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Volumn 2, Issue 4, 2015, Pages 378-382

CO-enabled rhenium hydride catalyst for directed C(sp2)-H bond alkylation with olefins

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; HYDRIDES; KETONES; OLEFINS;

EID: 84936851385     PISSN: 20524110     EISSN: 20524129     Source Type: Journal    
DOI: 10.1039/c4qo00329b     Document Type: Article
Times cited : (38)

References (44)
  • 29
    • 84886779743 scopus 로고    scopus 로고
    • The syntheses of rhenium carbonyl compounds from perrhenate usually require dangerous elevated pressures (100-300 atm), high temperatures and long reaction times (up to 2 days)
    • S. Sueki Y. Guo M. Kanai Y. Kuninobu Angew. Chem., Int. Ed. 2013 52 11879
    • (2013) Angew. Chem., Int. Ed. , vol.52 , pp. 11879
    • Sueki, S.1    Guo, Y.2    Kanai, M.3    Kuninobu, Y.4
  • 39
    • 84913582685 scopus 로고    scopus 로고
    • Less reductive hydrogen species derived from the decomposition of the rhenium hydride complex under standard conditions
    • D. Sarraf N. Richy J. Vidal J. Org. Chem. 2014 79 10945
    • (2014) J. Org. Chem. , vol.79 , pp. 10945
    • Sarraf, D.1    Richy, N.2    Vidal, J.3
  • 43
    • 84891856961 scopus 로고    scopus 로고
    • A large negative kinetic isotope effect is shown in the ESI Note that Kuninobu and Takai also investigated the KIE in the ortho-alkylation of 2-phenylpyridine with ethyl acrylate using rhenium carbonyl catalysis (see ref. 10a). In contrast to our system, they suggested that C-H oxidative addition was the rate determining step (KIE = 2.6)
    • S. Ma G. Villa P. S. Thuy-Boun A. Homs J.-Q. Yu Angew. Chem., Int. Ed. 2014 53 734
    • (2014) Angew. Chem., Int. Ed. , vol.53 , pp. 734
    • Ma, S.1    Villa, G.2    Thuy-Boun, P.S.3    Homs, A.4    Yu, J.-Q.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.