A theoretical and experimental study of the effects of silyl substituents in enantioselective reactions catalyzed by diphenylprolinol silyl ether

Chemistry - A European Journal

Volumn 20, Issue 51, 2014, Pages 17077-17088

  Hayashi, Yujiro ^a,b   Okamura, Daichi ^a,b   Yamazaki, Tatsuya ^c   Ameda, Yasuto ^c   Gotoh, Hiroaki ^c   Tsuzuki, Seiji ^d   Uchimaru, Tadafumi ^d   Seebach, Dieter ^d  

^a TOHOKU UNIVERSITY   (Japan)

^b TOKYO UNIVERSITY OF SCIENCE   (Japan)

^c NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^d ETH ZURICH   (Switzerland)

Author keywords

Asymmetric synthesis; Density functional calculations; Organocatalysis; Reaction mechanisms; Substituent effects

Indexed keywords

CATALYSIS; CATALYSTS; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ETHERS; IONS; REACTION INTERMEDIATES; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ASYMMETRIC SYNTHESIS; CONFORMATIONAL BEHAVIOR; CYCLOADDITION REACTION; ENANTIOSELECTIVE REACTIONS; ORGANOCATALYSIS; REACTION MECHANISM; SUBSTITUENT EFFECT; THEORETICAL CALCULATIONS;

ENANTIOSELECTIVITY;

EID: 84915825935     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201403514     Document Type: Article

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