Highly Flexible Self-Assembled V2O5 Cathodes Enabled by Conducting Diblock Copolymers

Scientific Reports

Volumn 5, Issue , 2015, Pages

  An, Hyosung ^a   Mike, Jared ^a   Smith, Kendall A ^b   Swank, Lisa ^b   Lin, Yen Hao ^b   Pesek, Stacy L ^b   Verduzco, Rafael ^b   Lutkenhaus, Jodie L ^a  

^a Department of Electrical and Computer Engineering   (United States)

^b Rice University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER; VANADIUM DERIVATIVE; VANADIUM PENTOXIDE;

ELECTRODE; POWER SUPPLY;

ELECTRIC POWER SUPPLIES; ELECTRODES; POLYMERS; VANADIUM COMPOUNDS;

EID: 84942288191     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep14166     Document Type: Article

References (50)

1. Nyholm, L., Nyström, G., Mihranyan, A. & Strømme, M. Toward fexible polymer and paper-based energy storage devices. Advanced Materials 23, 3751-3769, doi: 10.1002/adma.201004134 (2011).
2. Ling, Z. et al. Flexible and conductive MXene flms and nanocomposites with high capacitance. Proceedings of the National Academy of Sciences 111, 16676-16681 (2014).
3. Shirshova, N. et al. Multifunctional structural energy storage composite supercapacitors. Faraday discussions 172, 81-103 (2014).
4. Snyder, J. F., Carter, R. H. & Wetzel, E. D. Electrochemical and mechanical behavior in mechanically robust solid polymer electrolytes for use in multifunctional structural batteries. Chemistry of materials 19, 3793-3801 (2007).
5. Ng, S. et al. Single wall carbon nanotube paper as anode for lithium-ion battery. Electrochimica Acta 51, 23-28 (2005).
6. Whitten, P. G., Spinks, G. M. & Wallace, G. G. Mechanical properties of carbon nanotube paper in ionic liquid and aqueous electrolytes. Carbon 43, 1891-1896 (2005).
7. Lee, S. W. et al. High-power lithium batteries from functionalized carbon-nanotube electrodes. Nature Nanotechnology 5, 531-537 (2010).
8. Rigueur, J. L., Hasan, S. A., Mahajan, S. V. & Dickerson, J. H. Buckypaper fabrication by liberation of electrophoretically deposited carbon nanotubes. Carbon 48, 4090-4099 (2010).
9. Yang, X., Zhu, J., Qiu, L. & Li, D. Bioinspired efective prevention of restacking in multilayered graphene flms: towards the next generation of high-performance supercapacitors. Advanced Materials 23, 2833-2838 (2011).
10. Dikin, D. A. et al. Preparation and characterization of graphene oxide paper. Nature 448, 457-460 (2007).
11. Wang, K. et al. Super-aligned carbon nanotube flms as current collectors for lightweight and fexible lithium ion batteries. Advanced Functional Materials 23, 846-853 (2013).
12. 2(B)-based battery electrode with superior power rate and ultralong cycle life. Advanced Materials 25, 3462-3467 (2013).
13. 5-polypyrrole cathodes. Journal of Materials Chemistry 22, 11159-11165 (2012).
14. Wang, Y., Takahashi, K., Lee, K. H. & Cao, G. Z. Nanostructured vanadium oxide electrodes for enhanced lithium-ion intercalation. Advanced Functional Materials 16, 1133-1144, doi: 10.1002/adfm.200500662 (2006).
15. 5 hierarchical microspheres with enhanced lithium storage properties. Energy Environ. Sci. 6, 974-978 (2013).
16. Goward, G., Leroux, F. & Nazar, L. Poly(pyrrole) and poly(thiophene)/vanadium oxide interleaved nanocomposites: positive electrodes for lithium batteries. Electrochimica acta 43, 1307-1313 (1998).
17. 5 nanocomposites. Journal of The Electrochemical Society 144, 3886-3895, doi: 10.1149/1.1838107 (1997).
18. Olivetti, E. A., Kim, J. H., Sadoway, D. R., Asatekin, A. & Mayes, A. M. Sol-gel synthesis of vanadium oxide within a block copolymer matrix. Chemistry of Materials 18, 2828-2833, doi: 10.1021/cm060119s (2006).
19. Bates, F. S. & Fredrickson, G. H. Block copolymer thermodynamics: theory and experiment. Annual Review of Physical Chemistry 41, 525-557 (1990).
20. Javier, A. E., Patel, S. N., Hallinan, D. T., Srinivasan, V. & Balsara, N. P. Simultaneous electronic and ionic conduction in a block copolymer:application in lithium battery electrodes. Angewandte Chemie International Edition 50, 9848-9851, doi: 10.1002/anie.201102953 (2011).
21. Patel, S. N., Javier, A. E. & Balsara, N. P. Electrochemically oxidized electronic and ionic conducting nanostructured block copolymers for lithium battery electrodes. ACS Nano 7, 6056-6068, doi: 10.1021/nn4018685 (2013).
22. Kempf, C. N., Smith, K. A., Pesek, S. L., Li, X. & Verduzco, R. Amphiphilic poly(alkylthiophene) block copolymers prepared via externally initiated GRIM and click coupling. Polymer Chemistry 4, 2158-2163, doi: 10.1039/C3PY21098G (2013).
23. Bronstein, H. A. & Luscombe, C. K. Externally initiated regioregular P3HT with controlled molecular weight and narrow polydispersity. Journal of the American Chemical Society 131, 12894-12895, doi: 10.1021/ja9054977 (2009).
24. Huguenin, F., Giz, M. J., Ticianelli, E. A. & Torresi, R. M. Structure and properties of a nanocomposite formed by vanadium pentoxide containing poly (N-propane sulfonic acid aniline). Journal of power sources 103, 113-119 (2001).
25. 5 system. application as a high-capacity hybrid cathode for rechargeable lithium batteries. Journal of The Electrochemical Society 146, 2029-2033 (1999).
26. 5 intercalated with binary polymers. Journal of Power Sources 103, 273-279, doi: 10.1016/S0378-7753(01)00863-1 (2002).
27. Wong, H. Synthesis and characterization of polypyrrole/vanadium pentoxide nanocomposite aerogels. Journal of Materials Chemistry 8, 1019-1027 (1998).
28. Wanakule, N. S. et al. Ionic conductivity of block copolymer electrolytes in the vicinity of order-disorder and order-order transitions. Macromolecules 42, 5642-5651 (2009).
29. Patel, S. N., Javier, A. E., Stone, G. M., Mullin, S. A. & Balsara, N. P. Simultaneous conduction of electronic charge and lithium ions in block copolymers. ACS Nano 6, 1589-1600, doi: 10.1021/nn2045664 (2012).
30. Kamps, A. C., Fryd, M. & Park, S.-J. Hierarchical self-assembly of amphiphilic semiconducting polymers into isolated, bundled, and branched nanofbers. ACS nano 6, 2844-2852 (2012).
31. Park, S.-J., Kang, S.-G., Fryd, M., Saven, J. G. & Park, S.-J. Highly tunable photoluminescent properties of amphiphilic conjugated block copolymers. Journal of the American Chemical Society 132, 9931-9933 (2010).
32. Yang, H., Xia, H., Wang, G., Peng, J. & Qiu, F. Insights into poly(3-hexylthiophene)-b-poly(ethylene oxide) block copolymer: synthesis and solvent-induced structure formation in thin flms. Journal of Polymer Science Part A: Polymer Chemistry 50, 5060-5067 (2012).
33. Kline, R. J. et al. Dependence of regioregular poly (3-hexylthiophene) flm morphology and feld-efect mobility on molecular weight. Macromolecules 38, 3312-3319 (2005).
34. 2O xerogel solved by the atomic pair distribution function technique. Journal of the American Chemical Society 124, 10157-10162 (2002).
35. Coleman, J. N. et al. Improving the mechanical properties of single-walled carbon nanotube sheets by intercalation of polymeric adhesives. Applied Physics Letters 82, 1682-1684 (2003).
36. Park, S. et al. Graphene oxide papers modifed by divalent ions-enhancing mechanical properties via chemical cross-linking. ACS nano 2, 572-578 (2008).
37. Timoshenko, S., Goodier, J. & Abramson, H. N. Teory of elasticity. Journal of Applied Mechanics 37, 888 (1970).
38. Hibino, M., Ugaji, M., Kishimoto, A. & Kudo, T. Preparation and lithium intercalation of a new vanadium oxide with a two-dimensional structure. Solid State Ionics 79, 239-244 (1995).
39. 5 for lithium ion electroinsertion. Langmuir 27, 12209-12217 (2011).
40. 5 as intercalation hosts. Journal of The Electrochemical Society 142, L102-L103 (1995).
41. West, K., Zachau-Christiansen, B., Jacobsen, T. & Skaarup, S. Vanadium oxide xerogels as electrodes for lithium batteries. Electrochimica acta 38, 1215-1220 (1993).
42. 5 xerogel cathodes upon lithium intercalation. Journal of the Electrochemical Society 146, 2387-2392 (1999).
43. 5 xerogels. Solid State Ionics 90, 5-14 (1996).
44. 5 xerogel coin cells. Journal of the Electrochemical Society 143, 3473-3477 (1996).
45. 5-anchored carbon nanotubes for enhanced electrochemical energy storage. Journal of the American Chemical Society 133, 16291-16299 (2011).
46. Yu, J. et al. A porous vanadium pentoxide nanomaterial as cathode material for rechargeable lithium batteries. Electrochimica Acta 89, 292-299 (2013).
47. 5 flms electrodes characterized by a variety of electroanalytical techniques. Journal of power sources 97, 482-485 (2001).
48. 5 thin flms prepared by rf sputtering. Electrochimica Acta 53, 3329-3336 (2008).
49. Jiang, Z. et al. The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source. Journal of Synchrotron Radiation (International Union of Crystallography-IUCr) 19, 627-636, doi: 10.1107/S0909049512022017 (2012).
50. Jiang, Z. GIXSGUI sofware. Available at: https://www1.aps.anl.gov/Sector-8/8-ID/Operations-and-Schedules/Useful-Links/Sector-8-GIXSGUI. (Accessed: 23th July 2015).