Mechanism of Copper-Catalyzed Hydroalkylation of Alkynes: An Unexpected Role of Dinuclear Copper Complexes

Journal of the American Chemical Society

Volumn 137, Issue 24, 2015, Pages 7747-7753

  Suess, Alison M ^a   Uehling, Mycah R ^a   Kaminsky, Werner ^a   Lalic, Gojko ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; COPPER; HYDROCARBONS; ORGANIC COMPOUNDS; REACTION INTERMEDIATES;

CATALYTIC CYCLES; CATALYTIC INTERMEDIATES; COPPER CATALYZED; DINUCLEAR COMPLEX; DINUCLEAR COPPER COMPLEXES; ELEMENTARY STEPS; MECHANISTIC STUDIES; N-HETEROCYCLIC CARBENES;

COPPER COMPOUNDS;

ALKALI METAL; ALKYNE DERIVATIVE; CARBENE; COPPER; COPPER COMPLEX; ELECTROPHILE; TRIFLUOROMETHANESULFONIC ACID;

ALKYLATION; ARTICLE; CATALYST; CHEMICAL REACTION; ELECTROPHILICITY; STOICHIOMETRY; X RAY CRYSTALLOGRAPHY;

EID: 84934902676     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b03086     Document Type: Article

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