Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation

Journal of the American Chemical Society

Volumn 137, Issue 40, 2015, Pages 12865-12872

  Nguyen, Andy I ^a,b   Ziegler, Micah S ^a   Oña Burgos, Pascual ^c   Sturzbecher Hohne, Manuel ^b   Kim, Wooyul ^b   Bellone, Donatela E ^a   Tilley, T Don ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF ALMERÍA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CATALYSTS; COBALT; ENERGY RESOURCES; LIGANDS; REACTION INTERMEDIATES; ULTRAVIOLET VISIBLE SPECTROSCOPY;

ARTIFICIAL PHOTOSYNTHESIS; CARBON NEUTRAL FUEL; DISPROPORTIONATIONS; FOSSIL ENERGY RESOURCES; HETEROGENEOUS MATERIALS; OXYGEN EVOLUTION REACTION; OXYGEN ISOTOPIC LABELING; UV VISIBLE SPECTROSCOPY;

OXIDATION;

COBALT DERIVATIVE; OXIDE; PYRIDINE DERIVATIVE; SODIUM HYDROXIDE; COBALT; COBALT OXIDE; WATER;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; COLUMN CHROMATOGRAPHY; COMPARATIVE STUDY; CONTROLLED STUDY; CURRENT DENSITY; CYCLIC POTENTIOMETRY; DENSITY FUNCTIONAL THEORY; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE; ELECTROSPRAY MASS SPECTROMETRY; OXIDATION; OXIDATION REDUCTION POTENTIAL; OXYGEN EVOLUTION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STOICHIOMETRY; SURFACE PROPERTY; ULTRAVIOLET SPECTROSCOPY; WATER OXIDATION; X RAY CRYSTALLOGRAPHY; CHEMISTRY; OXIDATION REDUCTION REACTION;

CATALYSIS; COBALT; OXIDATION-REDUCTION; OXIDES; WATER;

EID: 84944406176     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b08396     Document Type: Article

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