Enantioselective Lewis Acid Catalysis in Intramolecular [2 + 2] Photocycloaddition Reactions: A Mechanistic Comparison between Representative Coumarin and Enone Substrates

Journal of the American Chemical Society

Volumn 137, Issue 15, 2015, Pages 5170-5176

  Brimioulle, Richard ^a   Bauer, Andreas ^a   Bach, Thorsten ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ENANTIOSELECTIVITY; FUNCTIONAL GROUPS; REACTION RATES;

CHIRAL LEWIS ACID; ENANTIOSELECTIVE; HIGH ENANTIOSELECTIVITY; HIGH EXTINCTION COEFFICIENTS; IRRADIATION WAVELENGTH; LEWIS ACID CATALYSIS; LEWIS ACID-CATALYZED REACTIONS; [2 + 2] PHOTOCYCLOADDITION;

CATALYSIS;

ALKENE; COUMARIN DERIVATIVE; KETONE DERIVATIVE; LEWIS ACID; METHYL GROUP; PYRIDONE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHIRALITY; COMPLEX FORMATION; CYCLOADDITION; DIASTEREOISOMER; ENANTIOSELECTIVITY; IRRADIATION; PHOTOCHEMISTRY; QUANTUM YIELD; REACTION ANALYSIS; STEREOCHEMISTRY; ULTRAVIOLET SPECTROSCOPY;

EID: 84928494437     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b01740     Document Type: Article

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