Functional Group Effect on Char Formation, Flame Retardancy and Mechanical Properties of Phosphonate-Triazine-based Compound as Flame Retardant in Epoxy Resin

Industrial and Engineering Chemistry Research

Volumn 54, Issue 30, 2015, Pages 7309-7319

  You, Geyun ^a   Cheng, Zhiquan ^a   Tang, Yuying ^a   He, Hongwu ^a  

^a CENTRAL CHINA NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BLENDING; CALORIMETERS; CURING; EPOXY RESINS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; IMPACT STRENGTH; MECHANICAL PROPERTIES; NITROGEN; PHOSPHORUS; SMOKE ABATEMENT; THERMOGRAVIMETRIC ANALYSIS; THERMOSETS;

DIGLYCIDYL ETHER OF BISPHENOL-A; FLAME-RETARDANT MECHANISMS; FOURIER TRANSFORM INFRA RED (FTIR) SPECTROSCOPY; LIMITING OXYGEN INDEX; PEAK HEAT RELEASE RATES; PHOSPHORUS-NITROGEN SYNERGISM; SCANNING ELECTRONIC MICROSCOPY (SEM); VERTICAL BURNING TESTS;

FLAME RETARDANTS;

EID: 84938567247     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/acs.iecr.5b00315     Document Type: Article

References (27)

1. Sun, D. C.; Yao, Y. W. Synthesis of three novel phosphorus-containing flame retardants and their application in epoxy resins Polym. Degrad. Stab. 2011, 96, 1720 10.1016/j.polymdegradstab.2011.08.004
2. Liang, S. Y.; Neisius, N. M.; Gaan, S. Recent developments in flame retardant polymeric coatings Prog. Org. Coat. 2013, 76, 1642 10.1016/j.porgcoat.2013.07.014
3. Wang, X. D.; Zhang, Q. Synthesis, characterization, and cure properties of phosphorus-containing epoxy resins for flame retardance Eur. Polym. J. 2004, 40, 385 10.1016/j.eurpolymj.2003.09.023
4. Lin, C. H.; Chang, S. L.; Wei, T. P.; Ding, S. H.; Su, W. C. Facile, one-pot synthesis of phosphinate-substituted bisphenol A and its alkaline-stable diglycidyl ether derivative Polym. Degrad. Stab. 2010, 95, 1167 10.1016/j.polymdegradstab.2010.04.011
5. Ryan, J. J.; Rawn, D. F. K. The brominated flame retardants, PBDEs and HBCD, in Canadian human milk samples collected from 1992 to 2005; concentrations and trends Environ. Int. 2014, 70, 1 10.1016/j.envint.2014.04.020
6. Qi, H.; Li, W. L.; Liu, L. Y.; Song, W. W.; Ma, W. L.; Li, Y. F. Brominated flame retardants in the urban atmosphere of Northeast China: Concentrations, temperature dependence and gas-particle partitioning Sci. Total Environ. 2014, 491, 60 10.1016/j.scitotenv.2014.03.002
7. Ye, J. H.; Liang, G. Z.; Gu, A. J.; Zhang, Z. Y.; Han, J. P.; Yuan, L. Novel phosphorus-containing hyperbranched polysiloxane and its high performance flame retardant cyanate ester resins Polym. Degrad. Stab. 2013, 98, 597 10.1016/j.polymdegradstab.2012.11.015
8. Zhang, W. C.; He, X. D.; Song, T. L.; Jiao, Q. J.; Yang, R. J. The influence of the phosphorus-based flame retardant on the flame retardancy of the epoxy resins Polym. Degrad. Stab. 2014, 109, 209 10.1016/j.polymdegradstab.2014.07.023
9. Zhu, S. W.; Shi, W. F. Thermal degradation of a new flame retardant phosphate methacrylate polymer Polym. Degrad. Stab. 2003, 80, 217 10.1016/S0141-3910(02)00401-9
10. Chang, S. S.; Condon, B.; Graves, E.; Uchimiya, M.; Fortier, C.; Easson, M.; Wakelyn, P. Flame retardant properties of triazine phosphonates derivative with cotton fabric Fibers Polym. 2011, 12, 334 10.1007/s12221-011-0334-7
11. Wo, S.; Shamblee, D. Flame retardant phosphonate additives for thermoplastics. Patent EP 1651737 B1, 2014.
12. Failla, S.; Consiglio, G.; Finocchiaro, P. New Diamine Phosphonate Monomers as Flame-Retardant Additives for Polymers Phosphorus, Sulfur Silicon Relat. Elem. 2011, 186, 983 10.1080/10426507.2010.514307
13. Shu, W. J.; Perng, L. H.; Chin, W. K. Synthesis and Characteristics of Phosphonate-Containing Maleimide Polymers Polym. J. 2001, 33, 676 10.1295/polymj.33.676
14. Zhao, X. Synthesis and application of a durable phosphorus/silicon flame-retardant for cotton J. Text. Inst. 2010, 101, 538 10.1080/00405000802563677
15. Hoang, D. Q.; Kim, J.; Jang, B. N. Synthesis and performance of cyclic phosphorus-containing flame retardants Polym. Degrad. Stab. 2008, 93, 2042 10.1016/j.polymdegradstab.2008.02.017
16. Liu, Y.; Wang, Q. Synthesis of in situ encapsulated intumescent flame retardant and the flame retardancy in polypropylene Polym. Compos. 2007, 28, 163 10.1002/pc.20289
17. Li, B.; Xu, M. J. Effect of a novel charring-foaming agent on flame retardancy and thermal degradation of intumescent flame retardant polypropylene Polym. Degrad. Stab. 2006, 91, 1380 10.1016/j.polymdegradstab.2005.07.020
18. Nie, S. B.; Hu, Y.; Song, L.; He, Q. L.; Yang, D. D.; Chen, H. Synergistic effect between a char forming agent (CFA) and microencapsulated ammonium polyphosphate on the thermal and flame retardant properties of polypropylene Polym. Adv. Technol. 2008, 19, 1077 10.1002/pat.1082
19. Kaya, ̄.; Ylldlrlm, M.; Kamacl, M.; Avcl, A. New Poly(azomethine-urethane)s including melamine derivatives in the main chain: Synthesis and thermal characterization J. Appl. Polym. Sci. 2011, 120, 3027 10.1002/app.33441
20. Dai, J. F.; Li, B. Synthesis, thermal degradation, and flame retardance of novel triazine ring-containing macromolecules for intumescent flame retardant polypropylene J. Appl. Polym. Sci. 2010, 116, 2157 10.1002/app.31813
21. Ke, C. H.; Li, J.; Fang, K. Y.; Zhu, Q. L.; Zhu, J.; Yan, Q. W.; Wang, Y. Z. Synergistic effect between a novel hyperbranched charring agent and ammonium polyphosphate on the flame retardant and anti-dripping properties of polylactide Polym. Degrad. Stab. 2010, 95, 763 10.1016/j.polymdegradstab.2010.02.011
22. Gu, L. Q.; Chen, G. A.; Yao, Y. W. Two novel phosphorus-nitrogen-containing halogen-free flame retardants of high performance for epoxy resin Polym. Degrad. Stab. 2014, 108, 68 10.1016/j.polymdegradstab.2014.05.030
23. Chen, H.; Zhang, K.; Xu, J. Synthesis and characterizations of novel phosphorous-nitrogen containing poly(ether sulfone)s Polym. Degrad. Stab. 2011, 96, 197 10.1016/j.polymdegradstab.2010.11.015
24. You, G. Y.; Cheng, Z. Q.; Peng, H.; He, H. W. The synthesis and characterization of a novel phosphorus-nitrogen containing flame retardant and its application in epoxy resins J. Appl. Polym. Sci. 2014, 131, 1 10.1002/app.41079
25. Jin, C. F.; He, H. W. Synthesis and Herbicidal Activity of Novel Dialkoxyphosphoryl Aryl Methyl 2-(4,6-Dimethoxypyrimidin-2-yloxy) Benzoate Derivatives Phosphorus, Sulfur Silicon Relat. Elem. 2011, 186, 1397 10.1080/10426507.2010.511512
26. Liu, Y.; Zhang, Y.; Cao, Z. H.; Fang, Z. P. Synthesis of Three Novel Intumescent Flame Retardants Having Azomethine Linkages and Their Applications in EVA Copolymer Ind. Eng. Chem. Res. 2012, 51, 11059 10.1021/ie301562b
27. Chang, Y. L.; Wang, Y. Z.; Ban, D. M.; Zhao, G. M. A novel phosphorus-containing polymer as a highly effective flame retardant Macromol. Mater. Eng. 2004, 289, 703 10.1002/mame.200400064