Environmentally friendly hide unhairing: Enzymatic-oxidative unhairing as an alternative to use of lime and sodium sulfide

Process Safety and Environmental Protection

Volumn 93, Issue , 2015, Pages 9-17

  Andrioli, E ^a   Petry, L ^a   Gutterres, M ^a  

^a FEDERAL UNIVERSITY OF RIO GRANDE DO SUL   (Brazil)

Author keywords

Bacillus subtilis; Enzymes; Hair; Hide; Hydrogen peroxide; Unharing

Indexed keywords

EID: 84929209010     PISSN: 09575820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.psep.2014.06.001     Document Type: Article

References (39)

1. ABNT Determinação do teor de sólidos totais, fixos e voláteis em banhos de curtimento. NBR 14550 2000 3
2. A. Aluigi, C. Vineis, A. Varesano, G. Mazzuchetti, F. Ferrero, and C. Tonin Structure and properties of keratin/PEO blend nanofibres Eur. Polym. J. 44 2008 2465 2475
3. E. Andrioli, and M. Gutterres Associated use of enzymes and hydrogen peroxide for hair removal of cowhides JALCA 109 2014 41 48
4. ASTM Standart Test Method for Nitrogen Content (Kjeldahl) and Hide Substance Content of Leather. D2868 2010 5
5. S. Bronco, D. Catiello, G. D'elia, M. Salvador, M. Seggiani, and S. Vetolo Oxidative unhairing with hydrogen peroxide: development of an industrial scale process for high quality upper leather JALCA 100 2005 45 53
6. L. Chabaane, S. Tahiri, A. Albizane, M.E. Krati, M.L. Cervera, and M. de la Guardia Immobilization of vegetable tannins on tannery chrome shavings and their use for the removal of hexavalent chromium from contaminated water Chem. Eng. J. 174 2011 310 317
7. A. Crispim, and M. Mota Unhairing with enzymes J. Soc. Leather Technol. Chem. 87 2003 198 202
8. A. Dettmer, M.A.Z. Ayub, and M. Gutterres Hide unhairing and characterization of commercial enzymes used in leather manufacture Braz. J. Chem. Eng. 29 2011 373 380
9. A. Dettmer, J.C. Cavalleiro, E. Cavalli, D.M. Rossi, C.S. Gusatti, M.A.Z. Ayub, and M. Gutterres Optimization of the biotechnological process for hide unhairing in substitution of toxic sulfides Chem. Eng. Technol. 35 2012 803 810
10. A. Dettmer, E. Cavalli, M.A.Z. Ayub, and M. Gutterres Environmentally friendly hide unhairing enzymatic hide processing for the replacement of sodium sulfide and deliming J. Clean. Prod. 47 2013 11 18
11. A. Dettmer, E. Cavalli, M.A.Z. Ayub, and M. Gutterres Optimization of the unhairing leather processing with enzymes and the evaluation of inter-fibrillary proteins removal and environment-friendly alternative Bioprocess Biosyst. Eng. 35 2012 1317 1324
12. A. Dettmer, K.G.P. Nunes, M. Gutterres, and N.R. Marcílio Obtaining sodium chromate from ash produced by thermal treatment of leather wastes Chem. Eng. J. 160 2010 8 12
13. N.N. Fathima, R. Aravindhan, J.R. Rao, and B.U. Nair Stabilized protein waste as a source for removal of color from wastewaters J. Appl. Polym. Sci. 120 2011 1397 1402
14. J.L. Goingo, F.S. Lucas, F. Casarin, P. Heeb, and A. Brandelli Keratinolytic proteases of Bacillus species isolated from the Amazon basin showing remarkable de-hairing acitivity World J. Microb. Biotechnol. 23 2007 375 382
15. M. Gutterres Tendencias Emergentes en la Industria Del Cuero vol. 57 2006 Boletín Técnico de la Asociación Química Española de la Industria de Cuero Barcelona 22 27 (n.1)
16. E. Heidemann Fundamentals of Leather Manufaturing 1993 Eduard Roether KG Darmstadt 165 193
17. P. Hill, H. Brantley, and M. Van Dyke Some properties of keratin biomaterials: kerateines Biomaterials 31 2010 585 593
18. S. Jian, T. Wenyi, and C. Wuyong Kinetics of enzymatic unhairing by protease in leather industry J. Clean. Prod. 19 2011 325 331
19. A.M.S. Kamal, Y. Nomura, Y. Ishii, and K. Shirai Properties of bovine hair keratins solubilized with thioglycolate J. Am. Leather Chem. Assoc. 93 1998 272 282
20. I.C. Kantarli, and J. Yanik Activated carbon from leather shaving wastes and its application in removal of toxic materials J. Hazard. Mater. 179 2010 348 356
21. S. Li, J. Li, J. Yi, and Z. Shan Cleaner beam house processes trial on cattle sofa leather J. Clean. Prod. 18 2010 471 477
22. B. Madhan, J.R. Rao, and B.U. Nair Studies on the removal of interfibrillary materials. Part I: Removal of protein, proteoglycan, glycosaminoglycans from conventional beamhouse process JALCA 105 2010 145 149
23. W.N. Marmer, R.L. Dudley, and A.G. Gehring Rapid oxidative unhairing with alcaline hydrogen peroxide JALCA 98 2003 351 358
24. A. Marsal, J. Cot, E. Bartoli, T. Bosh, and A. Manich Oxidising unhairing process with hair recovery J. Soc. Leather Technol. Chem. 86 2002 30 33
25. J.M. Morera, E. Bartolí, M.D. Borràs, and S. Banaszak Oxidative unhairing of leathers: influence of several process parameters and environmental improvments JALCA 101 2006 347 354
26. J.S. Piccin, C.S. Gomes, L.A. Feris, and M. Gutterres Kinetics and isotherms of leather dye adsorption by tannery solid waste Chem. Eng. J. 183 2012 30 38
27. G.P.S. Priebe, and M. Gutterres Olein production from pre-fleshing residues of hides in tanneries Lat. Am. Appl. Res. 42 2012 71 76
28. G.P.S. Priebe, and M. Gutterres Gas chromatography as a tool for quality control in production of bovine tallow olein JALCA 107 2012 116 122
29. T. Senthilvelan, J. Kanagaraj, and A.B. Mandal Application of enzymes for dehairing of skins: cleaner leather processing Clean Technol. Environ. Policy 14 2012 889 897
30. B. Shi, X. Lu, and D. Sun Further investigations of oxidative unhairing using hydrogen peroxide JALCA 98 2003 185 192
31. S. Sivasubramanian, B.M. Manohar, A. Rojaram, and R. Puvanakrishman Ecofriendly lime and sulfide free enzymatic dehairing of skins and hides using a bacterial alcaline protease Chemosphere 70 2008 1015 1024
32. F.R. Souza, and M. Gutterres Application of enzymes in leather processing: a comparison between chemical and coenzymatic processes Braz. J. Chem. Eng. 29 2012 473 481
33. V.J. Sundar, A. Gnanamani, C. Muralidharan, N.K. Chandrababu, and A.B. Mandal Recovery and utilization of proteinous wastes of leather making: a review Rev. Environ. Sci. Biotechnol. 10 2011 151 163
34. S. Tahiri, A. Messaoudi, A. Albizane, M. Azzi, M. Bouhria, S.A. Younssi, J. Bennazha, and J. Mabrour Removal of dyes from aqueous solutions by adsorption on chrome-tanned solid wastes generated in the leather industry Water Qual. Res. J. Can. 38 2003 393 411
35. P. Thanikaivelan, J.R. Rao, B.U. Nair, and T. Ramasami Progress and recent trends in biotechnological methods for leather processing Trends Biotechnol. 22 4 2004 181 188
36. M-L. Touloumet Redução de odores nos curtumes Revista do Couro 216 2011 50 55
37. V. Valeika, K. Belaska, V. Valeikiene, and V. Kolodzeiskis An approach to cleaner production from hair burning to hair saving using a lime-free unhairing system J. Clean. Prod. 17 2009 214 221
38. R. Wang, C. Min, C. Haiming, and Z. Li Enzyme unhairing - an ecofriendly biotechnoligical process J. Soc. Leather Technol. Chem. 93 2009 51 55
39. C. Winter, F.R. Souza, and M. Gutterres Avaliação analítica de proteínas e gorduras para detecção de constituintes da pele em meios aquosos XIX Encontro Nacional da ABQTIC, 2011 XIX Encontro Nacional da ABQTIC, Franca 2011