Photoinduced decomposition of formaldehyde on a TiO2(110) surface, assisted by bridge-bonded oxygen atoms

Journal of Physical Chemistry Letters

Volumn 4, Issue 16, 2013, Pages 2668-2673

  Xu, Chenbiao ^a   Yang, Wenshao ^a   Guo, Qing ^a   Dai, Dongxu ^a   Minton, Timothy K ^a,b   Yang, Xueming ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b MONTANA STATE UNIVERSITY   (United States)

Author keywords

bridge bonded oxygen; dioxymethylene; formaldehyde; photoinduced decomposition; temperature programmed desorption; titanium dioxide

Indexed keywords

BRIDGING OXYGEN; DIOXYMETHYLENE; LATTICE SITES; METHYL RADICAL; OXYGEN ATOM; PHOTO-INDUCED DECOMPOSITION; TI ATOMS; TIO;

ETHYLENE; FORMALDEHYDE; OXYGEN; TEMPERATURE PROGRAMMED DESORPTION; TITANIUM DIOXIDE;

ATOMS;

EID: 84882395910     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz401349q     Document Type: Article

References (53)

1. Hoffmann, M. R.; Martin, S. T.; Choi, W. Y.; Bahnemann, D. W. Environmental Applications of Semiconductor Photocatalysis Chem. Rev. 1995, 95, 69-96
2. 2 New Photochemical Processes Chem. Rev. 2006, 106, 4428-4453
3. 2(110) Surface: the Influence of Vacancies and Coadsorbed Species Faraday Discuss. 1999, 114, 313-319
4. 2(101) Surface: Behavior at Terraces, Steps, and Surface Oxygen Vacancies J. Am. Chem. Soc. 2008, 130, 370-381
5. 2 Photocatalysis Surf. Sci. Rep. 2011, 66, 185-297
6. 2(110) Chem. Soc. Rev. 2008, 37, 2328-2353
7. 2 Photocatalysis and Related Surface Phenomena Surf. Sci. Rep 2008, 63, 515-582
8. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229
9. Zang, L.; Lange, C.; Abraham, I.; Storck, S.; Maier, W. F.; Kisch, H. Amorphous Microporous Titania Modified with Platinum(IV) Chloride-A New Type of Hybrid Photocatalyst for Visible Light Detoxification J. Phys. Chem. B 1998, 102, 10765-10771
10. 2/UV Processes Sep. Purif. Technol. 2007, 54, 204-211
11. 2 Catalysts (M = Pd, Pt or Rh) Appl. Catal., B 2006, 67, 217-222
12. 2(110) Surf. Sci. 2000, 462, 68-76
13. 2(001) Surf. Sci. 2000, 447, 201-211
14. 2(110): Preparation and Anaerobic Photolysis J. Phys. Chem. B 2005, 109, 12417-12430
15. 2(110) J. Phys. Chem. B 2004, 108, 3592-3602
16. 2(110) Single-Crystal Surface J. Phys. Chem. C 2007, 111, 1764-1769
17. 2 (110): Competition for Sites Langmuir 2005, 21, 3443-3450
18. 2 J. Phys. Chem. C 2008, 112, 11433-14440
19. 2(110): Conversion to Acetate via Methyl Radical Ejection J. Phys. Chem. B 2005, 109, 12062-12070
20. 2(110) Surf. Sci. 2008, 602, 2238-2249
21. 2(110): Production and Chemical Detection of Active Sites J. Phys. Chem. 1994, 98, 11733-11738
22. 2(110) Surface J. Phys. Chem. B 2002, 106, 10680-10692
23. 2 (110) Catal. Today 2003, 85, 251-266
24. Lisachenko, A. A.; Mikhailov, R. V.; Basov, L. L.; Shelimov, B. N.; Che, M. Photocatalytic Reduction of NO by CO on Titanium Dioxide under Visible Light Irradiation J. Phys. Chem. C 2007, 111, 14440-14447
25. 3+ Defects in the Oxygen Chemistry on Titania Surfaces J. Am. Chem. Soc. 2011, 133, 6529-6532
26. 2(110) Chem. Sci. 2010, 1, 575-580
27. 2(110) J. Am. Chem. Soc. 2012, 134, 13366-13373
28. 2 J. Phys. Chem. B 1999, 103, 6957-6967
29. 2 J. Catal. 2000, 191, 318-325
30. Blount, M. C.; Buchholz, J. A.; Falconer, J. L. Photocatalytic Decomposition of Aliphatic Alcohols, Acids, and Esters J. Catal. 2001, 197, 303-314
31. 2 Catal. Lett. 2000, 70, 145-148
32. 2: Involvement of Lattice Oxygen J. Phys. Chem. B 2004, 108, 17857-17865
33. NIST Chemistry WebBook, webbook.nist.gov/chemistry.
34. 2(110) Chem.-Eur. J. 2011, 17, 4496-4506
35. 2 Rutile (110) and Anatase (001) Surfaces J. Phys. Chem. C 2012, 116, 8044-8053
36. Busca, G.; Lamotte, J.; Lavalley, J.-C.; Lorenzelli, V. FT-IR Study of the Adsorption and Transformation of Formaldehyde on Oxide Surfaces J. Am. Chem. Soc. 1987, 109, 5197-5202
37. 2 Supported Rh and Au Catalysts Appl. Catal., A 2004, 268, 9-16
38. 2-Supported Rh Catalysts Studied by FTIR and Mass Spectrometry J. Catal. 2004, 226, 183-191
39. Qiu, H.; Idriss, H.; Wang, Y.; Wöll, C. Carbon-Carbon Bond Formation on Model Titanium Oxide Surfaces: Identification of Surface Reaction Intermediates by High-Resolution Electron Energy Loss Spectroscopy J. Phys. Chem. C 2008, 112, 9828-9834
40. 2(110) Model Catalyst J. Phys. Chem. C 2010, 114, 17017-17022
41. 2(110) J. Am. Chem. Soc. 2012, 134, 14086-14098
42. 2 in Decomposing Volatile Aldehydes Bull. Korean Chem. Soc. 2008, 29, 494-496
43. Henderson, M. A. Complexity in the Decomposition of Formic Acid on the TiO2(110) Surface J. Phys. Chem. B 1997, 101, 221-229
44. 2(110) Surf. Sci. 2008, 602, 1507-1516
45. 2(110) Model Catalysts Surf. Sci. 2002, 511, 435-448
46. 2(110) J. Phys. Chem. B 2004, 108, 14316-14323
47. 2(110) by In Situ Scanning Tunneling Microscopic Observation J. Phys. Chem. B 2005, 109, 18831-18838
48. 2(110) J. Phys. Chem. B 2004, 108, 18932-18941
49. 2(110) J. Catal. 2008, 256, 287-292
50. 2(110) Phys. Chem. Chem. Phys. 2010, 12, 8084-8091
51. 2(110) J. Phys. Chem. C 2012, 116, 16541-16552
52. Bogumil, K.; Orphal, J.; Homann, T.; Voigt, S.; Spietz, P.; Fleischmann, O. C.; Vogel, A.; Hartmann, M.; Bovensmann, H.; Frerick, J. Measurements of Molecular Absorption Spectra with the SCIAMACHY pre-Flight Model: Instrument Characterization and Reference Data for Atmospheric Remote Sensing in the 230-2380 nm Region J. Photochem. Photobiol. A.: Photochem. 2003, 157, 167-184
53. 2(110), Initiated by Methanol Photocatalysis at 400 nm J. Phys. Chem. C 2013, 117, 5293-5300