Temperature-dependent phase behavior, particle size, and conductivity of middle-phase microemulsions stabilized by ethoxylated nonionic surfactants

Journal of Chemical and Engineering Data

Volumn 57, Issue 12, 2012, Pages 3617-3623

  Bera, Achinta ^a   Kumar, Shashikant ^a   Mandal, Ajay ^a  

^a INDIAN SCHOOL OF MINES   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRICAL CONDUCTIVITY; ELECTRICAL CONDUCTIVITY MEASUREMENTS; ETHYLENE OXIDE NUMBERS; MASS FRACTION; MICROEMULSION SYSTEMS; NACL CONCENTRATION; OPTIMAL SALINITY; PERCOLATION BEHAVIOR; PHASE MICROEMULSIONS; RELATIVE PHASE; TEMPERATURE DEPENDENT;

ACTIVATION ENERGY; ELECTRIC CONDUCTIVITY; NONIONIC SURFACTANTS; PARTICLE SIZE ANALYSIS; PHASE STABILITY; SALINITY MEASUREMENT; SODIUM CHLORIDE; SOLVENTS;

MICROEMULSIONS;

EID: 84871000437     PISSN: 00219568     EISSN: 15205134     Source Type: Journal    
DOI: 10.1021/je300845q     Document Type: Article

References (37)

1. Shah, D. O., Ed.; Macro- and Microemulsions; ACS Symposium Series 272; American Chemical Society: Washington, DC, 1985.
2. Healy, R. N.; Read, R. L.; Stenmark, D. G. Multiphase Microemulsion System Soc. Pet. Eng. J 1976, 261, 147-160
3. Magid, L. J. Formation of middle-phase microemulsions using surfactants derived from a renewable resource: Ethoxylated tall oils J. Colloid Interface Sci. 1982, 87, 447-459
4. Leung, R.; Shah, D. O. Solubilization and phase equilibria of water-in-oil microemulsions: II. Effects of alcohols, oils, and salinity on single-chain surfactant systems J. Colloid Interface Sci. 1987, 120, 330-344
5. Bourell, M.; Schechter, R. S. Microemulsions and Related Systems: Formulations, Solvency and Physical Properties; Dekker: New York, 1988.
6. Mitra, R. K.; Paul, B. K. Investigation on percolation in conductance of mixed reverse micelles Colloids Surf. A 2005, 252, 243-259
7. Moulik, S. P.; Paul, B. K. Structure, dynamics and transport properties of microemulsions Adv. Colloid Interface Sci. 1998, 78, 99-195
8. Paul, B. K.; Mitra, R. K. Water solubilization capacity of mixed reverse micelles: Effect of surfactant component, the nature of the oil, and electrolyte concentration J. Colloid Interface Sci. 2005, 288, 261-279
9. Lang, J.; Zana, R.; Lalem, N. The Structure, Dynamics and Equilibrium Properties of Colloidal Systems; Kluwer Academic: The Netherlands, 1990.
10. Boned, C.; Peyrelasse, J.; Saidi, Z. Dynamic percolation of spheres in a continuum: The case of microemulsions Phys. Rev. E 1993, 47, 468-478
11. Feldman, Y.; Korlovich, N.; Nir, L.; Garti, N. Dielectric relaxation in sodium bis(2-ethylhexyl)sulfosuccinate-water-decane microemulsions near the percolation temperature threshold Phys. Rev. E 1995, 51, 478-491
12. Schubel, D. A shear-induced viscoelastic system through addition of a crown-ether to AOT w/o-microemulsions Colloid Polym. Sci. 1998, 276, 743-746
13. Ray, S.; Bisal, S.; Moulik, S. P. Structure and dynamics of microemulsions. Part 1. Effect of additives on percolation of conductance and energetics of clustering in water-AOT-heptane microemulsions J. Chem. Soc., Faraday Trans. 1993, 89, 3277-3282
14. Alexandradis, P.; Holzwarth, J. F.; Hatton, T. A. Interfacial dynamics of water-in-oil microemulsion droplets: determination of the bending modulus using iodine laser temperature jump Langmuir 1993, 9, 2045-2052
15. Peyrelasse, J.; Boned, C. Structure and Dynamics of Strongly Interacting Colloids and Supramolecular Aggregates in Solution; Kluwer Academic: The Netherlands, 1992.
16. Bera, A.; Ojha, K.; Mandal, A.; Kumar, T. Interfacial tension and phase behavior of surfactant-brine-oil system Colloids Surf. A 2011, 383, 114-119
17. Griffin, W. C. Classification of surface active agents by HLB J. Soc. Cosm. Chem. 1949, 1, 311-326
18. Safran, S. A. Micellar Solutions and Microemulsions: Structure, Dynamics and Statistical Thermodynamics;; Spinger-Verlag: New York, 1990.
19. Langevin, D. Microemulsions-interfacial aspects Adv. Colloid Interface Sci. 1991, 34, 583-595
20. Aveyard, R.; Binks, B. P.; Fletcher, P. D. I. In the Structure, Dynamics and Equilibrium Properties of Colloidal Systems; Kluwer Academic Publishers: Norwell, MA, 1990.
21. John, A. C.; Rakshit, A. K. Phase behavior and properties of a microemulsion in the presence of NaCl Langmuir 1994, 10, 2084-2087
22. Tanford, C. The Hydrophobic Effect: Formation of Micelles and Biological Membranes; Wiley: New York, 1981.
23. Safran, S. A.; Grest, G. S.; Bug, A. L. R. Microemulsion Systems; Dekker: New York, 1987.
24. Hilfilker, R.; Eicke, H. F.; Geiger, S.; Furlur, G. Optical studies of critical phenomena in macrofluid-like three-component microemulsions J. Colloid Interface Sci. 1985, 105, 378-387
25. Peyrelasse, J.; Boned, C.; Saidi, Z. Percolation phenomenon in waterless microemulsions, Prog Colloid Polym. Sci. 1989, 79, 263-269
26. Kim, M. W.; Huang, J. S. Percolation like phenomena in oil-continuous microemulsions Phys. Rev. A 1986, 34, 719-722
27. Lang, J.; Lalem, N.; Zana, R. Droplet size and dynamics in water-in-oil microemulsions Colloids Surf. A 1992, 68, 199-206
28. Borkovec, M.; Eicke, H. F.; Hammerich, H.; Das Gupta, B. Two percolation processes in microemulsions J. Phys. Chem. 1988, 92, 206-211
29. Dutkiewicz, E.; Robinson, B. H. The electrical conductivity of a water-in-oil microemulsion system containing an ionic surfactant: Part I. Temperature effect J. Electroanal. Chem. 1988, 251, 11-20
30. Mukhopadhyay, L.; Bhattacharya, P. K.; Moulik, S. P. Additive effects on the percolation of water/AOT/decane microemulsion with reference to the mechanism of conduction Colloids Surf. A 1990, 50, 295-308
31. Paul, B. K.; Moulik, S. P. Biological microemulsions: Part III-The formation characteristics and transport properties of saffola-aerosol OT-hexylamine-water system Indian J. Biochem. Biophys. 1991, 28, 174-183
32. Paul, B. K.; Das, M. L.; Mukhopadhyay, D. C.; Moulik, S. P. Phase behaviour and physicochemical properties of a microemulsion obtained from an edible oil (saffola) Indian J. Chem. 1991, 30A, 328-334
33. Dogra, A.; Rakshit, A. K. Phase Behavior and Percolation Studies on Microemulsion System Water/SDS + Myrj45/Cyclohexane in the Presence of Various Alcohols as Cosurfactants J. Phys. Chem. B 2004, 108, 10053-10061
34. Wines, T. H.; Somasundaran, P. Effects of Adsorbed Block Copolymer and Comb-like Amphiphilic Polymers in Solution on the Electrical Percolation and Light Scattering Behavior of Reverse Microemulsions of Heptane/Water/AOT J. Colloid Interface Sci. 2002, 256, 183-189
35. Zhang, X. G.; Dong, J. F.; Zhang, G. Y.; Hong, X. L.; Li, X. F. The effect of additives on the water solubilization capacity and conductivity in n -pentanol microemulsions J. Colloid Interface Sci. 2005, 285, 336-341
36. Paul, B. K.; Mitra, R. K. Percolation phenomenon in mixed reverse micelles: The effect of additives J. Colloid Interface Sci. 2006, 295, 230-242
37. Fu, X.; Pan, Y.; Hu, Z. S.; Ma, Z. F. Conductivity study on the w/o microemulsion of a saponified mono (2-ethylhexyl) phosphoric acid extractant system Colloids Surf. A 1996, 110, 55-61