Structure-reactivity relationship of trifluoromethanesulfenates: Discovery of an electrophilic trifluoromethylthiolating reagent

Journal of Organic Chemistry

Volumn 80, Issue 6, 2015, Pages 3012-3021

  Shao, Xinxin ^a   Xu, Chunfa ^a   Lu, Long ^a   Shen, Qilong ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL COMPOUNDS; CHEMICAL REACTIVITY; FUNCTIONAL GROUPS;

ARYL RINGS; ARYLBORONIC ACIDS; GRIGNARD REAGENT; KETO ESTER; MILD REACTION CONDITIONS; STRUCTURE-REACTIVITY RELATIONSHIPS; SUBSTITUTED GROUPS; SULFINATES;

CHEMICAL REACTIONS;

1,2 DICHLOROETHANE; ALKYNE DERIVATIVE; BORONIC ACID DERIVATIVE; ELECTROPHILE; ESTER DERIVATIVE; GRIGNARD REAGENT; INDOLE DERIVATIVE; INSECTICIDE; METHYL GROUP; NUCLEOPHILE; OXINDOLE; SULFINIC ACID DERIVATIVE; THIOL REAGENT; TRIFLUOROMETHANESULFONIC ACID;

ARTICLE; AZUKI BEAN WEEVIL; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYST; COLUMN CHROMATOGRAPHY; CONTROLLED STUDY; ELECTROPHILICITY; FLUORINE NUCLEAR MAGNETIC RESONANCE; INSECTICIDAL ACTIVITY; LARVA; NONHUMAN; NUCLEOPHILICITY; PROTON NUCLEAR MAGNETIC RESONANCE; RICE STEM BORER; ROOM TEMPERATURE; SHIFT TO THE RIGHT; STEM BORER; STRUCTURE ACTIVITY RELATION; SUBSTITUTION REACTION; WEEVIL; X RAY DIFFRACTION;

EID: 84925352873     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo502645m     Document Type: Article

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