Microemulsions: a novel approach to enhanced oil recovery: a review

Journal of Petroleum Exploration and Production Technology

Volumn 5, Issue 3, 2015, Pages 255-268

  Bera, Achinta ^a   Mandal, Ajay ^b  

^a UNIVERSITY OF ALBERTA   (Canada)

^b INDIAN SCHOOL OF MINES   (India)

Author keywords

Enhanced oil recovery; Interfacial tension; Microemulsion; Microemulsion flooding; Phase behavior; Solubilization capacity

Indexed keywords

FLOODS; MICROEMULSIONS; OIL WELL FLOODING; PETROLEUM RESERVOIRS; PHASE BEHAVIOR; RESERVOIRS (WATER); SOLUBILITY; SURFACE ACTIVE AGENTS; SURFACE TENSION;

ALTERNATIVE SOURCE; CHEMICAL SYSTEMS; ENHANCED OIL RECOVERY; OIL PRODUCTIVITIES; PHYSICOCHEMICAL PROPERTY; RENEWABLE PRODUCTS; RESERVOIR CONDITIONS; SOLUBILIZATION CAPACITIES;

ENHANCED RECOVERY;

EID: 84939446532     PISSN: 21900558     EISSN: 21900566     Source Type: Journal    
DOI: 10.1007/s13202-014-0139-5     Document Type: Review

References (109)

1. Abe M, Schechter RS, Selliah RD, Sheikh B, Wade WH (1987) Phase behavior of branched tail ethoxylated carboxylate surfactant/electrolyte/alkane systems. J Dispers Sci Technol 8:157–172
2. Abe M, Yamazaki T, Ogino K (1992) Phase behavior and physicochemical properties of sodium octyl sulfate/n-dodecan/1-hexanol/aqueous AlCl3 middle-phase microemulsion. Langmuir 8:833–837
3. Anderson DR, Biduer MS, Dravis MT, Manning CD, Schevan LE (1976) Interfacial tension and phase behaviour in surfactant brine oil systems. Presented at SPE Improved Oil Recovery Symposium, Tulsa, OK
4. Austad T, Strand S (1996) Chemical flooding of oil reservoirs-4. Effects of temperature and pressure on the middle phase solubilization parameters close to optimum flood conditions. Colloids Surf A 108:243–252
5. Austad T, Fjelde I, Veggeland K (1994a) Adsorption VI. Nonequilibrium adsorption of ethoxylated sulfonate onto reservoir cores in the presence of xanthan. J Pet Sci Eng 12:1–8
6. Austad T, Fjelde I, Veggeland K, Taugbol K (1994b) Physicochemical principles of low tension polymer flood. J Pet Sci Eng 10:255–269
7. Auvray L, Cotton JP, Ober R, Taupin C (1984) Structure and phase equilibria of microemulsions. J Phys 45:913–925
8. Azouz IB, Ober R, Nakache E, Williams CE (1992) A small angle X-ray scattering investigation of the structure of a ternary water-in-oil microemulsion. Colloids Surf A 69:87–97
9. Bai Y, Xiong C, Shang X, Xin Y (2014) Experimental study on ethanolamine/surfactant flooding for enhanced oil recovery. Energy Fuels 28:1829–1837
10. Barakat Y, Fortney LN, Schechter RS, Wade WH, Yiv S, Graciaa A (1983) Criteria for structuring surfactants to maximize solubilization of oil and water: II. Alkyl benzene sodium sulfonates. J Colloid Interface Sci 92:561–574
11. Barnes JR, Smith JP, Smith JR, Shpakoff PG, Raney KH, Puerto MC (2008) Phase behavior methods for the evaluation of surfactants for chemical flooding at higher temperature reservoir conditions. Paper SPE 113314, presented at the 2008 SPE/DOE Improved Oil Recovery Symposium, Tulsa, OK
12. Baviere M (1976) Phase diagram optimization in micellar systems. Presented at the 51st annual fall technical conference and exhibition of the society of petroleum engineers of AIME, New Orleans, USA
13. Bera A, Ojha K, Mandal A, Kumar T (2011) Interfacial tension and phase behavior of surfactant-brine–oil system. Colloids Surf A 383:114–119
14. Bera A, Ojha K, Mandal A, Kumar T (2012a) Phase behavior and physicochemical properties of (sodium dodecyl sulfate + brine + propan-1-ol + heptane) microemulsions. J Chem Eng Data 57:1000–1006
15. Bera A, Kumar S, Mandal A (2012b) Temperature-dependent phase behavior, particle size and conductivity of middle-phase microemulsions stabilized by ethoxylated nonionic surfactants. J Chem Eng Data 57:3617–3623
16. Bera A, Ojha K, Kumar T, Mandal A (2012c) Water solubilization capacity, interfacial compositions and thermodynamic parameters of anionic and cationic microemulsions. Colloids Surf A 404:70–77
17. Bera A, Kumar T, Ojha K, Mandal A (2014a) Screening of microemulsion properties for application in enhanced oil recovery. Fuel 121:198–207
18. Bera A, Mandal A, Guha BB (2014b) Effect of synergism of surfactant and salt mixture on interfacial tension reduction between crude oil and water in enhanced oil recovery. J Chem Eng Data 59:89–96
19. Bera A, Kumar T, Mandal A (2014c) Physicochemical characterization of anionic and cationic microemulsions: water solubilization, particle size distribution, surface tension and structural parameters. J Chem Eng Data 59:2490–2498
20. Bostich JM, Hsieh WC, Koepke JW (1984) Process for enhanced oil recovery employing petroleum sulfonate blends. Patent number US 4446036 A
21. Bouabboune M, Hammouch N, Benhadid S (2006) Comparison between microemulsion and surfactant solution flooding efficiency for enhanced oil recovery in TinFouye oil Field. Paper 2006-058, presented at the Petroleum Society’s 7th Canadian International Petroleum Conference and 57th Annual Technical Meeting, Calgary, Alberta, Canada
22. Bourrel M, Schechter RS (1988) Microemulsion and related systems. Marcel Dekker Inc., New York
23. Bumajdad A, Eastoe J (2004) Conductivity of mixed surfactant water-in-oil microemulsions. Phys Chem Chem Phys 6:1597–1602
24. Cavalli R, Marengo E, Caputo O, Ugazio E, Gasco MR (1996) The effect of alcohols with different structures on the formation of warm o/w microemulsions. J Dispers Sci Technol 17:717–734
25. Cayias JL, Schechter RS, Wade WH (1977) The utilization of petroleum sulfonates for producing low interfacial tensions between hydrocarbons and water. J Colloid Interface Sci 59:31–38
26. Chai JL, Zhao JR, Gao YH, Yang XD, Wu CJ (2007) Studies on the phase behavior of the microemulsions formed by sodium dodecyl sulfonate, sodium dodecyl sulfate and sodium dodecyl benzene sulfonate with a novel fishlike phase diagram. Colloids Surf A 302:31–35
27. Chiang MY, Shah DO (1980) The effect of alcohol on surfactant mass transfer across the oil/brine interface and related phenomena. Presented at the SPE 5th International Symposium on oilfield and Geothermal Chemistry, Stanford, CA
28. Chilingar GV, Yen TF (1983) Some notes on wettability and relative permeability of carbonate rocks: II. Energy Resour 7:67–75
29. Comelles F, Pascual A (1997) Microemulsions with butyl lactate as cosurfactant. J Dispers Sci Technol 18:161–175
30. Dosher TM, Wise FA (1976) Enhanced oil recovery potential: an estimate. J Petrol Technol 28:575–585
31. El-Batanoney M, Abdel-Moghny T, Ramzi M (1999) The effect of mixed surfactants on enhancing oil recovery. J Surf Deterg 2:201–205
32. Elraies KA, Tan IM, Awang M, Fathaddin MT (2010) A new approach to low-cost, high performance chemical flooding system. Presented at the SPE Production and Operation Conference and Exhibition, Tunis, Tunisia
33. Engelskirchen S, Elsner N, Sottmann T, Strey R (2007) Triacylglycerol microemulsions stabilized by alkyl ethoxylate surfactants—a basic study. Phase behavior, interfacial tension and microstructure. J Colloid Interface Sci 312:114–121
34. Flaaten AK, Nguyen QP, Zhang J, Mohammadi H, Pope GA (2010) Alkaline/surfactant/polymer chemical flooding without the need for soft water. Presented at the SPE Annual Technical Conference and Exhibition, Denver, Colorado, USA
35. Gao B, Sharma MM (2013) A family of alkyl sulfate gemini surfactants. 2. Water–oil interfacial tension reduction. J Colloid Interface Sci 407:375–381
36. Glover FDS, Santanna VC, Barros Neto EI (1979) Surfactant phase behavior and retention in porous media. Soc Pet Eng J 19:183–193
37. Gurgel A, Moura MCPA, Dantas TNC, Barros Neto EL, Dantas Neto AA (2008) A review on chemical flooding methods applied in enhanced oil recovery. Braz J Pet Gas 2:83–95
38. Healy RN, Reed RL (1974) Physicochemical aspects of microemulsion flooding. Soc Pet Eng 14:491–501
39. Healy RN, Reed RL (1977) Immiscible microemulsion flooding. Presented at the SPE 4th symposium on improved oil recovery, Tulsa, OK
40. Healy RN, Reed RL, Carpenter CW (1975) A laboratory study of microemulsion flooding. Soc Pet Eng J 259:87–100
41. Healy RN, Read RL, Stenmark DG (1976) Multiphase microemulsion system. Soc Pet Eng J 261:147–160
42. Holm LW (1971) Use of soluble oils for oil recovery. J Pet Technol 23:1475–1483
43. Hussain A, Luckham PF, Tadros TF (1997) Phase behavior of ph dependent microemulsions at high temperatures and high salinity. Oil Gas Sci Technol Rev IFP 52:228–231
44. Iglauer S, Wu Y, Shuler P, Tang Y, Goddard WA III (2009) Alkyl polyglycoside surfactant–alcohol co-solvent formulations for improved oil recovery. Colloids Surf A 339:48–59
45. Iglauer S, Wu Y, Shuler P, Tang Y, Goddard WA III (2010) New surfactant classes for enhanced oil recovery and their tertiary oil recovery potential. J Pet Sci Eng 71:23–29
46. Jeirani Z, Mohamed Jan B, Si Ali B, Noor IM, See CH, Saphanuchart W (2013a) Formulation, optimization and application of triglyceride microemulsion in enhanced oil recovery. Ind Crop Prod 43:6–14
47. Jeirani Z, Mohamed Jan B, Si Ali B, Noor IM, See CH, Saphanuchart W (2013b) Formulation and phase behavior study of a nonionic triglyceride microemulsion to increase hydrocarbon production. Ind Crop Prod 43:15–24
48. John AC, Rakshit AK (1994) Phase behavior and properties of a microemulsion in the presence of NaCl. Langmuir 10:2084–2087
49. Kahlweit M, Strey R, Hasse D (1985) Effect of salt concentration on interfacial behavior in the surfactant system water + n-octadecane + diethylene glycol monohexyl ether. J Phys Chem 89:163–167
50. Kahlweit M, Strey R, Busses G (1990) Microemulsions: a qualitative thermodynamic approach. J Phys Chem 94:3881–3894
51. Kassel DG (1989) Chemical flooding-status report. J Pet Sci Eng 2:81–101
52. Kayalia IH, Liub S, Miller CA (2010) Microemulsions containing mixtures of propoxylated sulfates with slightly branched hydrocarbon chains and cationic surfactants with short hydrophobes or PO chains. Colloids Surf A 354:246–251
53. Kim V, Hilfiker R, Eicke HF (1988) Excess adsorption of hydrocarbons on the oil/water interface in H2O/AOT/oil microemulsions in the presence of additives. J Colloid Interface Sci 121:579–584
54. Kumar R, Mohanty KK (2010) ASP flooding of viscous oils. Presented at the SPE Annual Technical Conference and Exhibition, Florence, Italy
55. Kwok W, Hayes RE, Nasi-El-Din HA (1995) Modeling dynamic adsorption of an anionic surfactant on Berea sandstone with radial flow. Chem Eng Sci 50:768–783
56. Lalanne-Cassou C, Carmone I, Fortney LN, Samii A, Schechter RS, Wade WH, Weerasoooriya U, Weerasoooriya V, Yiv S (1983) Minimizing cosolvent requirements for microemulsion formed with binary surfactant mixtures. J Dispers Sci Technol 8:137–156
57. Leung R, Hou MJ, Monohar C, Shah DO, Chun PW (1985) Micro- and microemulsions.In: Shah DO (ed). Am Chem Soc, Washington, DC
58. Levitt DB, Jackson A, Heinson C, Britton LN, Malik T, Dwarakanath V, Pope GA (2006) Identification and evaluation of high-performance eor surfactants. SPE Reserv Eval Eng 12:243–253
59. Li X, He G, Zheng W, Xiao G (2010) Study on conductivity property and microstructure of TritonX-100/alkanol/n-heptane/water microemulsion. Colloids Surf A 360:150–158
60. Lu J, Liyanage PJ, Solairaj S, Adkins S, Arachchilage GP, Kim DH, Britton C, Weerasooriya U, Pope GA (2014) New surfactant developments for chemical enhanced oil recovery. J Pet Sci Eng 120:94–101
61. Maerker JM, Gale WW (1992) Surfactant flood process design for Loudon. SPE Reserv Eng J 7:36–44
62. Maidment LJ, Chen V, Warr GG (1997) Effect of added cosurfactant on ternary microemulsion structure and dynamics. Colloids Surf A 129–130:311–319
63. Mandal A, Bera A, Ojha K, Kumar T (2012) Characterization of surfactant stabilized nanoemulsion and its use in enhanced oil recovery. Paper SPE 155406-MS, presented at International Oilfield Nanotechnology Conference and Exhibition, 12–14 June, Noordwijk, The Netherlands
64. Mclendon WJ, Koronaios P, Enick RM, Biesmans G, Salazar L, Miller A, Soong Y, McLendon T, Romanov V, Crandall D (2014) Assessment of CO2-soluble non-ionic surfactants for mobility reduction using mobility measurements and CT imaging. J Pet Sci Eng 119:196–209
65. Meyers KO, Salter SJ (1980) The effect of oil brine ratio on surfactant adsorption from microemulsions. Presented at the SPE 55th annual fall technical conference and exhibition, Dallas, Texas
66. Mo C, Zhong M, Zhong Q (2000) Investigation of structure and structural transition in microemulsion systems of sodium dodecyl sulfonate/n-heptane/n-butanol/water by cyclic voltammetric and electrical conductivity measurements. J Electroanal Chem 493:100–107
67. Myers D (2006) Surfactant science and technology, 3rd edn. Wiley, Hoboken
68. Nakamae M, Abe M, Ogino K (1990) The effects of alkyl chain lengths of sodium alkyl sulfates and n-alkanes on microemulsion formation. J Colloid Interface Sci 135:449–454
69. Nelson RC, Pope GA (1978) Phase relationship in chemical flooding. Soc Pet Eng J 18:325–338
70. Osborne DW, Middleton CA, Rogers RL (1988) Alcohol-free microemulsions. J Dispers Sci Technol 9:415–423
71. Osterloh WT, Jante MJ (1992) Surfactant-polymer flooding with anionic PO/EO surfactant microemulsions containing polyethylene glycol additives. Paper SPE 24151, presented at the SPE 8th Symposium on enhanced oil recovery, Tulsa, OK
72. Pattarino F, Marengo E, Trotta M, Gasco MR (2000) Combined use of lecithin and decvl polyglucoside in microemulsions: domain of existence and cosurfactant effect. J Dispers Sci Technol 21:345–363
73. Pottmann FH (1974) Secondary and tertiary oil recovery process. Interstate Oil Compact Commission, Oklahoma City
74. Purwono S, Murachman B (2001) Development of non petroleum base chemicals for improving oil recovery in Indonesia. Paper SPE 68768, presented at the SPE Asia Pacific Oil and Gas Conference and Exhibition, Jakarta, Indonesia
75. Qiao W, Li J, Zhu Y, Cai H (2012) Interfacial tension behavior of double long-chain 1, 3, 5-triazine surfactants for enhanced oil recovery. Fuel 96:220–225
76. Qutubuddin S, Millar CA, Fort T (1984) Phase behavior of pH-dependent microemulsions. J Colloid Interface Sci 101:46–58
77. Richardson CJ, Aboofazeli A, Lawrence MJ, Barlow JD (1997) Prediction of phase behavior in microemulsion systems using artificial neural networks. J Colloid Interface Sci 187:296–303
78. Rosen MJ (1989) Selection of surfactant pairs for optimization of interfacial properties. J Am Oil Chem Soc 66:1840–1947
79. Sagitani H, Friberg SE (1980) Microemulsion systems with a nonionic cosurfactant. J Dispers Sci Technol 1:151–164
80. Salehi M, Johnson SJ, Liang JT (2008) Mechanistic study of wettability alteration using surfactants with applications in naturally fractured reservoirs. Langmuir 24:14099–14107
81. Santanna VC, Curbelo FDS, Castro Dantas TN, Dantas Neto AA, Albuquerque HS, Garnica AIC (2009) Microemulsion flooding for enhanced oil recovery. J Pet Sci Eng 66:117–120
82. Sayyouh MH (1994) Alkalines can improve miscibility of a surfactant–oil–brine system and areal sweep efficiency of oil. Oil Gas 1:13–17
83. Sayyouh MH, Abdel-Waly AA, George J, Salama AO (1991) Design of a microemulsion slug for maximizing tertiary oil recovery efficiency. SPE 20804
84. Schechter RS, Wade WH (1976) Research on tertiary oil recovery: annual report. University of Texas at Austin, Texas
85. Schramm LL, Stasiuk EN, Turner D (2003) The influence of interfacial tension in the recovery of bitumen by water-based conditioning and flotation of Athabasca oil sands. Fuel Proc Technol 80(2):101–118
86. Schulman JH, Stoeckenius W, Prince LM (1959) Mechanism of formation and structure of microemulsions by electron microscopy. J Phys Chem 63:1677–1680
87. Schwuger MJ, Stickdorn K, Plummer, MA, Roszelle, WO (1975) Patent number US3901317
88. Scriven LE (1976) Equilibrium bicontinuous structure. Nature 263:123–125
89. Shah DO (1981) Fundamental aspects of surfactant–polymer flooding process. Keynote paper presented at the European Symposium on Enhanced Oil Recovery, Bournemouth, England
90. Shah DO (ed) (1985) Macro- and microemulsions. ACS Symposium Series 272; American Chemical Society, Washington, DC
91. Shah DO, Schechter RS (1977) Improved oil recovery by surfactant and polymer flooding. Academic, New York
92. Sharma MK, Shah DO (1985) Macro- and microemulsion. In: Shah DO (ed). Am Chem Soc, Washington, DC
93. Shindy AM, Darwich TD, Sayyaouh MH, Abdel-Aziz O (1997) Development of an expert system for EOR method selection. Paper SPE-37708-MS, presented at the SPE Middle East Oil Show and Conference, 15–18 March, Bahrain
94. Southwick JG, Svec Y, Chilek G, Shahin GT (2010) The effect of live crude on alkaline-surfactant-polymer formulations: implications for final formulation design. SPE-135357-MS, presented at the SPE Annual Technical Conference and Exhibition, 19–22 September, Florence, Italy
95. Stoeckenius W, Schulman JH, Prince LM (1960) The structure of myelin figures and microemulsionsa s observed with the electron microscope. Kolloid-Z 169:170–178
96. Trabelsi S, Argillier J, Dalmazzone C, Hutin A, Bazin B, Langevin D (2011) Effect of added surfactants in an enhanced alkaline/heavy oil system. Energy Fuels 25:1681–1685
97. Verkruyse LA, Salter SJ (1985) Potential use of nonionic surfactants in micellar flooding. Paper SPE 13574, presented at the SPE International Symposium on Oilfield and Geothermal Chemistry, Phoenix, Arizona
98. Wadle A, Förster Th, von Rybinski W (1993) Influence of the microemulsion phase structure on the phase inversion temperature emulsification of polar oils. Colloids Surf A 76:51–57
99. Wan T, Yao J, Zishun S, Li W, Juan W (2011) Solution and drilling fluid properties of water soluble AM–AA–SSS copolymers by inverse microemulsion. J Pet Sci Eng 78:334–337
100. Wang D, Liu C, Wu W, Wang G (2010) Novel surfactants that attain ultra-low interfacial tension between oil and high salinity formation water without adding alkali, salts, cosurfactants, alcohol and solvents. Paper SPE 127452, presented at the SPE EOR Conference at Oil and Gas West Asia, Muscat, Oman
101. Wei J, Huang G, Yu H, An C (2011) Efficiency of single and mixed Gemini/conventional micelles on solubilization of phenanthrene. Chem Eng J 168:201–207
102. Willhite GP, Green DW, Okoye DM, Looney MD (1980) A study of oil displacement by microemulsion systems-mechanisms and phase behavior. Soc Pet Eng J 20:459–472
103. Wilson PM, Murphy CL, Foster WR (1976) The effects of sulfonate molecular weight and salt concentration on the interfacial tension of oil–brine–surfactant systems. Paper SPE 5812-MS, presented at the SPE Improved Oil Recovery Symposium, 22–24 March, Tulsa, OK
104. Winsor PA (1954) Solvent properties of amphiphile compounds. Butterworth’s Scientific Publications, London
105. Wormuth KR, Kaler EW (1987) Amines as microemulsion cosurfactants. J Phys Chem 91:611–617
106. Yangming Z, Huanxin W, Zulin C, Qi C (2003) Compositional modification of crude oil during oil recovery. J Pet Sci Eng 38:1–11
107. Zhang DL, Lui S, Yan W, Puerto M, Hirasaki J, Miller CA (2006) Favorable attributes of alkali–surfactant–polymer flooding. Paper SPE 99744, presented at the SPE symposium on improved oil recovery, Tulsa, OK
108. Zhou M, Rhue RD (2000) Effect of interfacial alcohol concentrations on oil solubilization by sodium dodecyl sulfate micelles. J Colloid Interface Sci 228:18–23
109. Zhu Y, Xu G, Gong H, Wu D, Wang Y (2009) Production of ultra-low interfacial tension between crude oil and mixed brine solution of Triton X-100 and its oligomer Tyloxapol with cetyltrimethylammonium bromide induced by hydrolyzed polyacrylamide. Colloids Surf A 332:90–97