Organically modified clays for pollutant uptake and environmental protection

Soil Mineral Microbe-Organic Interactions: Theories and Applications

Volumn , Issue , 2008, Pages 145-174

  Theng, B K G ^a   Churchman, G J ^b   Gates, W P ^c   Yuan, G ^a  

^a LANDCARE RESEARCH   (New Zealand)

^b UNIVERSITY OF ADELAIDE   (Australia)

^c SmecTech Research Consulting   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 76849110245     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1007/978-3-540-77686-4_6     Document Type: Chapter

References (121)

1. Adams JM, McCabe RW (2006) Clay minerals as catalysts. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 541-582
2. Adebajo MO, Frost RL, Kloprogge JT, Carmody O, Kokot S (2003) Porous materials for oil spill cleanup: A review of synthesis and absorbing properties. J Porous Mat 10:159-170
3. Ahmadi SJ, Huang YD, Li W (2004) Synthetic routes, properties and future applications of polymer-layered silicate nanocomposites. J Mater Sci 39:1919-1925
4. Alther G (2002) Using organoclays to enhance carbon filtration. Waste Manage 22:507-513
5. Anderson A J C, Williams PN (1962) Refining of oils and fats for edible purposes, 2nd ed. Pergamon Press, New York
6. Barrer RM (1978) Zeolites and clay minerals as sorbents and molecular sieves. Academic Press, London
7. Beall GW (2003) The use of organoclays in water treatment. Appl Clay Sci 24:11-20
8. Bergaya F, Aouad A, Mandalia T (2006) Pillared clays and clay minerals. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 393-422
9. Bojemueller E, Nennemann A, Lagaly G (2001) Enhanced pesticide adsorption by thermally modified bentonites. Appl Clay Sci 18:277-284
10. Bors J (1990) Sorption of radioiodine in organo-clays and organo-soils. Radiochim Acta 51:39-143
11. Bors J, Gorny A (1992) Studies on the interactions of HDPY-vermiculite with radioiodine. Appl Clay Sci 7:245-250
12. Bors J, Dultz S, Riebe B (2000) Organophilic bentonites as adsorbents for radionuclides: I. Adsorption of ionic fission products. Appl Clay Sci 16:1-13
13. Boyd SA, Jaynes WF (1994) Role of layer charge in organic contaminant sorption by organo-clays. In: Mermut AR (ed) Layer charge characteristics of 2:1 silicate clay minerals. CMS Workshop Lecture Series, vol 6, The Clay Minerals Society, Boulder, CO, pp 48-77
14. Boyd SA, Mortland MM, Chiou CT (1988a) Sorption characteristics of organic compounds on hexadecyltrimethylammonium-smectite. Soil Sci Soc Am J 52:652-657
15. Boyd SA, Lee J-F, Mortland MM (1988) Attenuating organic contaminant mobility by soil modification. Nature 333:345-347
16. Boyd SA, Shaobai S, Lee JF, Mortland MM (1988b) Pentachlorophenol sorption by organo-clays. Clays Clay Miner 36:125-130
17. Boyd SA, Sheng G, Teppen BJ, Johnston CT (2001) Mechanisms for the adsorption of substituted nitrobenzenes by smectite clays. Environ Sci Technol 35:4227-4234
18. Breen C (1999) The characterisation and use of polycation-exchanged bentonites. Appl Clay Sci 15:187-219
19. Breen C, Zahoor FD, Madejová J, Komadel P (1997) Characterisation and catalytic activity of acid-treated, size-fractionated smectites. J Phys Chem B 101:5324-5331
20. Brixie JM, Boyd SA (1994) Treatment of contaminated soils with organoclays to reduce leachable pentachlorophenol. J Environ Qual 23:1283-1290
21. Brown MJ, Burris DR (1996) Enhanced organic contaminant sorption on soil treated with cationic surfactants. Ground Water 34:734-744
22. Burris DR, Antworth CP (1992) In situ modification of an aquifer material by a cationic surfactant to enhance retardation of organic contaminants. J Contam Hydrol 10:325-337
23. Carretero MI, Gomes C S F, Tateo F (2006) Clays and human health. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 717-742
24. Carrizosa MJ, Hermosin MC, Koskinen WC, Cornejo J (2004) Interactions of two sulfonylurea herbicides with organoclays. Clays Clay Miner 52:643-649
25. Celis R, Hermosin MC, Cornejo J (2000) Heavy metal adsorption by functionalized clays. Environ Sci Technol 34:4593-4599
26. Chappell MA, Laird DA, Thompson ML, Li H, Teppen BJ, Johnston CT, Boyd SA (2005) Influence of smectite hydration and swelling on atrazine sorption behavior. Environ. Sci Technol 39:3150-3156
27. Chiou CT (1989) Theoretical considerations of the partition uptake of nonionic organic compounds by soil organic matter. In: Sawhney BL, Brown K (eds) Reactions and movement of organic chemicals in soils. Soil Science Society of America, Madison, WI, pp 1-29
28. Chorom M, Rengasamy P (1996) Effect of heating on swelling and dispersion of different cationic forms of a smectite. Clays Clay Miner 44:783-790
29. Christidis GE, Kosiari S, Petavratzi E (2003) Acid activation and bleaching capacity of bentonites from the Troodos ophiolite, Cyprus. In: Domínguez EA, Mas GR, Cravero F (eds) 2001. A Clay Odyssey. Proc 12th Internat Clay Conf. Elsevier, Amsterdam, pp 579-586
30. Churchman GJ (2002) Formation of complexes between bentonite and different cationic polyelectrolytes and their use as sorbents for non-ionic and anionic pollutants. Appl Clay Sci 21:177-189
31. Churchman GJ, Volzone C (2003) Activation of clays for environmental uses - can we improve on nature, and can we pay? In: Domínguez EA, Mas GR, Cravero F (eds) 2001. A Clay Odyssey. Proc 12th Internat Clay Conf. Elsevier, Amsterdam, pp 31-38
32. Churchman GJ, Gates WP, Theng B K G, Yuan G (2006) Clays and clay minerals for pollution control. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 625-676
33. Čičel B, Kranz G (1981) Mechanism of monmorillonite structure degradation by percussive grinding. Clay Miner 16:151-162
34. Cioffi R, Costanzo S, Maffucci L, Santoro L (2001a) Adsorption of the organic fraction of a tannery sludge by means of organophilic bentonite. Environ Technol 22:83-89
35. Cioffi R, Maffucci L, Santoro L, Glasser FP (2001b). Stabilization of chloroorganics using organophilic bentonite an a cement-blast furnace slag matrix. Waste Manage 21:651-660
36. Cowan CT, White D (1962) Adsorption by organo-clay complexes. Clays Clay Miner 9:459-467
37. Cox L, Hermosin MC, Koskinen WC, Cornejo J (2001). Interactions of imidacloprid with organic-and inorganic-exchanged smectites. Clay Miner 36:267-274
38. Crocker FH, Guerin WF, Boyd SA (1995) Bioavailability of naphthalene sorbed to cationic surfactant-modified smectite clay. Environ Sci Technol 29:2953-2958
39. Droy-Lefaix M-T, Tateo F (2006) Clays as drugs. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 743-752
40. Gates WP, Slade PG (2001) Removal of toxins from water. Australian Patent No. PCT/AU01/00586
41. German Society for Fat Science (2001) Bleaching of edible fats and oils. European J Lipid Sci Technol 103:505-550
42. Grim RE (1968) Clay mineralogy, 2nd edn. McGraw-Hill, New York
43. Groisman L, Rav-Acha C, Gerstl Z, Mingelgrin U (2004) Sorption and detoxification of toxic compounds by a bifunctional organoclay. J Environ Qual 33:1930-1936
44. Haderlein SB, Weissmahr KW, Schwarzenbach RP (1996) Specific adsorption of nitroaromatic explosives and pesticides to clay minerals. Environ Sci Technol 30:612-622
45. Harvey CC, Lagaly G (2006) Conventional applications. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 501-540
46. Hassett JJ, Banwart WL (1989) The sorption of nonpolar organics by soils and sediments. In: Sawhney BL, Brown K (eds) Reactions and movement of organic chemicals in soils. Soil Science Society of America, Madison, WI, pp 31-44
47. Heller-Kallai L (2006) Thermally modified clay minerals. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 289-308
48. Hermosin MC, Calderón MJ, Aguer J-P, Cornejo J (2001) Organoclays for controlled release of the herbicide fenuron. Pest Manage Sci 57:803-809
49. Huang PM, Schnitzer M (eds) (1986) Interactions of soil minerals with natural organics and microbes. Soil Science Society of America, Madison, WI
50. Jaynes WF, Boyd SA (1991a) Clay mineral type and organic-compound sorption by hexadecyltrimethylammonium-exchanged clays. Soil Sci Soc Am J 55:43-48
51. Jaynes WF, Boyd SA (1991b). Hydrophobicity of siloxane surfaces in smectites as revealed by aromatic hydrocarbon adsorption from water. Clays Clay Miner 39:428-436
52. Jaynes WF, Vance GF (1996) BTEX sorption by organo-clays: cosorptive enhancement and equivalence of interlayer complexes. Soil Sci Soc Am J 60:1742-1749
53. Jaynes WF, Vance GF (1999) Sorption of benzene, toluene, ethylbenzene and xylene (BTEX) compounds by hectorite clays exchanged with aromatic organic cations. Clays Clay Miner 47:358-365
54. Johnston CT, De Oliveira MF, Teppen BJ, Sheng G, Boyd SA (2001) Spectroscopic study of nitroaromatic-smectite sorption mechanisms. Environ Sci Technol 35:4767-4772
55. Komadel P, Madejová J (2006) Acid activation of clay minerals. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 263-288
56. Konta J (1995) Clay and man: clay raw materials in the service of man. Appl Clay Sci 10:275-335
57. Kowalska M, Güler H, Cocke DL (1994) Interactions of clay minerals with organic pollutants. Sci Total Environ 141:223-240
58. Kukkadapu RK, Boyd SA (1995) Tetramethylphosphonium-smectite and tetramethylammonium-smectite as adsorbents of aromatic and chlorinated hydrocarbons - effect of water on adsorption efficiency. Clays Clay Miner 43:318-323
59. Lagaly G (1982) Layer charge heterogeneity in vermiculites. Clays Clay Miner 30:215-222
60. Lagaly G, Köster HM (1993) Tone und Tonminerale. In: Jasmund K, Lagaly G (eds) Tonminerale und tone. Steinkopff Verlag, Darmstadt, pp 1-32
61. Lagaly G, Ogawa M, Dékány I (2006) Clay mineral-organic interactions. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 309-379
62. Laird DA, Barriuso E, Dowdy RH, Koskinen WC (1992) Adsorption of atrazine on smectites. Soil Sci Soc Am J 56:62-67
63. Le Baron PC, Wang Z, Pinnavaia TJ (1999) Polymer-layered silicate nanocomposites: an overview. Appl Clay Sci 15:11-29
64. Lee J-F, Crum JR, Boyd SA (1989) Enhanced retention of organic contaminants by soil exchanged with organic cations. Environ Sci Technol 23:1365-1372
65. Lee J-F, Mortland MM, Boyd SA, Chiou CT (1989a) Shape-selective adsorption of aromatic molecules from water by tetramethylammonium-smectite. J Chem Soc Faraday Trans I 8:2953-2962
66. Lee J-F, Mortland MM, Chiou CT, Kile DE, Boyd SA (1990) Adsorption of benzene, toluene, and xylene by two tetramethylammonium-smectites having different charge densities. Clays Clay Miner 38:113-120
67. Lee SY, Kim SJ, Chung SY, Jeong CH (2004) Sorption of hydrophobic organic compounds onto organoclays. Chemosphere 55:781-785
68. Lo I M C (1996) Solidification/stabilization of phenolic waste using organo-clay complex. J Environ Eng 122:850-855
69. Lo I M C, Mak R K M (1998) Transport of phenolic compounds through a compacted organoclay liner. Water Sci Technol 38:143-150
70. Lo I M C, Yang X (2001) Use of organoclay as secondary containment for gasoline storgae tanks. J Environ Eng 127:154-161
71. Lo I M C, Lee S C H, Mak R K M (1998) Sorption of nonpolar and polar organics on dicetyldimethylammonium-bentonite. Waste Manage Res 16:129-138
72. Lo I M C, Mak R K M, Lee S C H (1997) Modified clays for waste containment and pollutant attenuation. J Environ Eng 123:25-32
73. Lund E, Nissen B (1986) Low-technology water purification by bentonite clay flocculation as performed in Sudanese villages: virological examinations. Water Res 20:37-43
74. Madsen M, Schlundt J (1989) Low-technology water purification by bentonite clay flocculation as performed in Sudanese villages: bacteriological examinations. Water Res 23:873-882
75. McBride MB, Pinnavaia TJ, Mortland MM (1997) Adsorption of aromatic molecules by clays in aqueous suspension. In: Suffet IH (ed) Fate of pollutants in the air and water environments. Wiley, New York, pp 145-154
76. Mitchell IV (1990) Pillared layered structures: current trends and applications. Elsevier Applied Science, London
77. Montgomery DM, Sollars CJ, Sheriff TS, Perry R (1988) Organophilic clays for the successful stabilisation/solidification of problematic organic wastes. Environ Technol Lett 9:1403
78. Moraru VN (2001) Structure formation of alkylammonium montmorillonites in organic media. Appl Clay Sci 19:11-26
79. Mortland MM (1970) Clay-organic complexes and interactions. Adv Agron 22:79-117
80. Mortland MM, Shaobai S, Boyd SA (1986) Clay-organic complexes as adsorbents for phenol and chlorophenols. Clays Clay Miner 34:581-595
81. Murray HH (2003) Clays in industry. In: Dominguez EA, Mas GR, Cravero F (eds) 2001. A clay odyssey. Proc 12th Int Clay Conf. Elsevier, Amsterdam, pp 3-14
82. Nir S, El-Nahhal Y, Undabeytia T, Rytwo G, Polubesova T, Mishael Y, Rabinovitz O, Rubin B (2006) Clays and pesticides. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 677-692
83. Nzengung VA, Voudrias EA, Nkedi-Kizza P, Wampler JM, Weaver CE (1996) Organic cosolvent effects on sorption equilibrium of hydrophobic chemicals by organoclays. Environ Sci Technol 30:89-96
84. Ogawa M, Shirai H, Kuroda K, Kato C (1992) Solid-state intercalation of naphthalene and anthracene into alkylammonium-montmorillonites. Clays Clay Miner 40:485-490
85. Prost R, Yaron B (2001) Use of modified clays for controlling soil environmental quality. Soil Sci 166:880-895
86. Redding AZ, Burns SE, Upson RT, Andersen EF (2002) Organoclay sorption of benzene as a function of total organic carbon content. J Colloid Interface Sci 250:261-264
87. Robertson R H S (1986) Fuller's Earth: A history of calcium montmorillonite. Volturna Press, Hythe, Kent
88. Rodríguez-Gonzalo E, Sánchez-Martin MJ, Sánchez-Camazano M (1993) Adsorption of parathion and paraoxon by modified montmorillonites. Toxicol Environ Chem 37:157-163
89. Ruiz-Hitzky E, Van Meerbeek A (2006) Clay mineral-and organoclay-polymer nanocomposites. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 583-622
90. Schoonheydt RA, Johnston CT (2006) Surface and interface chemistry of clay minerals. In: Bergaya F, Theng BKG, Lagaly G (eds) Handbook of clay science. Elsevier, Amsterdam, pp 87-113
91. Sharmasarkar S, Jaynes WF, Vance GF (2000) BTEX sorption by montmorillonite organo-clays: TMPA, ADAM, HDTMA. Water Air Soil Poll 119:257-273
92. Shen YH (2002) Sorption of benzene and naphthol to organobentonites intercalated with short-chain cationic surfactants. J Environ Sci Health, Part A: Toxic/Hazardous Subst Environ Eng 37:43-54
93. Sheng GY, Boyd SA (1998) Relation of water and neutral organic compounds in the interlayers of mixed Ca/trimethylphenylammonium-smectites. Clays Clay Miner 46:10-17
94. Sheng GY, Xu S, Boyd SA (1996a) Cosorption of organic contaminants from water by hexadecyltrimethylammonium-exchanged clays. Water Res 30:1483-1489
95. Sheng GY, Xu SH, Boyd SA (1996b). Mechanism (s) controlling sorption of neutral organic contaminants by surfactant-derived and natural organic matter. Environ Sci Technol 30:1553-1557
96. Sheng G, Xu S, Boyd SA (1999) A dual function organoclay sorbent for lead and chlorobenzene. Soil Sci Soc Am J 63:73-78
97. Siddiqui M K H (1968) Bleaching Earths. Pergamon Press, Oxford
98. Singh N, Megharaj M, Gates WP, Churchman GJ, Anderson J, Kookana RS, Naidu R, Chen Z, Slade PG, Sethunathan N (2003) Bioavailability of an organophosphorus pesticide, fenamiphos, sorbed on an organo-clay. J Agr Food Chem 51:2653-2658
99. Slade PG, Gates WP (2004a) The ordering of HDTMA in the interlayers of vermiculite and the influence of solvents. Clays Clay Miner 52:192-203
100. Slade PG, Gates WP (2004b) The swelling of HDTMA smectites as influenced by their preparation and layer charges. Appl Clay Sci 25:93-101
101. Smith JA, Jaffé PR (1994) Benzene transport through landfill liners containing organophilic bentonite. J Environ Eng 120:1559-1577
102. Smith JA, Jaffé PR, Chiou CT (1990) Effect of ten quaternary ammonium cations on tetrachloromethane sorption to clay from water. Environ Sci Technol 24:1167-1172
103. Street GB, White D (1963) Adsorption by organo-clay derivatives. J Appl Chem 13:288-291
104. Theng B K G (1972) Formation, properties, and pratical applications of clayorganic complexes. J Roy Soc New Zealand 2:437-457
105. Theng B K G (1974) The chemistry of clay-organic reactions. Adam Hilger, London
106. Theng B K G (1979) Formation and properties of clay-polymer complexes. Elsevier, Amsterdam
107. Theng B K G, Aislabie J, Fraser R (2001) Bioavailability of phenanthrene intercalated into an alkylammonium-montmorillonite clay. Soil Biol Biochem 33:845-848
108. Theng B K G, Greenland DJ, Quirk JP (1967) Adsorption of alkylammonium cations by montmorillonite. Clay Miner 7:1-17
109. Theng B K G, Kookana RS, Rahman A (2000) Environmental concerns of pesticides in soil and groundwater and management strategies in Oceania. In: Huang PM, Iskandar IK (eds) Soils and groundwater pollution and remediation-Asia, Africa, and Oceania. Lewis Publishers, Boca Raton, FL, pp 42-79
110. Theng B K G, Newman RH, Whitton JS (1998) Characterization of an alkylammonium-montmorillonite-phenanthrene intercalation complex by carbon-13 nuclear magnetic resonance spectroscopy. Clay Miner 33:221-229
111. Vansant EF, Uytterhoeven JB (1972) Thermodynamics of the exchange on nalkylammonium ions on Na-montmorillonite. Clays Clay Mineral 20:47-54
112. Weiss A (1963) Mica-type layer silicates with alkylammonium ions. Clays Clay Miner 10:191-224
113. Weissmahr, KW, Haderlein SB, Schwarzenbach RP, Hany R, Nuesch R (1997) In situ spectroscopic investigations of adsorption mechanisms of nitroaromatic compounds at clay minerals. Environ Sci Technol 31:240-247
114. Xu SH, Boyd SA (1995) Cationic surfactant adsorption by swelling and nonswelling layer silicates. Langmuir 1:2508-2514
115. Xu, S, Sheng G, Boyd SA (1997) Use of organoclays in pollution abatement. Adv Agron 59:25-62
116. Yang X, Lo I M C (2004) Flow of gasoline through composite liners. J Environ Eng 130:886-890
117. Yariv S, Cross H (eds) (2002) Clay-organic complexes and interactions. Marcel Dekker, New York
118. Yuan G (2004) Natural and modified nanomaterials as sorbents of environmental contaminants. J Environ Sci Health, Part A: Toxic/Hazardous Subst Environ Eng 39:2661-2670
119. Zhao H, Jaynes WF, Vance GF (1996) Sorption of the ionizable organic compound, dicamba (3, 6-dichloro-2-methoxy benzoic acid), by organoclays. Chemosphere 33:2089-2100
120. Zhu LZ, Su YH (2002) Benzene vapor sorption by organobentonites from ambient air. Clays Clay Miner 50:421-427
121. Zielke RC, Pinnavaia TJ, Mortland MM (1989) Adsorption and reactions of selected organic molecules on clay mineral surfaces. In: Sawhney BL, Brown K (eds) Reactions and movement of organic chemicals in soils. Soil Science Society of America, Madison, WI, pp 81-97