Low-Temperature Reductive Coupling of Formaldehyde on Rutile TiO2(110)

Journal of Physical Chemistry C

Volumn 119, Issue 32, 2015, Pages 18452-18457

  Zhu, Ke ^a   Xia, Yaobiao ^a   Tang, Miru ^b   Wang, Zhi Tao ^c   Lyubinetsky, Igor ^c   Ge, Qingfeng ^b   Dohnálek, Zdenek ^d   Park, Kenneth T ^a   Zhang, Zhenrong ^a  

^a BAYLOR UNIVERSITY   (United States)

^b SOUTHERN ILLINOIS UNIVERSITY   (United States)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^d PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DESORPTION; DISSOCIATION; ETHYLENE; OXIDE MINERALS; OXYGEN VACANCIES; REACTION PRODUCTS; SCANNING TUNNELING MICROSCOPY; SURFACE REACTIONS; TEMPERATURE; TITANIUM DIOXIDE;

BOUND SPECIES; COUPLING REACTION; DEFECT SITES; LOW TEMPERATURES; METHYLENE GROUPS; REDUCTIVE COUPLINGS; RUTILE TIO2; VARIABLE TEMPERATURE;

FORMALDEHYDE;

EID: 84939201491     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b05639     Document Type: Article

References (34)

1. Chheda, J. N.; Huber, G. W.; Dumesic, J. A. Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals Angew. Chem., Int. Ed. 2007, 46, 7164-7183 10.1002/anie.200604274
2. Pelaez, M.; Nolan, N. T.; Pillai, S. C.; Seery, M. K.; Falaras, P.; Kontos, A. G.; Dunlop, P. S. M.; Hamilton, J. W. J.; Byrne, J. A.; O'Shea, K. et al. A Review on the Visible Light Active Titanium Dioxide Photocatalysts for Environmental Applications Appl. Catal., B 2012, 125, 331-349 10.1016/j.apcatb.2012.05.036
3. 2(111) J. Am. Chem. Soc. 2012, 134, 18034-18045 10.1021/ja3074243
4. Furstner, A. Multicomponent Catalysis for Reductive Bond Formations Chem.-Eur. J. 1998, 4, 567-570 10.1002/(SICI)1521-3765(19980416)4:4<567::AID-CHEM567>3.0.CO;2-X
5. Hirao, T. Catalytic Reductive Coupling of Carbonyl Compounds-the Pinacol Coupling Reaction and Beyond Top. Curr. Chem. 2007, 279, 53-75 10.1007/128
6. 2(110) ACS Nano 2011, 5, 834-843 10.1021/nn103144u
7. Yasuo, M.; Sasahara, A.; Onishi, H. Acetone Adsorption on Oxidized and Reduced TiO2 (110): A Scanning Tunneling Microscope Study J. Phys. Chem. C 2010, 114, 14579-14582 10.1021/jp105876u
8. X(111) Thin Films J. Phys. Chem. C 2011, 115, 3385-3392 10.1021/jp110429s
9. 2(110) Surf. Sci. 2008, 602, 2238-2249 10.1016/j.susc.2008.04.045
10. 2(110) J. Phys. Chem. C 2013, 117, 9290-9300 10.1021/jp401838r
11. Shen, M.; Zaera, F. Coupling Reactions in Aldehydes Adsorbed on V(100) Single-Crystal Surfaces J. Am. Chem. Soc. 2009, 131, 8708-8713 10.1021/ja9023379
12. Queeney, K. T.; Arumainayagam, C. R.; Balaji, A.; Friend, C. M. Carbon-Carbon Coupling from Formaldehyde Reaction on Mo(110) Surf. Sci. 1998, 418, L31-L38 10.1016/S0039-6028(98)00754-7
13. Filler, M. A.; Musgrave, C. B.; Bent, S. F. Carbon-Oxygen Coupling in the Reaction of Formaldehyde on Ge(100)-2 × 1 J. Phys. Chem. C 2007, 111, 1739-1746 10.1021/jp064820v
14. Wang, H.; He, C.; Huai, L.; Liu, J. Formaldehyde Decomposition and Coupling on V(100): A First-Principles Study J. Phys. Chem. C 2012, 116, 10639-10648 10.1021/jp301364w
15. Hung, W. H.; Bernasek, S. L. The Adsorption and Decomposition of Formaldehyde and Formic Acid on the Clean and Modified Fe(100) Surface Surf. Sci. 1996, 346, 165-188 10.1016/0039-6028(95)00905-1
16. Shen, M.; Guo, H.; Zaera, F. Bond Forming Reactions Involving C-1 Moieties: Late Versus Early Transition Metal Surfaces Top. Catal. 2011, 54, 482-489 10.1007/s11244-011-9611-3
17. 2(110) Surface, Assisted by Bridge-Bonded Oxygen Atoms J. Phys. Chem. Lett. 2013, 4, 2668-2673 10.1021/jz401349q
18. Qiu, H.; Idriss, H.; Wang, Y.; Woell, C. Carbon-Carbon Bond Formation on Model Titanium Oxide Surfaces: Identification of Surface Reaction Intermediates by High-Resolution Electron Energy Loss Spectroscopy J. Phys. Chem. C 2008, 112, 9828-9834 10.1021/jp801327b
19. 2(110) Chem.-Eur. J. 2011, 17, 4496-4506 10.1002/chem.201002588
20. Senanayake, S. D.; Chong, S. V.; Idriss, H. The Reactions of Formaldehyde Over the Surfaces of Uranium Oxides. A Comparative Study between Polycrystalline and Single Crystal Materials Catal. Today 2003, 85, 311-320 10.1016/S0920-5861(03)00397-3
21. 2 (110) Model Catalyst J. Phys. Chem. C 2010, 114, 17017-17022 10.1021/jp102710m
22. Truong, C. M.; Wu, M. C.; Goodman, D. W. Adsorption of Formaldehyde on Nickel-Oxide Studied by Thermal Programmed Desorption and High-Resolution Electron-Energy-Loss Spectroscopy J. Am. Chem. Soc. 1993, 115, 3647-3653 10.1021/ja00062a032
23. 2(110) Surface: Photocatalysis Vs Thermal-Catalysis J. Phys. Chem. C 2014, 118, 20420-20428 10.1021/jp5061733
24. Zhou, J.; Mullins, D. R. Adsorption and Reaction of Formaldehyde on Thin-Film Cerium Oxide Surf. Sci. 2006, 600, 1540-1546 10.1016/j.susc.2006.02.009
25. 2(110) Top. Catal. 2015, 58, 103-113 10.1007/s11244-014-0349-6
26. 2(110) J. Phys. Chem. C 2015, 119, 14267-14272 10.1021/acs.jpcc.5b04781
27. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229 10.1016/S0167-5729(02)00100-0
28. Horcas, I.; Fernandez, R.; Gomez-Rodriguez, J. M.; Colchero, J.; Gomez-Herrero, J.; Baro, A. M. WSXM: A Software for Scanning Probe Microscopy and a Tool for Nanotechnology Rev. Sci. Instrum. 2007, 78, 013705 10.1063/1.2432410
29. 2(110): Evidence for Inequivalent Geminate OH Groups J. Phys. Chem. B 2006, 110, 21840-21845 10.1021/jp063619h
30. 2: A Combined High-Resolution STM and DFT Study Surf. Sci. 2005, 598, 226-245 10.1016/j.susc.2005.08.041
31. Minato, T.; Sainoo, Y.; Kim, Y.; Kato, H. S.; Aika, K.; Kawai, M.; Zhao, J.; Petek, H.; Huang, T.; He, W. et al. The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl Impurity Defects on Titanium Dioxide (110) Surface J. Chem. Phys. 2009, 130, 124502 10.1063/1.3082408
32. 2(110): The Dominant Role of Surface Defects in Oxygen Chemisorption J. Phys. Chem. C 2009, 113, 12407-12411 10.1021/jp901989x
33. 2(110) J. Phys. Chem. C 2009, 113, 14583-14586 10.1021/jp9037655
34. 2(110) ACS Nano 2013, 7, 10414-10423 10.1021/nn404934q