Molecular salt effects in the gas phase: Tuning the kinetic basicity of [HCCLiCl]- and [HCCMgCl2]- by LiCl and MgCl2

Angewandte Chemie - International Edition

Volumn 53, Issue 41, 2014, Pages 10979-10983

  Khairallah, George N ^a   Da Silva, Gabriel ^c   O'Hair, Richard A J ^a,b  

^a UNIVERSITY OF MELBOURNE   (Australia)

^b Australian Government Australian Research Council   (Australia)

^c UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

ab initio calculations; gas phase reactions; mass spectrometry; organometallic compounds; salt effect

Indexed keywords

CALCULATIONS; CHEMICAL REACTIONS; CHEMICAL REACTIVITY; GASES; KINETIC THEORY; MASS SPECTROMETRY; ORGANOMETALLICS; PHASE INTERFACES;

AB INITIO CALCULATIONS; ENERGY AND ENTROPIES; GAS-PHASE REACTIONS; ION-MOLECULE REACTION; KINETIC MODELING; MASTER EQUATIONS; ORGANOMETALLIC COMPOUNDS; SALT EFFECT;

KINETICS;

ALKYNE; GAS; LITHIUM CHLORIDE; MAGNESIUM CHLORIDE; WATER;

CHEMISTRY; ELECTROSPRAY MASS SPECTROMETRY; GAS; KINETICS; THERMODYNAMICS;

ALKYNES; GASES; KINETICS; LITHIUM CHLORIDE; MAGNESIUM CHLORIDE; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; THERMODYNAMICS; WATER;

EID: 84925358914     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201404362     Document Type: Article

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