Chemical and physical aspects of self-healing materials

Progress in Polymer Science

Volumn 49-50, Issue , 2015, Pages 34-59

  Yang, Ying ^a   Ding, Xiaochu ^a   Urban, Marek W ^a  

^a Clemson University   (United States)

Author keywords

Heterogeneity; Nanocomposites; Reversible covalent bonds; Self healing; Supramolecular chemistry

Indexed keywords

CHEMICAL BONDS; NANOCOMPOSITES; REPAIR; SUPRAMOLECULAR CHEMISTRY; THERMODYNAMICS;

HETEROGENEITY; KINETICS AND THERMODYNAMICS; MOLECULAR HETEROGENEITY; SCIENTIFIC COMMUNITY; SELF-HEALING; SUPRAMOLECULAR ASSEMBLIES; SUSTAINABLE TECHNOLOGY; SYNTHETIC MATERIALS;

SELF-HEALING MATERIALS;

EID: 84941797349     PISSN: 00796700     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progpolymsci.2015.06.001     Document Type: Review

References (165)

1. D.Y. Wu, S. Meure, and D. Solomon Self-healing polymeric materials: a review of recent developments Prog Polym Sci 33 2008 479 522
2. R.P. Wool Self-healing materials: a review Soft Matter 4 2008 400 418
3. E.B. Murphy, and F. Wudl The world of smart healable materials Prog Polym Sci 35 2010 223 251
4. M.D. Hager, P. Greil, C. Leyens, S. van der Zwaag, and U.S. Schubert Self-healing materials Adv Mater 22 2010 5424 5430
5. Y. Yang, and M.W. Urban Self-healing polymeric materials Chem Soc Rev 42 2013 7446 7467
6. R. Vaiyapuri, B.W. Greenland, H.M. Colquhoun, J.M. Elliott, and W. Hayes Evolution of supramolecular healable composites: a minireview Polym Int 63 2014 933 942
7. H. Eyring Plasticity, and diffusion as examples of absolute reaction rates J Chem Phys 4 1936 283 291
8. P.J. Flory, and W. Krigbaum Statistical mechanics of dilute polymer solutions. II J Chem Phys 18 1950 1086 1094
9. R. Simha, and R.F. Boyer On a general relation involving the glass temperature and coefficients of expansion of polymers J Chem Phys 37 1962 1003 1007
10. F. Liu, and M.W. Urban Recent advances and challenges in designing stimuli-responsive polymers Prog Polym Sci 35 2010 3 23
11. F. Liu, and M.W. Urban New thermal transitions in stimuli-responsive copolymer films Macromolecules 42 2009 2161 2167
12. g) and stimuli-responsive (T-SR) transitions in random copolymers Macromolecules 43 2010 5330 5337
13. Y. Chen, A.M. Kushner, G.A. Williams, and Z. Guan Multiphase design of autonomic self-healing thermoplastic elastomers Nat Chem 4 2012 467 472
14. W.J. Wright, T. Hufnagel, and W. Nix Free volume coalescence and void formation in shear bands in metallic glass J Appl Phys 93 2003 1432 1437
15. S.R. White, N.R. Sottos, P.H. Geubelle, J.S. Moore, M.R. Kessler, S.R. Sriram, E.N. Brown, and S. Viswanathan Autonomic healing of polymer composites Nature 409 2001 794 797
16. X. Chen, M.A. Dam, K. Ono, A. Mal, H. Shen, S.R. Nutt, K. Sheran, and F. Wudl A thermally re-mendable cross-linked polymeric material Science 295 2002 1698 1702
17. X. Chen, F. Wudl, A.K. Mal, H. Shen, and S.R. Nutt New thermally remendable highly cross-linked polymeric materials Macromolecules 36 2003 1802 1807
18. C. Zeng, H. Seino, J. Ren, K. Hatanaka, and N. Yoshie Bio-based furan polymers with self-healing ability Macromolecules 46 2013 1794 1802
19. N. Bai, K. Saito, and G.P. Simon Synthesis of a diamine cross-linker containing Diels-Alder adducts to produce self-healing thermosetting epoxy polymer from a widely used epoxy monomer Polym Chem 4 2013 724 730
20. Y.L. Liu, and Y.W. Chen Thermally reversible cross-linked polyamides with high toughness and self-repairing ability from maleimide- and furan-functionalized aromatic polyamides Macromol Chem Phys 208 2007 224 232
21. M.J. Barthel, T. Rudolph, A. Teichler, R.M. Paulus, J. Vitz, S. Hoeppener, M.D. Hager, F.H. Schacher, and U.S. Schubert Self-healing materials via reversible crosslinking of poly(ethylene oxide)-block-poly(furfuryl glycidyl ether) (PEO-b-PFGE) block copolymer films Adv Funct Mater 23 2013 4921 4932
22. K.K. Oehlenschlaeger, J.O. Mueller, J. Brandt, S. Hilf, A. Lederer, M. Wilhelm, R. Graf, C. ML, F.G. Schmidt, and C. Barner-Kowollik Adaptable hetero Diels-Alder networks for fast self-healing under mild conditions Adv Mater 26 2014 3561 3566
23. C.-M. Chung, Y.-S. Roh, S.-Y. Cho, and J.-G. Kim Crack healing in polymeric materials via photochemical [2 + 2] cycloaddition Chem Mater 16 2004 3982 3984
24. J. Ling, M.Z. Rong, and M.Q. Zhang Photo-stimulated self-healing polyurethane containing dihydroxyl coumarin derivatives Polymer 53 2012 2691 2698
25. P. Froimowicz, H. Frey, and K. Landfester Towards the generation of self-healing materials by means of a reversible photo-induced approach Macromol Rapid Commun 32 2011 468 473
26. A.S. Fawcett, and M.A. Brook Thermoplastic silicone elastomers through self-association of pendant coumarin groups Macromolecules 47 2014 1656 1663
27. T. Ono, T. Nobori, and J.-M. Lehn Dynamic polymer blends-component recombination between neat dynamic covalent polymers at room temperature Chem Commun 2005 1522 1524
28. G. Deng, C. Tang, F. Li, H. Jiang, and Y. Chen Covalent cross-linked polymer gels with reversible sol-gel transition and self-healing properties Macromolecules 43 2010 1191 1194
29. W.W. Cleland Dithiothreitol, a new protective reagent for SH groups Biochemistry 3 1964 480 482
30. A.V. Tobolsky, W.J. MacKnight, and M. Takahashi Relaxation of disulfide and tetrasulfide polymers J Phys Chem 68 1964 787 790
31. B. Adhikari, D. De, and S. Maiti Reclamation and recycling of waste rubber Prog Polym Sci 25 2000 909 948
32. J. Canadell, H. Goossens, and B. Klumperman Self-healing materials based on disulfide links Macromolecules 44 2011 2536 2541
33. J.A. Yoon, J. Kamada, K. Koynov, J. Mohin, R. Nicolaÿ, Y. Zhang, A.C. Balazs, T. Kowalewski, and K. Matyjaszewski Self-healing polymer films based on thiol-disulfide exchange reactions and self-healing kinetics measured using atomic force microscopy Macromolecules 45 2011 142 149
34. U. Lafont, H. van Zeijl, and S. van der Zwaag Influence of cross-linkers on the cohesive and adhesive self-healing ability of polysulfide-based thermosets ACS Appl Mater Interfaces 4 2012 6280 6288
35. M. AbdolahZadeh, A.C. Esteves, S. van der Zwaag, and S.J. Garcia Healable dual organic-inorganic crosslinked sol-gel based polymers: crosslinking density and tetrasulfide content effect J Polym Sci, A Polym Chem 52 2014 1953 1961
36. P. Zheng, and T.J. McCarthy A surprise from 1954: siloxane equilibration is a simple, robust, and obvious polymer self-healing mechanism J Am Chem Soc 134 2012 2024 2027
37. H. Ying, Y. Zhang, and J. Cheng Dynamic urea bond for the design of reversible and self-healing polymers Nat Commun 5 2014 3218/1 3218/3218
38. Y. Amamoto, J. Kamada, H. Otsuka, A. Takahara, and K. Matyjaszewski Repeatable photoinduced self-healing of covalently cross-linked polymers through reshuffling of trithiocarbonate units Angew Chem Int Ed 50 2011 1660 1663
39. Y. Amamoto, H. Otsuka, A. Takahara, and K. Matyjaszewski Self-healing of covalently cross-linked polymers by reshuffling thiuram disulfide moieties in air under visible light Adv Mater 24 2012 3975 3980
40. L.M. García-Con, M.J. Whitcombe, E.V. Piletska, and S.A. Piletsky A sulfur-sulfur cross-linked polymer synthesized from a polymerizable dithiocarbamate as a source of dormant radicals Angew Chem Int Ed 49 2010 4075 4078
41. K. Imato, M. Nishihara, T. Kanehara, Y. Amamoto, A. Takahara, and H. Otsuka Self-healing of chemical gels cross-linked by diarylbibenzofuranone-based trigger-free dynamic covalent bonds at room temperature Angew Chem Int Ed 51 2012 1138 1142
42. C.E. Yuan, M.Z. Rong, M.Q. Zhang, Z.P. Zhang, and Y.C. Yuan Self-healing of polymers via synchronous covalent bond fission/radical recombination Chem Mater 23 2011 5076 5081
43. Z.P. Zhang, M.Z. Rong, M.Q. Zhang, and Ce. Yuan Alkoxyamine with reduced homolysis temperature and its application in repeated autonomous self-healing of stiff polymers Polym Chem 4 2013 4648 4654
44. Yuan Ce, M.Z. Rong, and M.Q. Zhang Self-healing polyurethane elastomer with thermally reversible alkoxyamines as crosslinkages Polymer 55 2014 1782 1791
45. M.K. Beyer The mechanical strength of a covalent bond calculated by density functional theory J Chem Phys 112 2000 7307 7312
46. B. Ghosh, and M.W. Urban Self-repairing oxetane-substituted chitosan polyurethane networks Science 323 2009 1458 1460
47. B. Ghosh, K.V. Chellappan, and M.W. Urban UV-initiated self-healing of oxolane-chitosan-polyurethane (OXO-CHI-PUR) networks J Mater Chem 22 2012 16104 16113
48. B. Ghosh, K.V. Chellappan, and M.W. Urban Self-healing inside a scratch of oxetane-substituted chitosan-polyurethane (OXE-CHI-PUR) networks J Mater Chem 21 2011 14473 14486
49. Y. Yang, and M.W. Urban Self-repairable polyurethane networks by atmospheric carbon dioxide and water Angew Chem Int Ed 53 2014 12142 12147
50. S. Telitel, Y. Amamoto, J. Poly, F. Morlet-Savary, O. Soppera, J. Lalevee, and K. Matyjaszewski Introduction of self-healing properties into covalent polymer networks via the photodissociation of alkoxyamine junctions Polym Chem 5 2014 921 930
51. J.M. Lehn Supramolecular chemistry - scope and perspectives molecules, supermolecules, and molecular devices (nobel lecture) Angew Chem Int Ed 27 1988 89 112
52. P. Cordier, F. Tournilhac, C. Soulié-Ziakovic, and L. Leibler Self-healing and thermoreversible rubber from supramolecular assembly Nature 451 2008 977 980
53. F. Herbst, S. Seiffert, and W.H. Binder Dynamic supramolecular poly (isobutylene) s for self-healing materials Polym Chem 3 2012 3084 3092
54. G.M.L. van Gemert, J.W. Peeters, S.H.M. Söntjens, H.M. Janssen, and A.W. Bosman Self-healing supramolecular polymers in action Macromol Chem Phys 213 2012 234 242
55. D. Montarnal, F. Tournilhac, M. Hidalgo, J.L. Couturier, and L. Leibler Versatile one-pot synthesis of supramolecular plastics and self-healing rubbers J Am Chem Soc 131 2009 7966 7967
56. R. Zhang, T. Yan, B.D. Lechner, K. Schroter, Y. Liang, B. Li, F. Furtado, P. Sun, and K. Saalwächter Heterogeneity, segmental and hydrogen bond dynamics, and aging of supramolecular self-healing rubber Macromolecules 46 2013 1841 1850
57. F. Maes, D. Montarnal, S. Cantournet, F. Tournilhac, L. Corté, and L. Leibler Activation and deactivation of self-healing in supramolecular rubbers Soft Matter 8 2012 1681 1687
58. C. Hilger, R. Stadler, L. Liane, and dL. Freitas Multiphase thermoplastic elastomers by combination of covalent and association chain structures: 2 small-strain dynamic mechanical properties Polymer 31 1990 818 823
59. C. Hilger, and R. Stadler Cooperative structure formation by combination of covalent and association chain polymers: 4 designing functional groups for supramolecular structure formation Polymer 32 1991 3244 3249
60. F. Herbst, K. Schroter, I. Gunkel, S. Groger, T. Thurn-Albrecht, J. Balbach, and W.H. Binder Aggregation and chain dynamics in supramolecular polymers by dynamic rheology: cluster formation and self-aggregation Macromolecules 43 2010 10006 10016
61. F.H. Beijer, R.P. Sijbesma, H. Kooijman, A.L. Spek, and E. Meijer Strong dimerization of ureidopyrimidones via quadruple hydrogen bonding J Am Chem Soc 120 1998 6761 6769
62. S.H. Söntjens, R.P. Sijbesma, M.H. van Genderen, and E. Meijer Stability and lifetime of quadruply hydrogen bonded 2-ureido-4 [1H]-pyrimidinone dimers J Am Chem Soc 122 2000 7487 7493
63. K.E. Feldman, M.J. Kade, T.F. de Greef, E. Meijer, E.J. Kramer, and C.J. Hawker Polymers with multiple hydrogen-bonded end groups and their blends Macromolecules 41 2008 4694 4700
64. K. Yamauchi, J.R. Lizotte, D.M. Hercules, M.J. Vergne, and T.E. Long Combinations of microphase separation and terminal multiple hydrogen bonding in novel macromolecules J Am Chem Soc 124 2002 8599 8604
65. K. Yamauchi, J.R. Lizotte, and T.E. Long Thermoreversible poly(alkyl acrylates) consisting of self-complementary multiple hydrogen bonding Macromolecules 36 2003 1083 1088
66. J. Cui, and A. del Campo Multivalent H-bonds for self-healing hydrogels Chem Commun 48 2012 9302 9304
67. J. Hentschel, A.M. Kushner, J. Ziller, and Z. Guan Self-healing supramolecular block copolymers Angew Chem Int Ed 51 2012 10561 10565
68. Y. Chen, and Z. Guan Multivalent hydrogen bonding block copolymers self-assemble into strong and tough self-healing materials Chem Commun 50 2014 10868 10870
69. I. Manners Synthetic metal-containing polymers 2004 John Wiley & Sons Inc New York, NY 275
70. G.R. Whittell, M.D. Hager, U.S. Schubert, and I. Manners Functional soft materials from metallopolymers and metallosupramolecular polymers Nat Mater 10 2011 176 188
71. C.G. Hardy, J. Zhang, Y. Yan, L. Ren, and C. Tang Metallopolymers with transition metals in the side-chain by living and controlled polymerization techniques Prog Polym Sci 39 2014 1742 1796
72. K.A. Williams, A.J. Boydston, and C.W. Bielawski Towards electrically conductive, self-healing materials J R Soc Interface 4 2007 359 362
73. M. Burnworth, L. Tang, J.R. Kumpfer, A.J. Duncan, F.L. Beyer, G.L. Fiore, S.J. Rowan, and C. Weder Optically healable supramolecular polymers Nature 472 2011 334 337
74. S. Bode, L. Zedler, F.H. Schacher, B. Dietzek, M. Schmitt, J. Popp, M. Hager, and U.S. Schubert Self-healing polymer coatings based on crosslinked metallosupramolecular copolymers Adv Mater 25 2013 1634 1638
75. N. Holten-Andersen, M.J. Harrington, H. Birkedal, B.P. Lee, P.B. Messersmith, K.Y.C. Lee, and J.H. Waite pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer networks with near-covalent elastic moduli Proc Natl Acad Sci USA 108 2011 2651 2655
76. H. Ceylan, M. Urel, T.S. Erkal, A.B. Tekinay, A. Dana, and M.O. Guler Mussel inspired dynamic cross-linking of self-healing peptide nanofiber network Adv Funct Mater 23 2013 2081 2090
77. 5N-Cu) supramolecular polymer networks Polym Chem 4 2013 4897 4901
78. J.F. Gohy, B.G. Lohmeijer, and U.S. Schubert Reversible metallo-supramolecular block copolymer micelles containing a soft core Macromol Rapid Commun 23 2002 555 560
79. A. Wild, A. Winter, F. Schlütter, and U.S. Schubert Advances in the field of π-conjugated 2,2′: 6′,2″-terpyridines Chem Soc Rev 40 2011 1459 1511
80. Constable EC 2,2′: 6′,2″-terpyridines: from chemical obscurity to common supramolecular motifs Chem Soc Rev 36 2007 246 253
81. E. Vaccaro, and J.H. Waite Yield and post-yield behavior of mussel byssal thread: a self-healing biomolecular material Biomacromolecules 2 2001 906 911
82. B.P. Lee, J.L. Dalsin, and P.B. Messersmith Synthesis and gelation of DOPA-modified poly (ethylene glycol) hydrogels Biomacromolecules 3 2002 1038 1047
83. M. Krogsgaard, M.A. Behrens, J.S. Pedersen, and H. Birkedal Self-healing mussel-inspired multi-pH-responsive hydrogels Biomacromolecules 14 2013 297 301
84. L. He, D.E. Fullenkamp, J.G. Rivera, and P.B. Messersmith pH responsive self-healing hydrogels formed by boronate-catechol complexation Chem Commun 47 2011 7497 7499
85. M. Vatankhah-Varnoosfaderani, S. Hashmi, A. GhavamiNejad, and F.J. Stadler Rapid self-healing and triple stimuli responsiveness of a supramolecular polymer gel based on boron-catechol interactions in a novel water-soluble mussel-inspired copolymer Polym Chem 5 2014 512 523
86. F.R. Kersey, D.M. Loveless, and S.L. Craig A hybrid polymer gel with controlled rates of cross-link rupture and self-repair J R Soc Interface 4 2007 373 380
87. Z. Wang, Y. Yang, R. Burtovyy, I. Luzinov, and M.W. Urban UV-induced self-repairing polydimethylsiloxane-polyurethane (PDMS-PUR) and polyethylene glycol-polyurethane (PEG-PUR) Cu-catalyzed networks J Mater Chem A 2 2014 15527 15534
88. S. Burattini, H.M. Colquhoun, B.W. Greenland, and W. Hayes A novel self-healing supramolecular polymer system Faraday Discuss 143 2009 251 264
89. S. Burattini, H.M. Colquhoun, J.D. Fox, D. Friedmann, B.W. Greenland, P.J.F. Harris, W. Hayes, M.E. Mackay, and S.J. Rowan A self-repairing, supramolecular polymer system: healability as a consequence of donor-acceptor [π]-[π] stacking interactions Chem Commun 44 2009 6717 6719
90. S. Burattini, B.W. Greenland, D.H. Merino, W. Weng, J. Seppala, H.M. Colquhoun, W. Hayes, M.E. Mackay, I.W. Hamley, and S.J. Rowan A healable supramolecular polymer blend based on aromatic π-π stacking and hydrogen-bonding interactions J Am Chem Soc 132 2010 12051 12058
91. S. Burattini, B.W. Greenland, W. Hayes, M.E. Mackay, S.J. Rowan, and H.M. Colquhoun A supramolecular polymer based on tweezer-type π-π stacking interactions: molecular design for healability and enhanced toughness Chem Mater 23 2010 6 8
92. Z. Xu, J. Peng, N. Yan, H. Yu, S. Zhang, K. Liu, and Y. Fang Simple design but marvelous performances: molecular gels of superior strength and self-healing properties Soft Matter 9 2013 1091 1099
93. A. Eisenberg, B. Hird, and R. Moore A new multiplet-cluster model for the morphology of random ionomers Macromolecules 23 1990 4098 4107
94. S.J. Kalista, and J. Stephen Self-healing of thermoplastic poly (ethylene-co-methacrylic acid) copolymers following projectile puncture 2003 Virginia Polytechnic Institute and State University Blacksburg, VA 67 (M.S. Thesis)
95. S.J. Kalista, and T.C. Ward Thermal characteristics of the self-healing response in poly (ethylene-co-methacrylic acid) copolymers J R Soc Interface 4 2007 405 411
96. R.J. Varley, S. Shen, and S. van der Zwaag The effect of cluster plasticisation on the self- healing behaviour of ionomers Polymer 51 2010 679 686
97. A. Reisch, E. Roger, T. Phoeung, C. Antheaume, C. Orthlieb, F. Boulmedais, P. Lavalle, J.B. Schlenoff, B. Frisch, and P. Schaaf On the benefits of rubbing salt in the cut: self-healing of saloplastic PAA/PAH compact polyelectrolyte complexes Adv Mater 26 2014 2547 2551
98. S.J. Kalista, J.R. Pflug, and R.J. Varley Effect of ionic content on ballistic self-healing in EMAA copolymers and ionomers Polym Chem 4 2013 4910 4926
99. A.B. South, and L.A. Lyon Autonomic self-healing of hydrogel thin films Angew Chem Int Ed 49 2009 767 771
100. M.J. Serpe, C.D. Jones, and L.A. Lyon Layer-by-layer deposition of thermoresponsive microgel thin films Langmuir 19 2003 8759 8764
101. X. Wang, F. Liu, X. Zheng, and J. Sun Water-enabled self-healing of polyelectrolyte multilayer coatings Angew Chem Int Ed 50 2011 11378 11381
102. Y. Huang, P.G. Lawrence, and Y. Lapitsky Self-assembly of stiff, adhesive and self-healing gels from common polyelectrolytes Langmuir 30 2014 7771 7777
103. B.K. Ahn, D.W. Lee, J.N. Israelachvili, and J.H. Waite Surface-initiated self-healing of polymers in aqueous media Nat Mater 13 2014 867 872
104. J. Szejtli Introduction and general overview of cyclodextrin chemistry Chem Rev 98 1998 1743 1754
105. M.D. Pluth, and K.N. Raymond Reversible guest exchange mechanisms in supramolecular host-guest assemblies Chem Soc Rev 36 2007 161 171
106. M. Nakahata, Y. Takashima, H. Yamaguchi, and A. Harada Redox-responsive self-healing materials formed from host-guest polymers Nat Commun 2 2011 511/1 511/511
107. T. Kakuta, Y. Takashima, M. Nakahata, M. Otsubo, H. Yamaguchi, and A. Harada Preorganized hydrogel: self-healing properties of supramolecular hydrogels formed by polymerization of host-guest monomers that contain cyclodextrins and hydrophobic guest groups Adv Mater 25 2013 2849 2853
108. E.A. Appel, F. Biedermann, U. Rauwald, S.T. Jones, J.M. Zayed, and O.A. Scherman Supramolecular cross-linked networks via host-guest complexation with cucurbit [8] uril J Am Chem Soc 132 2010 14251 14260
109. P.S. Stayton, T. Shimoboji, C. Long, A. Chilkoti, G. Ghen, J.M. Harris, and A.S. Hoffman Control of protein-ligand recognition using a stimuli-responsive polymer Nature 378 1995 472 474
110. W.A. Petka, J.L. Harden, K.P. McGrath, D. Wirtz, and D.A. Tirrell Reversible hydrogels from self-assembling artificial proteins Science 281 1998 389 392
111. E.A. Fogleman, W.C. Yount, J. Xu, and S.L. Craig Modular, well-behaved reversible polymers from DNA-based monomers Angew Chem Int Ed 41 2002 4026 4028
112. D.C. Lin, B. Yurke, and N.A. Langrana Mechanical properties of a reversible, DNA-crosslinked polyacrylamide hydrogel J Biomech Eng 126 2004 104 110
113. G. Seelig, B. Yurke, and E. Winfree Catalyzed relaxation of a metastable DNA fuel J Am Chem Soc 128 2006 12211 12220
114. T. Liedl, H. Dietz, B. Yurke, and F. Simmel Controlled trapping and release of quantum dots in a DNA-switchable hydrogel Small 3 2007 1688 1693
115. D.Y. Zhang, A.J. Turberfield, B. Yurke, and E. Winfree Engineering entropy-driven reactions and networks catalyzed by DNA Science 318 2007 1121 1125
116. M. Yoonessi, Y. Shi, D.A. Scheiman, M. Lebron-Colon, D.M. Tigelaar, R. Weiss, and M.A. Meador Graphene polyimide nanocomposites; thermal, mechanical, and high-temperature shape memory effects ACS Nano 6 2012 7644 7655
117. C. Wang, N. Liu, R. Allen, J.B.H. Tok, Y. Wu, F. Zhang, Y. Chen, and Z. Bao A rapid and efficient self-healing thermo-reversible elastomer crosslinked with graphene oxide Adv Mater 25 2013 5785 5790
118. S.K. Yadav, and J.W. Cho Functionalized graphene nanoplatelets for enhanced mechanical and thermal properties of polyurethane nanocomposites Appl Surf Sci 266 2013 360 367
119. M.V. Biyani, E.J. Foster, and C. Weder Light-healable supramolecular nanocomposites based on modified cellulose nanocrystals ACS Macro Lett 2 2013 236 240
120. V. Artel, R. Cohen, I. Aped, M. Ronen, D. Gerber, and C.N. Sukenik Controlled formation of thiol and disulfide interfaces Langmuir 29 2012 191 198
121. T. Engel, and G. Kickelbick Self-healing nanocomposites from silica-polymer core-shell nanoparticles Polym Int 63 2014 915 923
122. P. Froimowicz, D. Klinger, and K. Landfester Photoreactive nanoparticles as nanometric building blocks for the generation of self-healing hydrogel thin films Chem Eur J 17 2011 12465 12475
123. A.R. Smith, and D.F. Watson Photochemically triggered assembly of composite nanomaterials through the photodimerization of adsorbed anthracene derivatives Chem Mater 22 2009 294 304
124. R. Vaiyapuri, B.W. Greenland, S.J. Rowan, H.M. Colquhoun, J.M. Elliott, and W. Hayes Thermoresponsive supramolecular polymer network comprising pyrene-functionalized gold nanoparticles and a chain-folding polydiimide Macromolecules 45 2012 5567 5574
125. G. Cheng, N.R. Vautravers, R.E. Morris, and D.J. Cole-Hamilton Synthesis of functional cubes from octavinylsilsesquioxane (OVS) Org Biomol Chem 6 2008 4662 4667
126. K. Liang, G. Li, H. Toghiani, J.H. Koo, and C.U. Pittman Cyanate ester/polyhedral oligomeric silsesquioxane (POSS) nanocomposites: synthesis and characterization Chem Mater 18 2006 301 312
127. Y. Xue, Y. Liu, F. Lu, J. Qu, H. Chen, and L. Dai Functionalization of graphene oxide with polyhedral oligomeric silsesquioxane (POSS) for multifunctional applications J Phys Chem Lett 3 2012 1607 1612
128. Z. Xu, Y. Zhao, X. Wang, and T. Lin A thermally healable polyhedral oligomeric silsesquioxane (POSS) nanocomposite based on Diels-Alder chemistry Chem Commun 49 2013 6755 6757
129. S. Kango, S. Kalia, A. Celli, J. Njuguna, Y. Habibi, and R. Kumar Surface modification of inorganic nanoparticles for development of organic-inorganic nanocomposites - a review Prog Polym Sci 38 2013 1232 1261
130. J.Y. Lee, Q. Zhang, T. Emrick, and A.J. Crosby Nanoparticle alignment and repulsion during failure of glassy polymer nanocomposites Macromolecules 39 2006 7392 7396
131. R. Vaiyapuri, B.W. Greenland, H.M. Colquhoun, J.M. Elliott, and W. Hayes Molecular recognition between functionalized gold nanoparticles and healable, supramolecular polymer blends - a route to property enhancement Polym Chem 4 2013 4902 4909
132. C.C. Corten, and M.W. Urban Repairing polymers using oscillating magnetic field Adv Mater 21 2009 5011 5015
133. I. Alessandri Writing, self-healing, and self-erasing on conductive pressure-sensitive adhesives Small 6 2010 1679 1685
134. M.B. Cortie, and A.M. McDonagh Synthesis and optical properties of hybrid and alloy plasmonic nanoparticles Chem Rev 111 2011 3713 3735
135. V. Giannini, A.I. Fernandez-Dominguez, S.C. Heck, and S.A. Maier Plasmonic nanoantennas: fundamentals and their use in controlling the radiative properties of nanoemitters Chem Rev 111 2011 3888 3912
136. V. Amendola, D. Dini, S. Polizzi, J. Shen, K.M. Kadish, M.J.F. Calvete, M. Hanack, and M. Meneghetti Self-healing of gold nanoparticles in the presence of zinc phthalocyanines and their very efficient nonlinear absorption performances J Phys Chem C 113 2009 8688 8695
137. V. Amendola, and M. Meneghetti Advances in self-healing optical materials J Mater Chem 22 2012 24501 24508
138. G.L. Fiore, S.J. Rowan, and C. Weder Optically healable polymers Chem Soc Rev 42 2013 7278 7288
139. H. Zhang, H. Xia, and Y. Zhao Optically triggered and spatially controllable shape-memory polymer-gold nanoparticle composite materials J Mater Chem 22 2012 845 849
140. J. Fox, J.J. Wie, B.W. Greenland, S. Burattini, W. Hayes, H.M. Colquhoun, M.E. Mackay, and J.R. Rowan High-strength, healable, supramolecular polymer nanocomposites J Am Chem Soc 134 2012 5362 5368
141. H. Chen, L. Shao, Q. Li, and J. Wang Gold nanorods and their plasmonic properties Chem Soc Rev 42 2013 2679 2724
142. M.E. Pearce, J.B. Melanko, and A.K. Salem Multifunctional nanorods for biomedical applications Pharm Res 24 2007 2335 2352
143. J. Kim, I.S. Jung, S.Y. Kim, E. Lee, J.K. Kang, S. Sakamoto, K. Yamaguchi, and K. Kim New cucurbituril homologues: -syntheses, isolation, characterization, and X-ray crystal structures of cucurbit[n]uril (n = 5, 7, and 8) J Am Chem Soc 122 2000 540 541
144. J.R. McKee, E.A. Appel, J. Seitsonen, E. Kontturi, O.A. Scherman, and O. Ikkala Healable, stable and stiff hydrogels: combining conflicting properties using dynamic and selective three-component recognition with reinforcing cellulose nanorods Adv Funct Mater 24 2014 2706 2713
145. K.S. Novoselov, A.K. Geim, S. Morozov, D. Jiang, Y. Zhang, S. Dubonos, I.V. Grigorieva, and A.A. Firsov Electric field effect in atomically thin carbon films Science 306 2004 666 669
146. S. Stankovich, D.A. Dikin, G.H.B. Dommett, K.M. Kohlhaas, E.J. Zimney, E.A. Stach, R.D. Piner, S.T. Nguyen, and R.S. Ruoff Graphene-based composite materials Nature 442 2006 282 286
147. R.R. Kohlmeyer, M. Lor, and J. Chen Remote, local, and chemical programming of healable multishape memory polymer nanocomposites Nano Lett 12 2012 2757 2762
148. L. Huang, N. Yi, Y. Wu, Y. Zhang, Q. Zhang, Y. Huang, Y. Ma, and Y. Chen Multichannel and repeatable self-healing of mechanical enhanced graphene-thermoplastic polyurethane composites Adv Mater 25 2013 2224 2228
149. J.T. Kim, B.K. Kim, E.Y. Kim, S.H. Kwon, and H.M. Jeong Synthesis and properties of near IR induced self-healable polyurethane/graphene nanocomposites Eur Polym J 49 2013 3889 3896
150. H. Sun, X. You, Y. Jiang, G. Guan, X. Fang, J. Deng, P. Chen, Y. Luo, and H. Peng Self-healable electrically conducting wires for wearable microelectronics Angew Chem Int Ed 53 2014 9526 9531
151. C. Gong, J. Liang, W. Hu, X. Niu, S. Ma, H.T. Hahn, and Q. Pei A healable, semitransparent silver nanowire-polymer composite conductor Adv Mater 25 2013 4186 4191
152. A.M. Peterson, R.E. Jensen, and G.R. Palmese Thermoreversible and remendable glass-polymer interface for fiber-reinforced composites Compos Sci Technol 71 2011 586 592
153. A.R. Jones, B.J. Blaiszik, S.R. White, and N.R. Sottos Full recovery of fiber/matrix interfacial bond strength using a microencapsulated solvent-based healing system Compos Sci Technol 79 2013 1 7
154. R.P. Wool Crack healing in semicrystalline polymers, block copolymers and filled elastomers. Adhesion and adsorption of polymers Polym Sci Technol 12A 1980 341 362
155. R. Fall Puncture reversal of ethylene ionomers-mechanistic studies 2001 Virginia Tech Blacksburg, VA 65 (M.S. Thesis)
156. S.J. Kalista Jr., T.C. Ward, and Z. Oyetunji Self-healing of poly (ethylene-co-methacrylic acid) copolymers following projectile puncture Mech Adv Mater Struc 14 2007 391 397
157. R. Wool, and K. O'connor A theory crack healing in polymers J Appl Phys 52 1981 5953 5963
158. P.G. de Gennes Reptation of a polymer chain in the presence of fixed obstacles J Chem Phys 55 1971 572 579
159. C. Lin, S. Lee, and K. Liu Methanol-induced crack healing in poly(methyl methacrylate) Poly Eng Sci 30 1990 1399 1406
160. K. Jud, H. Kausch, and J. Williams Fracture mechanics studies of crack healing and welding of polymers J Mater Sci 16 1981 204 210
161. S. Prager, and M. Tirrell The healing process at polymer-polymer interfaces J Chem Phys 75 1981 5194 5198
162. J. Forrest, K. Dalnoki-Veress, J. Stevens, and J. Dutcher Effect of free surfaces on the glass transition temperature of thin polymer films Phys Rev Lett 77 1996 2002 2005
163. J. Forrest, K. Dalnoki-Veress, and J. Dutcher Interface and chain confinement effects on the glass transition temperature of thin polymer films Phys Rev E: Stat Nonlinear Soft Matter Phys 56 1997 5705 5716
164. A. Richard Interface and surface effects on the glass-transition temperature in thin polymer films Faraday Discuss 98 1994 219 230
165. R.P. Wool Twinkling fractal theory of the glass transition J Polym Sci, B: Polym Phys 46 2008 2765 2778