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For synthetic details, see Section 1 of the Supporting Information.
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From a synthetic perspective, we sought to develop a UPy unit that can be attached to a halogenated aromatic precursor via cross-coupling chemistry, instead of utilizing the common approach of coupling an activated UPy- to an amine-based aromatic precursor described in ref 13. This would allow our approach to be extended to other π-conjugated systems more easily, as halogenated aromatic precursors are more readily accessible than amine-based aromatic precursors.
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