite as a function of chemical affinity (T = 150°C, pH = 2 and 7.8). In: Kharaka, Y.K., Maest, A.S. (Eds.), Water Rock Interaction. Balkema, Dordrecht, pp. 93-96.
35. Dibble, W.E., Tiller, W.A., 1981. Non-equilibrium water-rock interactions, I. Model for interface controlled reactions. Geochim. Cosmochim. Acta 45, 79-92.
36. Douglas, R.W., Isard, J.O., 1949. The reaction of water and sulfur dioxide on glass surfaces. J. Soc. Glass Technol. 33, 289-335.
37. Dove, M.P., 1994. The dissolution kinetics of quartz in sodium chloride solutions at 25 to 300°C. Am. J. Sci. 294, 665-712.
38. Dove, P.M., Crerar, D.A., 1990. Kinetics of quartz dissolution in electrolyte solutions using a hydrothermal mixed flow reactor. Geochim. Cosmochim. Acta 54, 955-969.
39. Eick, M.J., Grossl, P.R., Golden, D.C., Sparks, D.L., Ming, D.W., 1996. Dissolution kinetics of a lunar glass simulant at 25°C: the effect of pH and organic acids. Geochim. Cosmochim. Acta 60, 157-170.
40. Ewing, R.C., Jercinovic, M.J., 1987. Natural analogues: their application to the prediction of the long-term behaviour of nuclear waste forms. In: Bates, J.K., Seefeldt, W.B. (Eds.), Scientific Basis for Nuclear Waste Management X, Mater. Res. Soc. Symp. Proc. 89 Pittsburgh, Penn., pp. 67-86.
41. Furrer, G., Zysset, M., Schindler, P.W., 1993. Weathering kinetics of montmorillonite: investigations in batch and mixed flow reactors. In: Manning, D.D.C. et al. (Eds.), Geochemistry of Clay-Pore Fluid Interactions. Chapman and Hall, London, pp. 243-262.
42. Ganor, J., Mogollon, J.L., Lasaga, A.C., 1995. The effect of pH on kaolinite dissolution rates and on activation energy. Geochim. Cosmochim. Acta 59, 1037-1052.
43. 2 glasses. J. Am. Ceram. Soc. 68, 376-379.
44. Gautier, J.-M., Oelkers, E.H., Schott, J., 1994. Experimental study of K-feldspar dissolution rates as a function of chemical affinity at 150°C and pH = 9. Geochim. Cosmochim. Acta 58, 4549-4560.
45. Ghiara, M.R., Franco, E., Petti, C., Stanzione, D., Valentino, G.M., 1993. Hydrothermal interaction between basaltic glass, deionized water and seawater. Chem. Geol. 104, 125-138.
46. Gíslason, S.R., Arnórson, S., 1993. Dissolution of primary basaltic minerals in natural waters: saturation state and kinetics. Chem. Geol. 105, 117-135.
47. Gíslason, S.R., Eugster, H.P., 1987. Meteoric water-basalt interactions, I. A laboratory study. Geochim. Cosmochim. Acta 51, 2827-2840.
48. Grambow, B., 1985. A general rate equation for nuclear waste glass corrosion. In: Jantzen, C.M. et al. (Eds.), Scientific Basis for Nuclear Waste Management VIII. Mater. Res. Soc. Proc., 44, pp. 15-27.
49. Gratz, A.J., Bird, P., 1993. Quartz dissolution: negative crystal experiments and a rate law. Geochim. Cosmochim. Acta 57, 965-976.
50. Guy, C., 1989. Mécanismes de dissolution des solides dans les solutions hydrothermales déduits du comportement de verres basaltiques et de calcites déformées. PhD thesis, Toulouse University.
51. Guy, C., Schott, J., 1989. Multisite surface reaction versus transport control during the hydrolysis of a complex oxide. Chem. Geol. 78, 181-204.
52. Helgeson, H.C., Kirkham, D.H., 1974a. Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures, I. Summary of the thermodynamics/electrostatic properties of the solvant. Am. J. Sci. 274, 1089-1198.
53. Helgeson, H.C., Kirkham, D.H., 1974b. Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures, II. Debye-Hückel parameters for activity coefficients and relative partial molal properties. Am. J. Sci. 274, 1199-1261.
54. Helgeson, H.C., Delany, J.M., Nesbitt, H.W., Bird, D.K., 1978. Summary and critique of the thermodynamic properties of rock-forming minerals. Am. J. Sci. 278, 1-229.
55. Helgeson, H.C., Kirkham, D.H., Flowers, G.C., 1981. Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures, IV. Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600°C and 5 kb. Am. J. Sci. 281, 1249-1516.
56. Helgeson, H.C., Murphy, W.M., Aagaard, P., 1984. Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solution. Geochim. Cosmochim. Acta 48, 2405-2432.
57. Hellmann, R., 1994, The albite-water system, Part I. The kinetics of dissolution as a function of pH at 100, 200 and 300°C. Geochim. Cosmochim. Acta 58, 595-611.
58. Hellmann, R., 1995. The albite-water system, Part II. The time evolution of the stoichiometry of dissolution as a function of pH at 100, 200, and 300°C. Geochim. Cosmochim. Acta 59, 1669-1697.
59. Huang, W.L., Longo, J.M., 1992. The effect of organics on feldspar dissolution and the development of secondary porosity. Chem. Geol. 98, 271-292.
60. Kirkwood, D.E., Nesbitt, H.G., 1991. Formation and evolution of soils from an acidified watershed, Plastic Lake, Ontario, Canada. Geochim. Cosmochim. Acta 55, 1295-1308.
61. 2, temperature and time. Geochim. Cosmochim. Acta 57, 285-294.
62. Lasaga, A.C., 1981. Transition state theory. In: Lasaga A.C., Kirkpatrick, R.J. (Eds.), Kinetics of Geochemical Processes. Reviews in Mineralogy 8. Mineralogical Society of America, pp. 1-68.
63. Lutze, W., Mallow, G., Ewing, R.C., Jercinovic, M.J., Keil, K., 1985. Alteration of basalt glasses: implications for modelling the long-term stability of nuclear waste glasses. Nature 314, 252-255.
64. Ménard, O., Advocat, T., Michard, A., 1995. Comportement des terres rares et des actinides en solution lors de l'altération aqueuse du verre nucléaire R7T7 à 90°C: étude en système dynamique. C.R. Acad. Sci. Paris, 321, II, 17-23.
65. Muir, I.J., Nesbitt, H.W., 1991. Effects of aqueous cations on the dissolution of labradorite feldspar. Geochim. Cosmochim. Acta 55, 3181-3189.
66. Muir, I.J., Nesbitt, H.W., 1992. Controls on differential leaching of calcium and aluminum from labradorite in dilute electrolyte solutions. Geochim. Cosmochim. Acta 56, 3979-3985.
67. Murphy, W.M., Helgeson, H.C., 1989. Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions, IV. Retrieval of rate constants and activation parameters for the hydrolysis of pyroxene, wollastonite, olivine, andalusite and quartz. Am. J. Sci. 289, 17-101.
68. Murphy, W.M., Oelkers, E.H., Lichtner, C., 1989. Surface reaction versus diffusion control of mineral dissolution and growth rates in geochemical processes. Chem. Geol. 78, 357-380.
69. Murphy, W.M., Pabalan, R., Prikryl, J.D., Goulet, C.J., 1992. Dissolution rate and solubility of analcime at 25°C. In: Kharaka, Y.K., Maest, A.S. (Eds.), Water Rock Interaction Balkema, Dordrecht, pp. 107-110.
70. Nagy, K.L., Lasaga, A.C., 1993. Simultaneous precipitation kinetics of kaolinite at 80°C and pH 3. Geochim. Cosmochim. Acta 57, 4329-4336.
71. Nagy, K.L., Blum, A.E., Lasaga, A.C., 1991. Dissolution and precipitation kinetics of kaolinite at 80°C and pH 3. The dependence on solution saturation state. Am. J. Sci. 291, 649-686.
72. Nesbitt, H.W., MacRae, N.D., Shotyk, W., 1991. Congruent and incongruent dissolution of labradorite in dilute, acidic, salt solutions. J. Geol. 99, 429-442.
73. Oelkers, E.H., Schott, J., 1995a. The dependence of silicate dissolution rates on their structure and composition In: Kharaka, Y.K., Chudaev, O.V. (Eds.), Water Rock Interaction. Balkema, Dordrecht, pp. 153-156.
74. Oelkers, E.H., Schott, J., 1995b. Experimental study of anorthite dissolution and the relative mechanism of feldspar hydrolysis. Geochim. Cosmochim. Acta 59, 5039-5053.
75. Oelkers, E.H., Schott, J., Devidal, J.L., 1994. The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicates dissolution reactions. Geochim. Cosmochim. Acta 58, 2011-2024.
76. Oxburgh, R., Drever, J.I., Sun, Y-T., 1994. Mechanism of plagioclase dissolution in acid solution at 25°C. Geochim. Cosmochim. Acta 58, 661-669.
77. Petit, J.C., Della Mea, G., Dran, J.C., Magonthier, M.C., Mando, P.A., Paccagnella, A., 1990. Hydrated-layer formation during dissolution of complex silicate glasses and minerals. Geochim. Cosmochim. Acta 54, 1941-1955.
78. Rafal'skiy, R.P., Prisyagina, N.I., 1991. Reaction of andesine with hot aqueous solutions. Geocheni. Int. 28, 72-81.
79. Renders, P.J.N., Gammons, C.H., Barnes, H.L., 1995. Precipitation and dissolution rate for cristobalite from 150 to 300°C. Geochim. Cosmochim. Acta 59, 77-85.
80. Rimstidt, D., Barnes, H.L., 1980. The kinetics of silica-water reactions. Geochim. Cosmochim. Acta 44, 1683-1699.
81. Rooksby, H.P., 1961. Oxides and hydroxides of iron and aluminium. In: Brown, G. (Ed.), X-Ray Identification and Crystal Structures of Clay Minerals. Mineralogical Society, London, 210 pp.
82. Rose, N.M., 1991. Dissolution rates of prehnite, epidote and albite. Geochim. Cosmochim. Acta 55, 3273-3286.
83. Schott, J., Oelkers, E.H., 1995. Dissolution and crystallization rates of silicate minerals as a function of chemical affinity. Pure Appl. Chem. 67, 903-910.
84. Swoboda-Colberg, N., Drever, J.I., 1993. Mineral dissolution rates in plot-scale field and laboratory experiments. Chem. Geol. 105, 51-69.
85. Tester, J.W., Worley, W.G., Robinson, B.A., Grigsby, C.O., Feerer, J.L., 1994. Correlating quartz dissolution kinetics in pure water from 25 to 625°C. Geochim. Cosmochim. Acta 58, 2407-2420.
86. Thomassin, J.H., Touray, J.C., 1979. Etude des premiers stades de l'interaction eauverre basaltique: données de la spectrométrie de photoélectrons (XPS) et de la microscopie électronique à balayage. Bull. Mineral. 102, 594-599.
87. Walther, J.V., Wood, B.J., 1986. Mineral-fluid reaction rates. In: Walther, J.V., Wood, B.J. (Eds.), Fluid-Rock Interactions During Metamorphism. Springer-Verlag, pp. 194-213.
88. White, A.F., 1983. Surface chemistry and dissolution kinetics of glassy rocks at 25°C. Geochim. Cosmochim. Acta 47, 805-815.
89. Wieland, E., Stumm, W., 1992. Dissolution kinetics of kaolinite in acidic aqueous at 25°C. Geochim. Cosmochim. Acta 56, 3339-3355.
90. 2 and organic acids. Geochim. Cosmochim. Acta 55, 943-954.
91. Wogelius, R.A., Walther, J.V., 1992. Olivine dissolution kinetics at near surface conditions. Chem. Geol. 97, 101-112.
92. Wolery, T.J., 1983. EQ3/NR, A computer program for geochemical aqueous speciation-solubility calculations: user's guide and documentation. Lawrence Livermore National Laboratory UCRL-53414, Livermore, CA.
93. 2O vapor on the internal friction of binary alkali silicate glasses. J. Am. Ceram. Soc. 64, 635-648.