Synthesis of organoclays: A critical review and some unresolved issues

Applied Clay Science

Volumn 100, Issue C, 2014, Pages 22-28

  He, Hongping ^a   Ma, Lingya ^a,e   Zhu, Jianxi ^a   Frost, Ray L ^b   Theng, Benny K G ^c   Bergaya, Faïza ^d  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

^b QUEENSLAND UNIVERSITY OF TECHNOLOGY   (Australia)

^c LANDCARE RESEARCH   (New Zealand)

^d UNIVERSITÉ D'ORLÉANS   (France)

^e UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Basal spacing; Cation exchange capacity (CEC); Locking effect; Organoclay (OC); Pillared interlayered clay (PILC); Silane grafting

Indexed keywords

GRAFTING (CHEMICAL); LOCKS (FASTENERS); NANOCOMPOSITES; ORGANOCLAY; POSITIVE IONS;

BASAL SPACING; CATION EXCHANGE CAPACITIES; LOCKING EFFECTS; PILLARED INTER-LAYERED CLAYS; SILANE-GRAFTING;

CLAY MINERALS;

EID: 84927804856     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2014.02.008     Document Type: Article

References (93)

1. Annabi-Bergaya F. Layered clay minerals. Basic research and innovative composite applications. Microporous Mesoporous Mater. 2008, 107:141-148.
2. Bergaya F., Lagaly G. Surface modification of clay minerals. Appl. Clay Sci. 2001, 19:1-3.
3. Bergaya F., Lagaly G. Intercalation Processes of Layered Minerals, in Layered Mineral Structures and Their Application in Advanced Technology. EMU notes in Mineralogy 2011, vol. 11:259-284. Chapter 6. M.F. Brigatti, A. Mottana (Eds.).
4. Bergaya F., Lagaly G. General Introduction: Clays, Clay Minerals and Clay Science Chapter 1, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5A:1-19. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
5. Bergaya F., Mandalia T., Amigouët P. A brief survey on CLAYPEN and nanocomposites based on unmodified PE and organo-pillared clays. Colloid Polym. Sci. 2005, 283:773-782.
6. Bergaya F., Jaber M., Lambert J-F. Organophilic Clay Minerals, Chapter 2. Rubber-Clay Nanocomposites: Science, Technology and Applications 2011, 45-86. John Willey & Sons. M. Galimberti (Ed.).
7. Bergaya F., Jaber M., Lambert J-F. Clays and Clay Minerals, Chapter 1. Rubber-Clay Nanocomposites: Science, Technology and Applications 2011, 3-44. John Willey & Sons. M. Galimberti (Ed.).
8. Bergaya F., Jaber M., Lambert J-F. Clay Minerals as Layered Nanofillers for (Bio)Polymers, Chapter 3. Environmental Silicate Nano-biocomposites 2012, 41-76. Springer-Verlag, London. L. Averous, E. Pollet (Eds.).
9. Bergaya F., Detellier C., Lambert J-F., Lagaly G. Introduction on Clay Polymer Nanocomposites (CPN), Chapter 13, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5A:655-677. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
10. Bergaya F., Lagaly G., Vayer M. Cation and Anion Exchange Chapter 2.11, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5B:333-359. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
11. Bouberka Z., Kacha S., Kameche M., Elmaleh S., Derriche Z. Sorption study of an acid dye from an aqueous solutions using modified clays. J. Hazard. Mater. 2005, 119:117-124.
12. Bouberka Z., Khenifi A., Mahamed H.A., Haddou B., Belkaid N., Bettahar N., Derriche Z. Adsorption of Supranol Yellow 4GL from aqueous solution by surfactant-treated aluminum/chromium-intercalated bentonite. J. Hazard. Mater. 2009, 162:378-385.
13. Brigatti M.F., Galan E., Theng B.K.G. Structure and Mineralogy of Clay Minerals, Chapter 2, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5A:20-81. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
14. Carrizosa M.J., Rice P.J., Koskinen W.C., Carrizosa I., Hermosin M.D. Sorption of isoxaflutole and DKN on organoclays. Clays Clay Miner. 2004, 52:341-349.
15. Chen D. Modification of Microporous Mineral Materials and Adsorption Mechanism of Organic Contaminants Onto the Materials 2008, (Ph.D. Thesis), Graduate University of the Chinese Academy of Sciences, China.
16. Choy J.H., Kwak S.Y., Han Y.S., Kim B.W. New organo-montmorillonite complexes with hydrophobic and hydrophilic functions. Mater. Lett. 1997, 33:143-147.
17. Daniel L.M., Frost R.L., Zhu H.Y. Edge-modification of laponite with dimethyl-octylmethoxysilane. J. Colloid Interface Sci. 2008, 321:302-309.
18. Dentel S.K., Jamrah A.I., Sparks D.L. Sorption and cosorption of 1,2,4-trichlorobenzene and tannic acid by organo-clays. Water Res. 1998, 32:3689-3697.
19. Fatimah I., Huda T. Preparation of cetyltrimethylammonium intercalated Indonesian montmorillonite for adsorption of toluene. Appl. Clay Sci. 2013, 74:115-120.
20. Feng X.Y., Hu G.J., Meng X.F., Ding Y.F., Zhang S.M., Yang M.S. Influence of ethanol addition on the modification of montmorillonite by hexadecyl trimethylammonium bromide. Appl. Clay Sci. 2009, 45:239-243.
21. Gammoudi S., Frini-Srasra N., Srasra E. Influence of exchangeable cation of smectite on HDTMA adsorption: equilibrium, kinetic and thermodynamic studies. Appl. Clay Sci. 2012, 69:99-107.
22. 27Al MAS NMR study of the thermal transformations of kaolinite from North China. Clay Miner. 2003, 38:551-559.
23. He H.P., Ding Z., Zhu J.X., Yuan P., Xi Y.F., Yang D., Frost R.L. Thermal characterization of surfactant-modified montmorillonites. Clays Clay Miner. 2005, 53:287-293.
24. +-modified montmorillonite and its influence on sorption characteristics. Clays Clay Miner. 2006, 54:689-696.
25. + surfactant loading. Appl. Clay Sci. 2006, 31:262-271.
26. He H.P., Ma Y.H., Zhu J.X., Yuan P., Qing Y.H. Organoclays prepared from montmorillonites with different cation exchange capacity and surfactant configuration. Appl. Clay Sci. 2010, 48:67-72.
27. He H.P., Tao Q., Zhu J.X., Yuan P., Shen W., Yang S.Q. Silylation of clay mineral surfaces. Appl. Clay Sci. 2013, 71:15-20.
28. He H.P., Li T., Tao Q., Chen T.H., Zhang D., Zhu J.X., Yuan P., Zhu R.L. Aluminum ion occupancy in the structure of synthetic saponites: effect on crystallinity. Am. Mineral. 2014, 99:109-116.
29. Herrera N.N., Letoffe J.M., Putaux J.L., David L., Bourgeat-Lami E. Aqueous dispersions of silane-functionalized laponite clay platelets. A first step toward the elaboration of water-based polymer/clay nanocomposites. Langmuir 2004, 20:1564-1571.
30. Herrera N.N., Letoffe J.M., Reymond J.P., Bourgeat-Lami E. Silylation of laponite clay particles with monofunctional and trifunctional vinyl alkoxysilanes. J. Mater. Chem. 2005, 15:863-871.
31. Heylen I., Vanhoof C., Vansant E.F. Preadsorption of organic-compounds on iron oxide-pillared clays. Microporous Mater. 1995, 5:53-60.
32. Ishii R., Nakatsuji M., Ooi K. Preparation of highly porous silica nanocomposites from clay mineral: a new approach using pillaring method combined with selective leaching. Microporous Mesoporous Mater. 2005, 79:111-119.
33. Janek M., Lagaly G. Interaction of a cationic surfactant with bentonite: a colloid chemistry study. Colloid Polym. Sci. 2003, 281:293-301.
34. Jović-Jovičić N., Milutinović-Nikolić A., Banković P., Mojović Z., Žunić M., Gržetić I., Jovanović D. Organo-inorganic bentonite for simultaneous adsorption of Acid Orange 10 and lead ions. Appl. Clay Sci. 2010, 47:452-456.
35. Khalaf H., Bouras O., Perrichon V. Synthesis and characterization of Al-pillared and cationic surfactant modified Al-pillared Algerian bentonite. Microporous Mater. 1997, 8:141-150.
36. Klapyta Z., Fujita T., Iyi N. Adsorption of dodecyl- and octadecyltrimethylammonium ions on a smectite and synthetic micas. Appl. Clay Sci. 2001, 19:5-10.
37. Koswojo R., Utomo R.P., Ju Y.H., Ayucitra A., Soetaredjo F.E., Sunarso J., Ismadji S. Acid Green 25 removal from wastewater by organo-bentonite from Pacitan. Appl. Clay Sci. 2010, 48:81-86.
38. Lagaly G. Characterization of clays by organic compounds. Clay Miner. 1981, 16:1-21.
39. Lagaly G., Dékany I. Colloid Clay Science. Chapter 8, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5A:243-345. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
40. Lagaly G., Ogawa M., Dékany I. Clay Minerals Organic Interactions. Chapter 10.3, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5A:435-505. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
41. Lambert J.F., Bergaya F. Smectites-Polymer Nanocomposites, Chapter 13.1, Handbook of Clay Science. Developments in Clay Science 2013, vol. 5A:699-706. Elsevier. 2nd edition. F. Bergaya, G. Lagaly (Eds.).
42. Lee S.Y., Kim S.J. Expansion characteristics of organoclay as a precursor to nanocomposites. Colloid Surf. A 2002, 211:19-26.
43. Lee J.J., Choi J.Y., Park J.W. Simultaneous sorption of lead and chlorobenzene by organobentonite. Chemosphere 2002, 49:1309-1315.
44. Lee S.Y., Kim S.J., Chung S.Y., Jeong C.H. Sorption of hydrophobic organic compounds onto organoclays. Chemosphere 2004, 55:781-785.
45. Li Y.Q., Ishida H. Concentration-dependent conformation of alkyl tail in the nanoconfined space: hexadecylamine in the silicate galleries. Langmuir 2003, 19:2479-2484.
46. Li J.F., Li Y.M., Lu J.H. Adsorption of herbicides 2,4-D and acetochlor on inorganic-organic bentonites. Appl. Clay Sci. 2009, 46:314-318.
47. Liu N., Wang M.X., Liu M.M., Liu F., Weng L., Koopal L.K., Tan W.F. Sorption of tetracycline on organo-montmorillonites. J. Hazard. Mater. 2012, 225-226:28-35.
48. Ma Y.H. Factors Controlling and Affecting the Interlayer Structure and Properties of Organo (Pillared) Montmorillonites 2010, (Master's Thesis), Graduate University of the Chinese Acadamy of Sciences, China.
49. Ma L.Y., Zhou Q., Li T., Tao Q., Zhu J.X., Yuan P., Zhu R.L., He H.P. Investigation of structure and thermal stability of surfactant-modified Al-pillared montmorillonite. J. Therm. Anal. Calorim. 2014, 115:219-225.
50. Mahadevaiah N., Vijayakumar B., Hemalatha K., Prakash B.S.J. Uptake of permanganate from aqueous environment by surfactant modified montmorillonite batch and fixed bed studies. Bull. Mater. Sci. 2011, 34:1675-1681.
51. Mandalia T., Bergaya F. Organo clay mineral-melted polyolefin nanocomposites. Effect of surfactant/CEC ratio. J. Phys. Chem. Solids 2006, 67:836-845.
52. Marsal A., Bautista E., Ribosa I., Pons R., García M.T. Adsorption of polyphenols in wastewater by organo-bentonites. Appl. Clay Sci. 2009, 44:151-155.
53. Michot L.J., Pinnavaia T.J. Improved synthesis of alumina-pillared montmorillonite by surfactant modification. Chem. Mater. 1992, 4:1433-1437.
54. Mojović Z., Jović-Jovičić N., Milutinović-Nikolić A., Banković P., Rabi-Stanković A.A., Jovanović D. Phenol determination on HDTMA-bentonite-based electrodes. J. Hazard. Mater. 2011, 194:178-184.
55. Murray H.H. Traditional and new applications for kaolin, smectite, and palygorskite: a general overview. Appl. Clay Sci. 2000, 17:207-221.
56. Ouellet-Plamondon C., Lynch R.J., Al-Tabbaa A. Comparison between granular pillared, organo- and inorgano-organo-bentonites for hydrocarbon and metal ion adsorption. Appl. Clay Sci. 2012, 67-68:91-98.
57. Paiva L., Morales A., Valenzueladiaz F. Organoclays: properties, preparation and applications. Appl. Clay Sci. 2008, 42:8-24.
58. Park M., Shim I.K., Jung E.Y., Choy J.H. Modification of external surface of laponite by silane grafting. J. Phys. Chem. Solids 2004, 65:499-501.
59. Piscitelli F., Posocco P., Toth R., Fermeglia M., Pricl S., Mensitieri G., Lavorgna M. Sodium montmorillonite silylation: unexpected effect of the aminosilane chain length. J. Colloid Interface Sci. 2010, 351:108-115.
60. 13-intercalated/Al-pillared montmorillonite. Appl. Clay Sci. 2010, 50:546-553.
61. Ray S.S., Okamoto M. Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog. Polym. Sci. 2003, 28:1539-1641.
62. Sánchez-Camazano M., Sánchez-Martín M.J. Organo-clays as adsorbents for azinphosmethyl and dichlorvos in aqueous medium. Water Air Soil Pollut. 1994, 74:19-28.
63. Shen W., He H.P., Zhu J.X., Yuan P., Frost R.L. Grafting of montmorillonite with different functional silanes via two different reaction systems. J. Colloid Interface Sci. 2007, 313:268-273.
64. Stockmeyer M.R. Adsorption of organic compounds on organophilic bentonites. Appl. Clay Sci. 1991, 6:39-57.
65. Su L.N., Tao Q., He H.P., Zhu J.X., Yuan P. Locking effect: a novel insight in the silylation of montmorillonite surfaces. Mater. Chem. Phys. 2012, 136:292-295.
66. Swartzen-Allen S.L., Matijevic E. Surface and colloid chemistry of clays. Chem. Rev. 1974, 74:385-400.
67. Tahani A., Karroua M., El Farissi M., Levitz P., Van Damme H., Bergaya F., Margulies L. Adsorption of phenol and its chlorine derivatives on PILCs and organo-PILCs. J. Chim. Phys. 1999, 96:464-469.
68. Tahani A., Karroua M., Van Damme H., Levitz P., Bergaya F. Adsorption of a cationic surfactant on Na-Montmorillonite: inspection of adsorption layer by X-ray and fluorescence spectroscopies. J. Colloid Interface Sci. 1999, 216:242-249.
69. Theng B.K.G. The Chemistry of Clay-Organic Reactions 1974, Adam Hilger, London.
70. Theng B.K.G. Formation and Properties of Clay-Polymer Complexes 2012, Elsevier, Amsterdam. 2nd edition.
71. Theng B.K.G., Churchman G.J., Gates W.P., Yuan G. Organically Modified Clays for Pollutant Uptake and Environmental Protection. Soil Mineral-Microbe-Organic Interactions: Theories and Applications 2008, 145-174. Springer-Verlag, Berlin. Q. Huang, P.M. Huang, A. Violante (Eds.).
72. Vaia R.A., Teukolsky R.K., Giannelis E.P. Interlayer structure and molecular environment of alkylammonium layered silicates. Chem. Mater. 1994, 6:1017-1022.
73. Vianna M., Dweck J., Kozievitch V.F.J., Valenzuela-Diaz F.R., Buchler P.M. Characterization and study of sorptive properties of differently prepared organoclays from a Brazilian natural bentonite. J. Therm. Anal. Calorim. 2005, 82:595-602.
74. Volzone C., Rinaldi J.O., Ortiga J. Retention of gases by hexadecyltrimethylammonium-montmorillonite clays. J. Environ. Manage. 2006, 79:247-252.
75. +-pillared bentonite. J. Radioanal. Nucl. Chem. 2012, 293:519-528.
76. Xi Y., Martens W., He H.P., Frost R.L. Thermogravimetric analysis of organoclays intercalated with the surfactant octadecyltrimethylammonium bromide. J. Therm. Anal. Calorim. 2005, 81:91-97.
77. Xie W., Xie R.C., Pan W.P., Hunter D., Koene B., Tan L.S., Vaia R. Thermal stability of quaternary phosphonium modified montmorillonites. Chem. Mater. 2002, 14:4837-4845.
78. Xin X.D., Wang J., Yu H.Q., Du B., Wei Q., Yan L.G. Removal of o-nitrobenzoic acid by adsorption on to a new organoclay: montmorillonite modified with HDTMA microemulsion. Environ. Technol. 2011, 32:447-454.
79. Yan L.G., Wang J., Yu H.Q., Wei Q., Du B., Shan X.Q. Adsorption of benzoic acid by CTAB exchanged montmorillonite. Appl. Clay Sci. 2007, 37:226-230.
80. Yílmaz N., Yapar S. Adsorption properties of tetradecyl- and hexadecyl trimethylammonium bentonites. Appl. Clay Sci. 2004, 27:223-228.
81. Zaghouane-Boudiaf H., Boutahala M. Preparation and characterization of organo-montmorillonites. Application in adsorption of the 2,4,5-trichlorophenol from aqueous solution. Adv. Powder Technol. 2011, 22:735-740.
82. Zhao H., Vance G.F. Sorption of trichloroethylene by organo-clays in the presence of humic substances. Water Res. 1998, 32:3710-3716.
83. Zhou Q., Frost R.L., He H.P., Xi Y.F. Changes in the surfaces of adsorbed para-nitrophenol on HDTMA organoclay- The XRD and TG study. J. Colloid Interface Sci. 2007, 307(1):50-55.
84. Zhou Q., Deng S., Yu Q., Zhang Q., Yu G., Huang J., He H.P. Sorption of perfluorooctane sulfonate on organo-montmorillonites. Chemosphere 2010, 78:688-694.
85. Zhu L.Z., Chen B.L. Sorption behavior of p-nitrophenol on the interface between anion-cation organobentonite and water. Environ. Sci. Technol. 2000, 34:2997-3002.
86. Zhu L.Z., Chen B.L., Shen X.Y. Sorption of phenol, p-nitrophenol, and aniline to dual-cation organobentonites from water. Environ. Sci. Technol. 2000, 34:468-475.
87. + pillared montmorillonites. Chin. Sci. Bull. 2003, 48:368-372.
88. Zhu L.Z., Tian S.L., Zhu J.X., Shi Y. Silylated pillared clay (SPILC): a novel bentonite-based inorgano-organo composite sorbent synthesized by integration of pillaring and silylation. J. Colloid Interface Sci. 2007, 315:191-199.
89. Zhu J.X., Zhu L.Z., Zhu R.L., Chen B.L. Microstructure of organo-bentonites in water and the effect of steric hindrance on the uptake of organic compounds. Clays Clay Miner. 2008, 56:144-154.
90. 13 intercalated bentonites. J. Hazard. Mater. 2009, 168:1590-1594.
91. 13 into montmorillonite. J. Colloid Interface Sci. 2009, 335:77-83.
92. Zhu J.X., Qing Y.H., Wang T., Zhu R.L., Wei J.M., Tao Q., Yuan P., He H.P. Preparation and characterization of zwitterionic surfactant-modified montmorillonites. J. Colloid Interface Sci. 2011, 360:386-392.
93. Zidelkheir B., Abdelgoad M. Effect of surfactant agent upon the structure of montmorillonite X-ray diffraction and thermal analysis. J. Therm. Anal. Calorim. 2008, 94:181-187.