Catalytic reduction of polar substrates without metals: A thermodynamic and kinetic study of heterolytic activation of hydrogen by vacancies in frustrated Lewis pairs

Catalysis Today

Volumn 251, Issue , 2015, Pages 28-33

  Whittemore, Sean M ^a   Edvenson, Gary ^a   Camaioni, Donald M ^a   Karkamkar, Abhi ^a   Neiner, Doinita ^a   Parab, Kshitij ^a   Autrey, Tom ^a  

^a MINNESOTA STATE UNIVERSITY MOORHEAD   (United States)

Author keywords

Acid base cooperativity; Calorimetry; Catalytic reduction; Frustrated Lewis pairs; Kinetics; Thermodynamics

Indexed keywords

CALORIMETERS; CALORIMETRY; CHEMICAL ACTIVATION; ENZYME KINETICS; EQUILIBRIUM CONSTANTS; FREE ENERGY; HYDROGEN; MAGNETIC RESONANCE SPECTROSCOPY; NITROGEN COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SUBSTRATES; THERMODYNAMICS;

CATALYTIC REDUCTION; COOPERATIVITY; ENTHALPIC DRIVING FORCE; FRUSTRATED LEWIS PAIRS; HETEROLYTIC SPLITTING; PSEUDO-FIRST ORDER REACTIONS; RATE-LIMITING STEPS; REACTION CALORIMETRY;

HEAT FLUX;

EID: 84940004726     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cattod.2014.10.040     Document Type: Article

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