Performance of Choline-Based Deep Eutectic Solvents in the Extraction of Tocols from Crude Palm Oil

JAOCS, Journal of the American Oil Chemists' Society

Volumn 92, Issue 11-12, 2015, Pages 1709-1716

  Abdul Hadi, Nu'Man ^a,b   Ng, Mei Han ^a   Choo, Yuen May ^a   Hashim, Mohd Ali ^b   Jayakumar, Natesan Subramanian ^b  

^a MALAYSIAN PALM OIL BOARD   (Malaysia)

^b UNIVERSITY OF MALAYA   (Malaysia)

Author keywords

Carboxylic acid; Choline chloride; Deep eutectic solvent; Palm oil; Tocols

Indexed keywords

CARBOXYLIC ACIDS; CHLORINE COMPOUNDS; EUTECTICS; HYDROGEN BONDS; OIL SHALE; SOLVENT EXTRACTION; SOLVENTS;

CHLORIDE SALTS; CHOLINE CHLORIDE; CRUDE PALM OIL; DEEP EUTECTIC SOLVENTS; GREENER SOLVENTS; NATURAL SOURCES; PERFORMANCE; SEPARATION PROCESS; TOCOL; TOCOTRIENOLS;

PALM OIL;

EID: 84947920749     PISSN: 0003021X     EISSN: 15589331     Source Type: Journal    
DOI: 10.1007/s11746-015-2720-6     Document Type: Article

References (25)

1. Sundram K, Sambanthamurthi R, Tan YA (2003) Palm fruit chemistry and nutrition. Asia Pac J Clin Nutr 12:355-362
2. Chandan KS, Savita K, Sashwati R (2007) Tocotrienols in health and disease: the other half of the natural vitamin E family. Mol Aspects Med 28:692-728
3. de Man JM (1998) Functionality of palm oil in foods. J Food Lipids 5:159-170
4. Goh SH, Choo YM, Ong SH (1985) Minor constituents of palm oil. J Am Oil Chem Soc 62:237-240
5. Mukherjee S, Mitra A (2009) Health effects of palm oil. J Hum Ecol 26:197-203
6. Othman N, Manan Z, Wan Alwi S, Sarmidi M (2010) A review of extraction technology for carotenoids and vitamin E recovery from palm oil. J Appl Sci 10:1187-1191
7. Lin SW, Yoo CK (2009) Short-path distillation of palm olein and characterization of products. Euro J Lipid Sci Tech 111:142-147
8. Puah CW, Choo YM, Ma AN, Chuah CH (2007) Cleaner production technologies for the palm oil industry. Lipid Tech 19:31-34
9. Peres VF, Saffi J, Melecchi MI, Abad FC, Martinez MM, Oliveira EC, Jacques RA, Caramao EB (2006) Optimization of pressurized liquid extraction of Piper gaudichaudianum Kunth leaves. J Chromatogr A 1105:148-153
10. Choo YM, Ng MH, Ma AN, Chuah CH, Hashim MA (2005) Application of supercritical fluid chromatography in the quantitative analysis of minor components (carotenes, vitamin E, sterols, and squalene) from palm oil. Lipids 40:429-432
11. Kraujalis P, Venskutonis PR (2013) Supercritical carbon dioxide extraction of squalene and tocopherols from Amaranth and assessment of extracts antioxidant activity. J Supercrit Fluid 80:78-85
12. Ng MH, Choo YM, Ma AN, Chuah CH, Hashim MA (2004) Isolation of palm tocols using supercritical fluid chromatography. J Chromatogr Sci 42:536-539
13. Han X, Armstrong DW (2007) Ionic liquids in separations. Accounts Chem Res 40:1079-1086
14. Malik MA, Hashim MA, Nabi F (2011) Ionic liquids in supported liquid membrane technology. Chem Eng J 171:242-254
15. Zhang Q, De Oliveira Vigier K, Royer S, Jerome F (2012) Deep eutectic solvents: syntheses, properties and applications. Chem Soc Rev 41:7108-7146
16. Hayyan M, Mjalli FS, Hashim MA, AlNashef IM (2010) A novel technique for separating glycerine from palm oil-based biodiesel using ionic liquids. Fuel Process Technol 91:116-120
17. Abbott AP, Capper G, Davies DL, Rasheed RK, Shikotra P (2005) Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids. Inorg Chem 44:6497-6499
18. Yang Q, Xing H, Cao Y, Su B, Yang Y, Ren Q (2009) Selective separation of tocopherol homologues by liquid-liquid extraction using ionic liquids. Ind Eng Chem Res 48:6417-6422
19. Abbott AP, Boothby D, Capper G, Davies DL, Rasheed RK (2004) Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. J Am Chem Soc 126:9142-9147
20. Zhao H, Xia S, Ma P (2005) Use of ionic liquids as 'green' solvents for extractions. J Chem Technol Biot 80:1089-1096
21. Dai Y, van Spronsen J, Witkamp GJ, Verpoorte R, Choi YH (2013) Ionic liquids and deep eutectic solvents in natural products research: mixtures of solids as extraction solvents. J Nat Prod 76:2162-2173
22. Schwartz H, Ollilainen V, Piironen V, Lampi A-M (2008) Tocopherol, tocotrienol and plant sterol contents of vegetable oils and industrial fats. J Food Compos Anal 21:152-161
23. Ng MH, Choo YM (2012) Chromatographic analyses of tocopherols and tocotrienols in palm oil. J Chromatog Sci 50:283-286
24. Gee PT (2011) Unleashing the untold and misunderstood observations on vitamin E. Genes Nutr 6:5-16
25. Hayyan A, Hashim MA, Hayyan M, Mjalli FS, AlNashef IM (2013) A novel ammonium based eutectic solvent for the treatment of free fatty acid and synthesis of biodiesel fuel. Ind Crop Prod 46:392-398