Silylation of clay mineral surfaces

Applied Clay Science

Volumn 71, Issue , 2013, Pages 15-20

  He, Hongping ^a   Tao, Qi ^a   Zhu, Jianxi ^a   Yuan, Peng ^a   Shen, Wei ^a   Yang, Shuqin ^a  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

Author keywords

Clay mineral surface; Kaolinite; Montmorillonite; Silane grafting; Silylation

Indexed keywords

GRAFTING REACTIONS; INTERLAYER SURFACE; MINERAL SURFACES; REACTION CONDITIONS; REACTION TEMPERATURE; SILANE-GRAFTING; SILYLATIONS; SURFACE HYDROXYL;

CLAY MINERALS; FUNCTIONAL GROUPS; KAOLINITE; MOLECULES; SYNTHESIS (CHEMICAL);

GRAFTING (CHEMICAL);

KAOLINITE; MINERAL PROPERTY; MOLECULAR ANALYSIS; MONTMORILLONITE; SWELLING; TEMPERATURE EFFECT;

EID: 84870665103     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2012.09.028     Document Type: Review

References (67)

1. Avila L.R., de Faria E.H., Ciuffi K.J., Nassar E.J., Calefi P.S., Vicente M.A., Trujillano R. New synthesis strategies for effective functionalization of kaolinite and saponite with silylating agents. Journal of Colloid and Interface Science 2010, 341:186-193.
2. Bergaya F., Lagaly G. Surface modification of clay minerals. Applied Clay Science 2001, 19:1-3.
3. Bergaya F., Theng B.K.G., Lagaly G. Handbook of Clay Science 2006, Elsevier, Amsterdam; London.
4. Brandt K.B., Elbokl T.A., Detellier C. Intercalation and interlamellar grafting of polyols in layered aluminosilicates. d-Sorbitol and adonitol derivatives of kaolinite. Journal of Materials Chemistry 2003, 13:2566-2572.
5. Breen C., Madejova J., Komadel P. Characterisation of moderately acid-treated, size-fractionated montmorillonites using IR and MAS NMR spectroscopy and thermal analysis. Journal of Materials Chemistry 1995, 5:469-474.
6. Breen C., Watson R., Madejova J., Komadel P., Klapyta Z. Acid-activated organoclays: preparation, characterization and catalytic activity of acid-treated tetraalkylammonium-exchanged smectites. Langmuir 1997, 13:6473-6479.
7. Burch R. Pillared interlayer clays. Applied Catalysis 1984, 12:284-285.
8. Carrado K.A. Synthetic organo- and polymer-clays: preparation, characterization, and materials applications. Applied Clay Science 2000, 17:1-23.
9. Carrado K.A., Xu L., Csencsits R., Muntean J.V. Use of organo- and alkoxysilanes in the synthesis of grafted and pristine clays. Chemistry of Materials 2001, 13:3766-3773.
10. Charnay C., Lagerge S., Partyka S. Assessment of the surface heterogeneity of talc materials. Journal of Colloid and Interface Science 2001, 233:250-258.
11. da Fonseca M.G., Airoldi C. New layered inorganic-organic nanocomposites containing n-propylmercapto copper phyllosilicates. Journal of Materials Chemistry 2000, 10:1457-1463.
12. da Fonseca M.G., Airoldi C. New amino-inorganic hybrids from talc silylation and copper adsorption properties. Materials Research Bulletin 2001, 36:277-287.
13. da Fonseca M.G., Airoldi C. Inorganic-organic hybrids derived from the reaction of phyllosilicates with organosilanes. Quimica Nova 2003, 26:699-707.
14. da Fonseca M.G., Barone J.S., Airoldi C. Self-organized inorganic-organic hybrids induced by silylating agents with phyllosilicate-like structure and the influence of the adsorption of cations. Clays and Clay Minerals 2000, 48:638-647.
15. da Fonseca M.G., Silva C.R., Barone J.S., Airoldi C. Layered hybrid nickel phyllosilicates and reactivity of the gallery space. Journal of Materials Chemistry 2000, 10:789-795.
16. Daniel L.M., Frost R.L., Zhu H.Y. Edge-modification of laponite with dimethyl-octylmethoxysilane. Journal of Colloid and Interface Science 2008, 321:302-309.
17. de Faria E.H., Ciuffi K.J., Nassar E.J., Vicente M.A., Trujillano R., Calefi P.S. Novel reactive amino-compound: tris(hydroxymethyl)aminomethane covalently grafted on kaolinite. Applied Clay Science 2010, 48:516-521.
18. de Mello Ferreira Guimarães A., Ciminelli V.S.T., Vasconcelos W.L. Smectite organofunctionalized with thiol groups for adsorption of heavy metal ions. Applied Clay Science 2009, 42:410-414.
19. Fujii K., Hayashi S., Kodama H. Synthesis of an alkylammonium/magnesium phyllosilicate hybrid nanocomposite consisting of a smectite-like layer and organosiloxane layers. Chemistry of Materials 2003, 15:1189-1197.
20. Gardolinski J.E.F.C., Lagaly G. Grafted organic derivatives of kaolinite: I. Synthesis, chemical and rheological characterization. Clay Minerals 2005, 40:537-546.
21. Gârea S.-A., Iovu H., Bulearca A. New organophilic agents of montmorillonite used as reinforcing agent in epoxy nanocomposites. Polymer Testing 2008, 27:100-113.
22. Giese R.F., Vanoss C.J. The surface thermodynamic properties of silicates and their interactions with biological materials. Reviews in Mineralogy 1993, 28:327-346.
23. Guerra D.L., Viana R., Airoldi C. Adsorption of mercury cation on chemically modified clay. Materials Research Bulletin 2009, 44:485-491.
24. Guerra D.L., Oliveira S.P., Silva R.A.S., Silva E.M., Batista A.C. Dielectric properties of organofunctionalized kaolinite clay and application in adsorption mercury cation. Ceramics International 2012, 38:1687-1696.
25. He H.P., Guo J.G., Xie X.D., Lin H.F., Li L.Y. A microstructural study of acid-activated montmorillonite from Choushan, China. Clay Minerals 2002, 37:337-344.
26. He H.P., Duchet J., Galy J., Gerard J. Grafting of swelling clay materials with 3-aminopropyltriethoxysilane. Journal of Colloid and Interface Science 2005, 288:171-176.
27. +-modified montmorillonite and its influence on sorption characteristics. Clays and Clay Minerals 2006, 54:691-698.
28. Hernando J., Pourrostami T., Garrido J.A., Williams O.A., Gruen D.M., Kromka A., Steinmüller D., Stutzmann M. Immobilization of horseradish peroxidase via an amino silane on oxidized ultrananocrystalline diamond. Diamond and Related Materials 2007, 16:138-143.
29. Herrera N.N., Letoffe J.-M., Putaux J.-L., David L., Bourgeat-Lami E. Aqueous dispersions of silane-functionalized laponite clay platelets. A first step toward the elaboration of water-based polymer/clay nanocomposites. Langmuir 2004, 20:1564-1571.
30. Herrera N.N., Letoffe J.-M., Reymond J.-P., Bourgeat-Lami E. Silylation of laponite clay particles with monofunctional and trifunctional vinyl alkoxysilanes. Journal of Materials Chemistry 2005, 15:863.
31. Itagaki T., Kuroda K. Organic modification of the interlayer surface of kaolinite with propanediols by transesterification. Journal of Materials Chemistry 2003, 13:1064-1068.
32. Jaber M., Miehe-Brendle J., Delmotte L., Le Dred R. New range of Al-Mg organoclays with tailored hydrophobicity: incorporation of fluoride as a local probe to study the octahedral character. Microporous and Mesoporous Materials 2003, 65:155-163.
33. Jaber M., Miehe-Brendle J., Delmotte L., Le Dred R. Formation of organoclays by a one step synthesis. Solid State Sciences 2005, 7:610-615.
34. Katsarava R.D., Yakov S.V. Silylation in polymer chemistry. Russian Chemical Reviews 1992, 61:629.
35. Kiliaris P., Papaspyrides C.D. Polymer/layered silicate (clay) nanocomposites: an overview of flame retardancy. Progress in Polymer Science 2010, 35:902-958.
36. Kim J., Grate J.W., Wang P. Nanostructures for enzyme stabilization. Chemical Engineering Science 2006, 61:1017-1026.
37. Kobayashi H., Matsunaga T. Amino-silane modified superparamagnetic particles with surface-immobilized enzyme. Journal of Colloid and Interface Science 1991, 141:505-511.
38. Lagaly G. Characterization of clays by organic-compounds. Clay Minerals 1981, 16:1-21.
39. LeBaron P.C., Wang Z., Pinnavaia T.J. Polymer-layered silicate nanocomposites: an overview. Applied Clay Science 1999, 15:11-29.
40. 29Si NMR. Journal of the American Chemical Society 1980, 102:4889-4893.
41. Michot L.J., Villieras F., Francois M., Yvon J., Ledred R., Cases J.M. The structural microscopic hydrophilicity of talc. Langmuir 1994, 10:3765-3773.
42. Miehe-Brendle J., Tuilier M.H., Marichal C., Gallego J.C., Reinholdt M. Mg environments in the octahedral sheet of 2:1 talc-like hybrid phyllosilicates: a comparative XAFS study. European Journal of Inorganic Chemistry 2010, 2010:5587-5591.
43. Murakami J., Itagaki T., Kuroda K. Synthesis of kaolinite-organic nanohybrids with butanediols. Solid State Ionics 2004, 172:279-282.
44. 2+ separation in the aqueous phase. Journal of Membrane Science 2007, 301:118-125.
45. Okada A., Usuki A. Twenty years of polymer-clay nanocomposites. Macromolecular Materials and Engineering 2006, 291:1449-1476.
46. Park M. Modification of external surface of laponite by silane grafting. Journal of Physics and Chemistry of Solids 2004, 65:499-501.
47. Piscitelli F., Posocco P., Toth R., Fermeglia M., Pricl S., Mensitieri G., Lavorgna M. Sodium montmorillonite silylation: unexpected effect of the aminosilane chain length. Journal of Colloid and Interface Science 2010, 351:108-115.
48. Ray S.S., Okamoto M. Polymer/layered silicate nanocomposites: a review from preparation to processing. Progress in Polymer Science 2003, 28:1539-1641.
49. Rong M.Z., Zhang M.Q., Ruan W.H. Surface modification of nanoscale fillers for improving properties of polymer nanocomposites: a review. Materials Science and Technology 2006, 22:787-796.
50. Sayi{dotless}lkan H., Erdemoǧlu S., Şener Ş., Sayi{dotless}lkan F., Akarsu M., Erdemoǧlu M. Surface modification of pyrophyllite with amino silane coupling agent for the removal of 4-nitrophenol from aqueous solutions. Journal of Colloid and Interface Science 2004, 275:530-538.
51. Shanmugharaj A., Rhee K., Ryu S. Influence of dispersing medium on grafting of aminopropyltriethoxysilane in swelling clay materials. Journal of Colloid and Interface Science 2006, 298:854-859.
52. Shen W., He H.P., Zhu J.X., Yuan P., Frost R.L. Grafting of montmorillonite with different functional silanes via two different reaction systems. Journal of Colloid and Interface Science 2007, 313:268-273.
53. Shen W., He H.P., Zhu J.X., Yuan P., Ma Y.H., Liang X.L. Preparation and characterization of 3-aminopropyltriethoxysilane grafted montmorillonite and acid-activated montmorillonite. Chinese Science Bulletin 2009, 54:265-271.
54. Silva C.R., Fonseca M.G., Barone J.S., Airoldi C. Layered inorganic-organic talc-like nanocomposites. Chemistry of Materials 2002, 14:175-179.
55. Takahashi N., Kuroda K. Materials design of layered silicates through covalent modification of interlayer surfaces. Journal of Materials Chemistry 2011, 21:14336-14353.
56. Tan G., Zhang L., Ning C., Liu X., Liao J. Preparation and characterization of APTES films on modification titanium by SAMs. Thin Solid Films 2011, 519:4997-5001.
57. Tonlé I.K., Diaco T., Ngameni E., Detellier C. Nanohybrid kaolinite-based materials obtained from the interlayer grafting of 3-aminopropyltriethoxysilane and their potential use as electrochemical sensors. Chemistry of Materials 2007, 19:6629-6636.
58. Tonlé I.K., Letaief S., Ngameni E., Walcarius A., Detellier C. Square wave voltammetric determination of lead(II) ions using a carbon paste electrode modified by a thiol-functionalized kaolinite. Electroanalysis 2011, 23:245-252.
59. Tunney J.J., Detellier C. Interlamellar covalent grafting of organic units on kaolinite. Chemistry of Materials 1993, 5:747-748.
60. Tunney J.J., Detellier C. Chemically modified kaolinite. Grafting of methoxy groups on the interlamellar aluminol surface of kaolinite. Journal of Materials Chemistry 1996, 6:1679-1685.
61. Xu S.H., Sheng G.Y., Boyd S.A. Use of organoclays in pollution abatement. Advances in Agronomy 1997, 59:25-62.
62. 2 groups substituting for bridging oxygen centers in the tetrahedral sheet. Applied Clay Science 2010, 48:60-66.
63. Yang S.Q., Yuan P., He H.P., Qin Z.H., Zhou Q., Zhu J.X., Liu D. The grafting of γ-aminopropyltriethoxysilane (APTES) onto the interlayer hydroxyl groups of kaolinite: effects of the reaction temperature. Applied Clay Science 2012, 62-63:8-14.
64. Yariv S. The effect of tetrahedral substitution of Si by Al on the surface acidity of the oxygen plane of clay minerals. International Reviews in Physical Chemistry 1992, 11:345-375.
65. Yariv S. The role of charcoal on DTA curves of organo-clay complexes: an overview. Applied Clay Science 2004, 24:225-236.
66. Zhou T.H., Ruan W.H., Wang Y.L., Mai Y.L., Rong M.Z., Zhang M.Q. Performance improvement of nano-silica/polypropylene composites through in-situ graft modification of nanoparticles during melt compounding. E-Polymers 2007, 2858-2863.
67. + pillared montmorillonites. Chinese Science Bulletin 2003, 48:368-372.