Kinetics and Mechanism of the Oxidation of Cyclic Methylsiloxanes by Hydroxyl Radical in the Gas Phase: An Experimental and Theoretical Study

Environmental Science and Technology

Volumn 49, Issue 22, 2015, Pages 13322-13330

  Xiao, Ruiyang ^a,b   Zammit, Ian ^c   Wei, Zongsu ^d   Hu, Wei Ping ^f   MacLeod, Matthew ^c   Spinney, Richard ^e  

^a CENTRAL SOUTH UNIVERSITY   (China)

^b CHINESE NATIONAL ENGINEERING RESEARCH CENTER FOR CONTROL AND TREATMENT OF HEAVY METAL POLLUTION   (China)

^c STOCKHOLM UNIVERSITY   (Sweden)

^d Ohio State University   (United States)

^e OHIO STATE UNIVERSITY   (United States)

^f NATIONAL CHUNG CHENG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; CHEMICAL REACTIONS; GASES; KINETICS; PHASE INTERFACES; RATE CONSTANTS; SILICON COMPOUNDS; TEMPERATURE; TEMPERATURE DISTRIBUTION;

ARRHENIUS ACTIVATION ENERGY; ENVIRONMENTAL CONCERNS; GAS-PHASE REACTIONS; KINETICS AND MECHANISM; LONG-RANGE TRANSPORT POTENTIALS; SECOND-ORDER RATE CONSTANTS; TEMPERATURE DEPENDENCE; THEORETICAL VALUES;

ACTIVATION ENERGY;

CYCLOALKANE DERIVATIVE; DECAMETHYCYCLOPENTASILOXANE; HEXAMETHYLCYCLOTRISILOXANE; HYDROXYL RADICAL; METHYL GROUP; OCTAMETHYCYCLOTETRASILOXANE; SILOXANE; UNCLASSIFIED DRUG; VOLATILE AGENT; AIR POLLUTANT; GAS; HYDROGEN;

ACTIVATION ENERGY; ATMOSPHERIC CHEMISTRY; GAS PHASE REACTION; HYDROXYL RADICAL; ORGANIC COMPOUND; OXIDATION; REACTION KINETICS; SILICON; TEMPERATURE EFFECT; THEORETICAL STUDY; TROPOSPHERE;

ARTICLE; ENERGY; OXIDATION KINETICS; REACTION ANALYSIS; TEMPERATURE DEPENDENCE; THEORETICAL STUDY; THERMODYNAMICS; TROPOSPHERE; AIR POLLUTANT; ATMOSPHERE; CHEMICAL MODEL; CHEMISTRY; GAS; KINETICS; OXIDATION REDUCTION REACTION; TEMPERATURE;

AIR POLLUTANTS; ATMOSPHERE; GASES; HYDROGEN; HYDROXYL RADICAL; KINETICS; MODELS, CHEMICAL; OXIDATION-REDUCTION; SILOXANES; TEMPERATURE; THERMODYNAMICS;

EID: 84947277106     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/acs.est.5b03744     Document Type: Article

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