Molecular catalysis science: Nanoparticle synthesis and instrument development for studies under reaction conditions

Journal of Catalysis

Volumn 328, Issue , 2015, Pages 91-101

  Gross, Elad ^a,b   Somorjai, Gabor A ^a,c  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Heterogeneous catalysis; In situ spectroscopy; IR spectroscopy; SFG vibrational spectroscopy; X ray spectroscopy

Indexed keywords

CATALYSIS; CATALYST SELECTIVITY; CATALYTIC OXIDATION; GOLD; GOLD NANOPARTICLES; HYDROGENATION; INFRARED SPECTROSCOPY; METAL NANOPARTICLES; OXIDATION; PLATINUM; SYNTHESIS (CHEMICAL); VIBRATIONAL SPECTROSCOPY; X RAY SPECTROSCOPY;

CATALYTIC NANOSTRUCTURES; IN-SITU CHARACTERIZATION; IN-SITU SPECTROSCOPY; INSTRUMENT DEVELOPMENT; NANOPARTICLE SYNTHESIS; PRODUCT SELECTIVITIES; SFG VIBRATIONAL SPECTROSCOPY; STRUCTURE REACTIVITY;

NANOCATALYSTS;

EID: 84937924149     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2014.12.031     Document Type: Article

References (77)

1. K. An, and G.A. Somorjai Size and shape control of metal nanoparticles for reaction selectivity in catalysis Chemcatchem 4 2012 1512 1524
2. K. Na, Q. Zhang, and G.A. Somorjai Colloidal metal nanocatalysts: synthesis, characterization, and catalytic applications J. Clust. Sci. 25 2014 83 114
3. H. Zhang, M.S. Jin, Y.J. Xiong, B. Lim, and Y.N. Xia Shape-controlled synthesis of Pd nanocrystals and their catalytic applications Accounts Chem. Res. 46 2013 1783 1794
4. B.R. Cuenya Synthesis and catalytic properties of metal nanoparticles: size, shape, support, composition, and oxidation state effects Thin Solid Films 518 2010 3127 3150
5. M.S. Chen, and D.W. Goodman Structure-activity relationships in supported Au catalysts Catal. Today 111 2006 22 33
6. S. Bordiga, E. Groppo, G. Agostini, J.A. van Bokhoven, and C. Lamberti Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques Chem. Rev. 113 2013 1736 1850
7. E. Gross, J.M. Krier, L. Heinke, and G.A. Somorjai Building bridges in catalysis science. Monodispersed metallic nanoparticles for homogeneous catalysis and atomic scale characterization of catalysts under reaction conditions Top. Catal. 55 2012 13 23
8. C. Lamberti, A. Zecchina, E. Groppo, and S. Bordiga Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy Chem. Soc. Rev. 39 2010 4951 5001
9. B.M. Weckhuysen Chemical imaging of spatial heterogeneities in catalytic solids at different length and time scales Angew. Chem. Int. Edit. 48 2009 4910 4943
10. F. Zaera Probing liquid/solid interfaces at the molecular level Chem. Rev. 112 2012 2920 2986
11. B.M. Weckhuysen Snapshots of a working catalyst: possibilities and limitations of in situ spectroscopy in the field of heterogeneous catalysis Chem. Commun. 2002 97 110
12. C.W. Jones, F. Tao, and M.V. Garland Introduction to special issue on Operando and in situ studies of catalysis Acs Catal. 2 2012 2444 2445
13. M.S. Chen, and D.W. Goodman Catalytically active gold: from nanoparticles to ultrathin films Accounts Chem. Res. 39 2006 739 746
14. H.J. Freund Model studies in heterogeneous catalysis Chem.-Eur. J. 16 2010 9384 9397
15. U. Landman, B. Yoon, C. Zhang, U. Heiz, and M. Arenz Factors in gold nanocatalysis: oxidation of CO in the non-scalable size regime Top. Catal. 44 2007 145 158
16. M.S. Chen, and D.W. Goodman The structure of catalytically active gold on titania Science 306 2004 252 255
17. M. Valden, X. Lai, and D.W. Goodman Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties Science 281 1998 1647 1650
18. B. Yoon, H. Hakkinen, U. Landman, A.S. Worz, J.M. Antonietti, S. Abbet, K. Judai, and U. Heiz Charging effects on bonding and catalyzed oxidation of CO on Au-8 clusters on MgO Science 307 2005 403 407
19. 2 hydrogenation over Rh by metal-oxides - the influence of oxide Lewis acidity and reducibility J. Catal. 149 1994 149 158
20. A.B. Boffa, C. Lin, A.T. Bell, and G.A. Somorjai Lewis acidity as an explanation for oxide promotion of metals - implications of its importance and limits for catalytic reactions Catal. Lett. 27 1994 243 249
21. 2 catalyst Science 333 2011 736 739
22. 2 via water as buffer layer: CO-IRAS and TPD characterization J. Phys. Chem. C 111 2007 16197 16201
23. M.C. Kung, R.J. Davis, and H.H. Kung Understanding Au-catalyzed low-temperature CO oxidation J. Phys. Chem. C 111 2007 11767 11775
24. H.J. Freund Metal-supported ultrathin oxide film systems as designable catalysts and catalyst supports Surf. Sci. 601 2007 1438 1442
25. C. Burda, X.B. Chen, R. Narayanan, and M.A. El-Sayed Chemistry and properties of nanocrystals of different shapes Chem. Rev. 105 2005 1025 1102
26. C.K. Tsung, J.N. Kuhn, W.Y. Huang, C. Aliaga, L.I. Hung, G.A. Somorjai, and P.D. Yang Sub-10 nm platinum nanocrystals with size and shape control: catalytic study for ethylene and pyrrole hydrogenation J. Am. Chem. Soc. 131 2009 5816 5822
27. 2 increases the activity of an for CO oxidation by two orders of magnitude Angew. Chem. Int. Edit. 43 2004 2538 2540
28. P. Sonstrom, and M. Baumer Supported colloidal nanoparticles in heterogeneous gas phase catalysis: on the way to tailored catalysts Phys. Chem. Chem. Phys. 13 2011 19270 19284
29. C. Aliaga, J.Y. Park, Y. Yamada, H.S. Lee, C.K. Tsung, P.D. Yang, and G.A. Somorjai Sum frequency generation and catalytic reaction studies of the removal of organic capping agents from Pt nanoparticles by UV-ozone treatment J. Phys. Chem. C 113 2009 6150 6155
30. J.M. Krier, W.D. Michalak, L.R. Baker, K. An, K. Komvopoulos, and G.A. Somorjai Sum frequency generation vibrational spectroscopy of colloidal platinum nanoparticle catalysts: disordering versus removal of organic capping J. Phys. Chem. C 116 2012 17540 17546
31. J.A. Lopez-Sanchez, N. Dimitratos, C. Hammond, G.L. Brett, L. Kesavan, S. White, P. Miedziak, R. Tiruvalam, R.L. Jenkins, A.F. Carley, D. Knight, C.J. Kiely, and G.J. Hutchings Facile removal of stabilizer-ligands from supported gold nanoparticles Nat. Chem. 3 2011 551 556
32. L.R. Baker, G. Kennedy, M. Van Spronsen, A. Hervier, X.J. Cai, S.Y. Chen, L.W. Wang, and G.A. Somorjai Furfuraldehyde hydrogenation on titanium oxide-supported platinum nanoparticles studied by sum frequency generation vibrational spectroscopy: acid-base catalysis explains the molecular origin of strong metal-support interactions J. Am. Chem. Soc. 134 2012 14208 14216
33. F. Tao, S. Dag, L.W. Wang, Z. Liu, D.R. Butcher, H. Bluhm, M. Salmeron, and G.A. Somorjai Break-up of stepped platinum catalyst surfaces by high CO coverage Science 327 2010 850 853
34. F. Tao, M.E. Grass, Y.W. Zhang, D.R. Butcher, J.R. Renzas, Z. Liu, J.Y. Chung, B.S. Mun, M. Salmeron, and G.A. Somorjai Reaction-driven restructuring of Rh-Pd and Pt-Pd core-shell nanoparticles Science 322 2008 932 934
35. M.A. Newton, and W. van Beek Combining synchrotron-based X-ray techniques with vibrational spectroscopies for the in situ study of heterogeneous catalysts: a view from a bridge Chem. Soc. Rev. 39 2010 4845 4863
36. E. Stavitski, and B.M. Weckhuysen Infrared and Raman imaging of heterogeneous catalysts Chem. Soc. Rev. 39 2010 4615 4625
37. 2: catalytic reaction and sum-frequency generation vibrational spectroscopy studies of crotonaldehyde hydrogenation Angew. Chem. Int. Edit. 53 2014 3405 3408
38. F. Gao, Y.L. Wang, and D.W. Goodman Reaction kinetics and polarization-modulation infrared reflection absorption spectroscopy (PM-IRAS) investigation of co oxidation over supported Pd-Au alloy catalysts J. Phys. Chem. C 114 2010 4036 4043
39. C. Rameshan, C. Weilach, W. Stadlmayr, S. Penner, H. Lorenz, M. Havecker, R. Blume, T. Rocha, D. Teschner, A. Knop-Gericke, R. Schlogl, D. Zemlyanov, N. Memmel, G. Rupprechter, and B. Klotzer Steam reforming of methanol on PdZn near-surface alloys on Pd(1 1 1) and Pd foil studied by in-situ XPS, LEIS and PM-IRAS J. Catal. 276 2010 101 113
40. X.Z. Shu, M. Zhang, Y. He, H. Frei, and F.D. Toste Dual visible light photoredox and gold-catalyzed arylative ring expansion J. Am. Chem. Soc. 136 2014 5844 5847
41. M. Zhang, M. de Respinis, and H. Frei Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst Nat. Chem. 6 2014 362 367
42. E. Gross, X.Z. Shu, S. Alayoglu, H.A. Bechtel, M.C. Martin, F.D. Toste, and G.A. Somorjai In situ IR and X-ray high spatial-resolution microspectroscopy measurements of multistep organic transformation in flow microreactor catalyzed by Au nanoclusters J. Am. Chem. Soc. 136 2014 3624 3629
43. E. Stavitski, M.H.F. Kox, I. Swart, F.M.F. de Groot, and B.M. Weckhuysen In situ synchrotron-based IR microspectroscopy to study catalytic reactions in zeolite crystals Angew. Chem. Int. Edit. 47 2008 3543 3547
44. A. Urakawa, N. Maeda, and A. Baiker Space- and time-resolved combined DRIFT and Raman spectroscopy: monitoring dynamic surface and bulk processes during NO(x) storage reduction Angew. Chem. Int. Edit. 47 2008 9256 9259
45. A.M. Beale, and B.M. Weckhuysen EXAFS as a tool to interrogate the size and shape of mono and bimetallic catalyst nanoparticles Phys. Chem. Chem. Phys. 12 2010 5562 5574
46. A.I. Frenkel, J.A. Rodriguez, and J.G.G. Chen Synchrotron techniques for in situ catalytic studies: capabilities, challenges, and opportunities Acs Catal. 2 2012 2269 2280
47. M. Ebner, F. Marone, M. Stampanoni, and V. Wood Visualization and quantification of electrochemical and mechanical degradation in Li ion batteries Science 342 2013 716 720
48. 3 catalyst bodies by a combination of X-ray absorption tomography and diagonal offset Raman spectroscopy Acs Catal. 3 2013 339 347
49. J. Ruiz-Martinez, A.M. Beale, U. Deka, M.G. O'Brien, P.D. Quinn, J.F.W. Mosselmans, and B.M. Weckhuysen Correlating metal poisoning with zeolite deactivation in an individual catalyst particle by chemical and phase-sensitive X-ray microscopy Angew. Chem. Int. Edit. 52 2013 5983 5987
50. I.D. Gonzalez-Jimenez, K. Cats, T. Davidian, M. Ruitenbeek, F. Meirer, Y.J. Liu, J. Nelson, J.C. Andrews, P. Pianetta, F.M.F. de Groot, and B.M. Weckhuysen Hard X-ray nanotomography of catalytic solids at work Angew. Chem. Int. Edit. 51 2012 11986 11990
51. W.D. Michalak, J.M. Krier, K. Komvopoulos, and G.A. Somorjai Structure sensitivity in Pt nanoparticle catalysts for hydrogenation of 1,3-butadiene: in situ study of reaction intermediates using SFG vibrational spectroscopy J. Phys. Chem. C 117 2013 1809 1817
52. K. An, S. Alayoglu, N. Musselwhite, S. Plamthottam, G. Melaet, A.E. Lindeman, and G.A. Somorjai Enhanced CO oxidation rates at the interface of mesoporous oxides and Pt nanoparticles J. Am. Chem. Soc. 135 2013 16689 16696
53. 2 studied with nanoparticle model catalysts on silica Top. Catal. 57 2014 500 507
54. V.V. Pushkarev, K.J. An, S. Alayoglu, S.K. Beaumont, and G.A. Somorjai Hydrogenation of benzene and toluene over size controlled Pt/SBA-15 catalysts: elucidation of the Pt particle size effect on reaction kinetics J. Catal. 292 2012 64 72
55. J.K. Norskov, T. Bligaard, B. Hvolbaek, F. Abild-Pedersen, I. Chorkendorff, and C.H. Christensen The nature of the active site in heterogeneous metal catalysis Chem Soc Rev 37 2008 2163 2171
56. L. Li, A.H. Larsen, N.A. Romero, V.A. Morozov, C. Glinsvad, F. Abild-Pedersen, J. Greeley, K.W. Jacobsen, and J.K. Norskov Investigation of catalytic finite-size-effects of platinum metal clusters J. Phys. Chem. Lett. 4 2013 222 226
57. C.J. Kliewer, C. Aliaga, M. Bieri, W.Y. Huang, C.K. Tsung, J.B. Wood, K. Komvopoulos, and G.A. Somorjai Furan hydrogenation over Pt(1 1 1) and Pt(1 0 0) single-crystal surfaces and Pt nanoparticles from 1 to 7 nm: a kinetic and sum frequency generation vibrational spectroscopy study J. Am. Chem. Soc. 132 2010 13088 13095
58. C.A. Witham, W.Y. Huang, C.K. Tsung, J.N. Kuhn, G.A. Somorjai, and F.D. Toste Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles Nat. Chem. 2 2010 36 41
59. C.H. Yoon, M.X. Yang, and G.A. Somorjai Hydrogenation of 1,3-butadiene on platinum surfaces of different structures Catal. Lett. 46 1997 37 41
60. E. Gross, and G.A. Somorjai The impact of electronic charge on catalytic reactivity and selectivity of metal-oxide supported metallic nanoparticles Top. Catal. 56 2013 1049 1058
61. A. Taguchi, and F. Schuth Ordered mesoporous materials in catalysis Micropor. Mesopor. Mat. 77 2005 1 45
62. D. Astruc, F. Lu, and J.R. Aranzaes Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis Angew. Chem. Int. Edit. 44 2005 7852 7872
63. E. Gross, J.H. Liu, S. Alayoglu, M.A. Marcus, S.C. Fakra, F.D. Toste, and G.A. Somorjai Asymmetric catalysis at the mesoscale: gold nanoclusters embedded in chiral self-assembled monolayer as heterogeneous catalyst for asymmetric reactions J. Am. Chem. Soc. 135 2013 3881 3886
64. E. Gross, J.H.C. Liu, F.D. Toste, and G.A. Somorjai Control of selectivity in heterogeneous catalysis by tuning nanoparticle properties and reactor residence time Nat. Chem. 4 2012 947 952
65. W.Y. Huang, J.H.C. Liu, P. Alayoglu, Y.M. Li, C.A. Witham, C.K. Tsung, F.D. Toste, and G.A. Somorjai Highly active heterogeneous palladium nanoparticle catalysts for homogeneous electrophilic reactions in solution and the utilization of a continuous flow reactor J. Am. Chem. Soc. 132 2010 16771 16773
66. Y.M. Li, J.H.C. Liu, C.A. Witham, W.Y. Huang, M.A. Marcus, S.C. Fakra, P. Alayoglu, Z.W. Zhu, C.M. Thompson, A. Arjun, K. Lee, E. Gross, F.D. Toste, and G.A. Somorjai A Pt-cluster-based heterogeneous catalyst for homogeneous catalytic reactions: X-ray absorption spectroscopy and reaction kinetic studies of their activity and stability against leaching J. Am. Chem. Soc. 133 2011 13527 13533
67. W. Huang, J.N. Kuhn, C.K. Tsung, Y. Zhang, S.E. Habas, P. Yang, and G.A. Somorjai Dendrimer templated synthesis of one nanometer Rh and Pt particles supported on mesoporous silica: catalytic activity for ethylene and pyrrole hydrogenation Nano Lett. 8 2008 2027 2034
68. A. Iglesias-Juez, A.M. Beale, K. Maaijen, T.C. Weng, P. Glatzel, and B.M. Weckhuysen A combined in situ time-resolved UV-Vis, Raman and high-energy resolution X-ray absorption spectroscopy study on the deactivation behavior of Pt and Pt-Sn propane dehydrogenation catalysts under industrial reaction conditions J. Catal. 276 2010 268 279
69. A. Patlolla, P. Baumann, W. Xu, S.D. Senanayake, J.A. Rodriguez, and A.I. Frenkel Characterization of metal-oxide catalysts in operando conditions by combining X-ray absorption and Raman spectroscopies in the same experiment Top. Catal. 56 2013 896 904
70. A.M. Beale, M.G. O'Brien, M. Kasunic, A. Golobic, M. Sanchez-Sanchez, A.J.W. Lobo, D.W. Lewis, D.S. Wragg, S. Nikitenko, W. Bras, and B.M. Weckhuysen Probing ZnAPO-34 self-assembly using simultaneous multiple in situ techniques J. Phys. Chem. C 115 2011 6331 6340
71. F.M.F. de Groot, E. de Smit, M.M. van Schooneveld, L.R. Aramburo, and B.M. Weckhuysen In-situ scanning transmission X-ray microscopy of catalytic solids and related nanomaterials ChemPhysChem 11 2010 951 962
72. J.R. Jinschek Advances in the environmental transmission electron microscope (ETEM) for nanoscale in situ studies of gas-solid interactions Chem. Commun. 50 2014 2696 2706
73. I.L.C. Buurmans, and B.M. Weckhuysen Heterogeneities of individual catalyst particles in space and time as monitored by spectroscopy Nat. Chem. 4 2012 873 886
74. K.H. Cats, I.D. Gonzalez-Jimenez, Y.J. Liu, J. Nelson, D. van Campen, F. Meirer, A.M.J. van der Eerden, F.M.F. de Groot, J.C. Andrews, and B.M. Weckhuysen X-ray nanoscopy of cobalt Fischer-Tropsch catalysts at work Chem. Commun. 49 2013 4622 4624
75. H.A. Bechtel, E.A. Muller, R.L. Olmon, M.C. Martin, and M.B. Raschke Ultrabroadband infrared nanospectroscopic imaging Proc. Natl. Acad. Sci. USA 111 2014 7191 7196
76. J. Stadler, T. Schmid, and R. Zenobi Nanoscale chemical imaging using top-illumination tip-enhanced Raman spectroscopy Nano. Lett. 10 2010 4514 4520
77. E.M. van Schrojenstein Lantman, T. Deckert-Gaudig, A.J.G. Mank, V. Deckert, and B.M. Weckhuysen Catalytic processes monitored at the nanoscale with tip-enhanced Raman spectroscopy Nature Nano 7 2012 583 586