Two Reaction Mechanisms via Iminium Ion Intermediates: The Different Reactivities of Diphenylprolinol Silyl Ether and Trifluoromethyl-Substituted Diarylprolinol Silyl Ether

Chemistry - A European Journal

Volumn 21, Issue 35, 2015, Pages 12337-12346

  Gotoh, Hiroaki ^a   Uchimaru, Tadafumi ^b   Hayashi, Yujiro ^c  

^a YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

asymmetric synthesis; iminium ions; organocatalysis; reaction mechanisms; silyl ethers

Indexed keywords

ALDEHYDES; CALCULATIONS; CATALYSTS; IONS; REACTION INTERMEDIATES;

ASYMMETRIC SYNTHESIS; IMINIUM IONS; ORGANOCATALYSIS; REACTION MECHANISM; SILYL ETHERS;

ETHERS;

EID: 84939467545     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201500326     Document Type: Article

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