Electrochemically induced free solvent transfer in thin poly(3,4-ethylenedioxythiophene) films

Electrochimica Acta

Volumn 164, Issue , 2015, Pages 21-30

  Agrisuelas, J ^a   Gabrielli, C ^b,c   Garcia Jareno J J ^a   Perrot, H ^b,c   Sel, O ^b,c   Vicente, F ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

^b SORBONNE UNIVERSITÉ   (France)

^c CNRS   (France)

Author keywords

ac Electrogravimetry; changes; Electrochemical impedance spectroscopy; Electrochemical quartz crystal; Electrochemically induced conformational; microbalance; Poly(3,4 ethylenedioxythiophene)

Indexed keywords

CONDUCTIVE FILMS; CONFORMATIONS; MOLECULES; QUARTZ; SEMICONDUCTOR DOPING; SPECTROSCOPY;

CHANGES; ELECTROCHEMICALLY INDUCED CONFORMATIONAL; MICROBALANCES; POLY-3 ,4-ETHYLENEDIOXYTHIOPHENE; QUARTZ CRYSTAL;

ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY;

EID: 84923677470     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2015.02.133     Document Type: Article

References (69)

1. B.L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, and J.R. Reynolds Poly(3,4-ethylenedioxythiophene) and its derivatives: Past, present, and future Adv. Mater. 12 2000 481 494
2. S. Kirchmeyer, and K. Reuter Scientific importance properties and growing applications of poly(3,4-ethylenedioxythiophene) J. Mater. Chem. 15 2005 2077 2088
3. Y. Wang Research progress on a novel conductive polymer-poly(3,4-ethylenedioxythiophene) (PEDOT) J. Phys. Conf. Ser. 152 2009 012023
4. M. Vazquez, J. Bobacka, M. Luostarinen, K. Rissanen, A. Lewenstam, and A. Ivaska Potentiometric sensors based on poly(3,4-ethylenedioxythiophene) (PEDOT) doped with sulfonated calix[4] arene and calix[4] resorcarenes J. Solid State Electrochem. 9 2005 312 319
5. F. Jonas, and J.T. Morrison 3,4-polyethylenedioxythiophene (PEDT): Conductive coatings technical applications and properties Synth. Met. 85 1997 1397 1398
6. T.M. Brown, J.S. Kim, R.H. Friend, F. Cacialli, R. Daik, and W.J. Feast Built-in field electroabsorption spectroscopy of polymer light-emitting diodes incorporating a doped poly(3,4-ethylene dioxythiophene) hole injection layer Appl. Phys. Lett. 75 1999 1679 1681
7. J.-H. Huang, D. Kekuda, C.-W. Chu, and K.-C. Ho Electrochemical characterization of the solvent-enhanced conductivity of poly(3,4-ethylenedioxythiophene) and its application in polymer solar cells J. Mater. Chem. 19 2009 3704 3712
8. G.A. Snook, P. Kao, and A.S. Best Conducting-polymer-based supercapacitor devices and electrodes J. Power Sources. 196 2011 1 12
9. M.S. Cho, H.J. Seo, J.D. Nam, H.R. Choi, J.C. Koo, K.G. Song, and Y. Lee A solid state actuator based on the PEDOT/NBR system Sens. Actuators B-Chem. 119 2006 621 624
10. D.-H. Kim, S.M. Richardson-Burns, J.L. Hendricks, C. Sequera, and D.C. Martin Effect of immobilized nerve growth factor on conductive polymers: Electrical properties and cellular response Adv. Funct. Mater. 17 2007 79 86
11. L. Niu, C. Kvarnström, K. Fröberg, and A. Ivaska Electrochemically controlled surface morphology and crystallinity in poly(3,4-ethylenedioxythiophene) films Synth. Met. 122 2001 425 429
12. E. Poverenov, M. Li, A. Bitler, and M. Bendikov Major Effect of Electropolymerization Solvent on Morphology and Electrochromic Properties of PEDOT Films Chem. Mater. 22 2010 4019 4025
13. T.F. Otero, and J.G. Martinez Artificial Muscles: A Tool To Quantify Exchanged Solvent during Biomimetic Reactions Chem. Mater. 24 2012 4093 4099
14. A. Bund, and R. Peipmann Application of PEDOT layers for the electrogravimetric detection of sulphate and phosphate in aqueous media Electrochimica Acta. 53 2008 3772 3778
15. M.J. Brown, A.R. Hillman, S.J. Martin, R.W. Cernosek, and H.L. Bandey Manipulation of electroactive polymer film viscoelasticity: the roles of applied potential and frequency J. Mater. Chem. 10 2000 115 126
16. E. Kriván, C. Visy, and J. Kankare Deprotonation and Dehydration of Pristine PPy/DS Films during Open-Circuit Relaxation: an Ignored Factor in Determining the Properties of Conducting Polymers J. Phys. Chem. B 107 2003 1302 1308
17. A. Bund, and S. Neudeck Effect of the solvent and the anion on the doping/dedoping behavior of poly(3,4-ethylenedioxythiophene) films studied with the electrochemical quartz microbalance J. Phys. Chem. B 108 2004 17845 17850
18. W. Plieth, A. Bund, U. Rammelt, S. Neudeck, and L.M. Duc The role of ion and solvent transport during the redox process of conducting polymers Electrochimica Acta 51 2006 2366 2372
19. A.R. Hillman, I. Efimov, and K.S. Ryder Time-Scale- and Temperature-Dependent Mechanical Properties of Viscoelastic Poly(3,4-ethylenedioxythiophene) Films J. Am. Chem. Soc. 127 2005 16611 16620
20. S. Bruckenstein, and A. Hillman Consequences of Thermodynamic Restraints on Solvent and Ion Transfer During Redox Switching of Electroactive Polymers J. Phys. Chem. 92 1988 4837 4839
21. S. Bruckenstein, and A. Hillman Solvent and Salt Transfer Upon Redox Switching of Electroactive Polymers J. Phys. Chem. 95 1991 10748 10752
22. A.R. Hillman, S.J. Daisley, and S. Bruckenstein Solvent effects on the electrochemical p-doping of PEDOT Phys. Chem. Chem. Phys. 9 2007 2379 2388
23. A.R. Hillman, S.J. Daisley, and S. Bruckenstein Kinetics and mechanism of the electrochemical p-doping of PEDOT Electrochem. Commun. 9 2007 1316 1322
24. A. Hillman, and S. Bruckenstein Role of Film History and Observational Timescale on Redox Switching Kinetics of Electroactive Films.1. a New Model for Permselective Films with Polymer Relaxation Processes J. Chem. Soc. -Faraday Trans. 89 1993 339 348
25. A.R. Hillman, and S. Bruckenstein Role of film history and observational timescale in redox switching kinetics of electroactive films. Part 2. - Visualizing electrochemical redox switching pathways involving four or more distinct relaxation times J. Chem. Soc. Faraday Trans. 89 1993 3779 3782
26. R. Hass, J. García-Cañadas, and G. García-Belmonte Electrochemical impedance analysis of the redox switching hysteresis of poly(3,4-ethylenedioxythiophene) films J. Electroanal. Chem. 577 2005 99 105
27. J. Agrisuelas, C. Gabrielli, J.J. Garcia-Jareño, H. Perrot, and F. Vicente Ionic and Free Solvent Motion in Poly(azure A) Studied by ac-Electrogravimetry J. Phys. Chem. C 115 2011 11132 11139
28. J. Agrisuelas, C. Gabrielli, J.J. García-Jareño, H. Perrot, and F. Vicente Kinetic and Mechanistic Aspects of a Poly(o-Toluidine)-Modified Gold Electrode. 2. Alternating Current Electrogravimetry Study in H2SO4 Solutions J. Phys. Chem. C 116 2012 15630 15640
29. J. Agrisuelas, C. Gabrielli, J.J. García-Jareño, H. Perrot, and F. Vicente Effects of anion size on the electrochemical behavior of H2SO4-structured poly(o-toluidine) films. An ac-electrogravimetry study in acid solutions Electrochimica Acta 132 2014 561 573
30. J. Agrisuelas, C. Gabrielli, J.J. Garcia-Jareño, H. Perrot, O. Sel, and F. Vicente Polymer dynamics in thin p-type conducting films investigated by ac-electrogravimetry. Kinetics aspects on anion exclusion, free solvent transfer, and conformational changes in poly(o-toluidine) Electrochimica Acta 153 2015 33 43
31. T.F. Otero, and J.G. Martinez Biomimetic intracellular matrix (ICM) materials, properties and functions. Full integration of actuators and sensors J. Mater. Chem. B 1 2013 26 38
32. T.F. Otero, and J.G. Martinez Structural and Biomimetic Chemical Kinetics: Kinetic Magnitudes Include Structural Information Adv. Funct. Mater. 23 2013 404 416
33. C. Gabrielli, J.J. García-Jareño, M. Keddam, H. Perrot, and F. Vicente Ac-Electrogravimetry Study of Electroactive Thin Films. I. Application to Prussian Blue J. Phys. Chem. B 106 2002 3182 3191
34. C. Gabrielli, J.J. Garcia-Jareño, M. Keddam, H. Perrot, and F. Vicente Ac-Electrogravimetry Study of Electroactive Thin Films. II. Application to Polypyrrole J. Phys. Chem. B 106 2002 3192 3201
35. C. Gabrielli, J. Garcia-Jareño, and H. Perrot Charge transport in electroactive thin films investigated by ac electrogravimetry ACH-Models Chem. 137 2000 269 297
36. J. Agrisuelas, J.J. Garcia-Jareño, D. Gimenez-Romero, and F. Vicente Innovative Combination of Three Alternating Current Relaxation Techniques: Electrical Charge, Mass, and Color Impedance Spectroscopy. Part I: The Tool J. Phys. Chem. C 113 2009 8430 8437
37. J. Agrisuelas, J. Juan Garcia-Jareño, D. Gimenez-Romero, and F. Vicente Innovative Combination of Three Alternating Current Relaxation Techniques: Electrical Charge, Mass, and Color Impedance Spectroscopy. Part II: Prussian Blue reversible arrow Everitt's Salt Process J. Phys. Chem. C 113 2009 8438 8446
38. L.T.T. Kim, C. Gabrielli, A. Pailleret, and H. Perrot Correlation between ion-exchange properties and swelling/shrinking processes in hexasulfonated calix[6] arene doped polypyrrole films: ac-electrogravimetry and electrochemical atomic force microscopy investigations Electrochimica Acta 56 2011 3516 3525
39. L.T.T. Kim, C. Gabrielli, A. Pailleret, and H. Perrot Ions/Solvent Exchanges and Electromechanical Processes in Hexasulfonated Calix[6] Arene Doped Polypyrrole Films: Towards a Relaxation Mechanism Electrochem. Solid State Lett. 14 2011 F9 F11
40. L. Lizarraga, E.M. Andrade, M.I. Florit, and F.V. Molina Quasi-Equilibrium Volume Changes of Polyaniline Films upon Redox Switching. Formal Potential Distribution and Configurational Modeling J. Phys. Chem. B 109 2005 18815 18821
41. K. Kaneto, and M. Kaneko Contribution of conformational change of polymer structure to electrochemomechanical deformation based on polyaniline Appl. Biochem. Biotechnol. 96 2001 13 23
42. B. Zanfrognini, A. Colina, A. Heras, C. Zanardi, R. Seeber, and J. López-Palacios A UV-Visible/Raman spectroelectrochemical study of the stability of poly(3,4-ethylendioxythiophene) films Polym. Degrad. Stab. 96 2011 2112 2119
43. J.R. Macdonald Comparison and application of two methods for the least squares analysis of immittance data Solid State Ion 58 1992 97 107
44. D. Benito, C. Gabrielli, J.J. GarcIÍa-Jareño, M. Keddam, H. Perrot, and F. Vicente Study by EQCM on the voltammetric electrogeneration of poly(neutral red). The effect of the pH and the nature of cations and anions on the electrochemistry of the films Electrochimica Acta 48 2003 4039 4048
45. T.-Y. Chiang, M.-C. Huang, and C.-H. Tsai The effects of solvent on the electrochromic properties of poly(3,4-ethylenedioxythiophene) Rsc Adv. 4 2014 21201 21207
46. H. Grande, and T.F. Otero Conformational movements explain logarithmic relaxation in conducting polymers Electrochimica Acta 44 1999 1893 1900
47. I. Efimov, S. Winkels, and J.W. Schultze EQCM study of electropolymerization and redox cycling of 3,4-polyethylenedioxythiophene J. Electroanal. Chem. 499 2001 169 175
48. X. Chen, K.-Z. Xing, and O. Inganäs Electrochemically Induced Volume Changes in Poly(3,4-ethylenedioxythiophene) Chem. Mater. 8 1996 2439 2443
49. S.N. Eliseeva, T.A. Babkova, and V.V. Kondratiev Mass transfer of ions and solvent at redox processes in poly-3,4-ethylenedioxythiophene films Russ. J. Electrochem. 45 2009 152 159
50. C. Lei, P. Wilson, and C. Lekakou Effect of poly(3,4-ethylenedioxythiophene) (PEDOT) in carbon-based composite electrodes for electrochemical supercapacitors J. Power Sources 196 2011 7823 7827
51. J. Agrisuelas, D. Giménez-Romero, J.J. García-Jareño, and F. Vicente Vis/NIR spectroelectrochemical analysis of poly-(Azure A) on ITO electrode Electrochem. Commun. 8 2006 549 553
52. J.G. Martinez, T.F. Otero, and E.W.H. Jager Effect of the Electrolyte Concentration and Substrate on Conducting Polymer Actuators Langmuir 30 2014 3894 3904
53. C. Gabrielli, H. Takenouti, O. Haas, and A. Tsukada Impedance Investigation of the Charge Transport in Film-Modified Electrodes J. Electroanal. Chem. 302 1991 59 89
54. M. Mathias, and O. Haas An Alternating-Current Impedance Model Including Migration and Redox-Site Interactions at Polymer-Modified Electrodes J. Phys. Chem. 96 1992 3174 3182
55. W.J. Doherty, R.J. Wysocki, N.R. Armstrong, and S.S. Saavedra Potential-modulated attenuated total reflectance spectroscopy of poly(3,4-ethylenedioxythiophene) and poly(3,4-ethylenedioxythiophene methanol) copolymer films on indium-tin oxide J. Phys. Chem. B 110 2006 4900 4907
56. C. Gabrielli, M. Keddam, N. Nadi, and H. Perrot Ions and solvent transport across conducting polymers investigated by ac electrogravimetry. Application to polyaniline J. Electroanal. Chem. 485 2000 101 113
57. J. Agrisuelas, J.J. García-Jareño, D. Gimenez-Romero, and F. Vicente An approach to the electrochemical activity of poly-(phenothiazines) by complementary electrochemical impedance spectroscopy and Vis-NIR spectroscopy Electrochimica Acta 55 2010 6128 6135
58. A. Zykwinska, W. Domagala, and M. Lapkowski ESR spectroelectrochemistry of poly(3,4-ethylenedioxythiophene) (PEDOT) Electrochem. Commun. 5 2003 603 608
59. D. Benito, C. Gabrielli, J.J. GarcIÍa-Jareño, M. Keddam, H. Perrot, and F. Vicente An electrochemical impedance and ac-electrogravimetry study of PNR films in aqueous salt media Electrochem. Commun. 4 2002 613 619
60. J. Agrisuelas, C. Gabrielli, J.J. Garcia-Jareño, D. Gimenez-Romero, J. Gregori, H. Perrot, and F. Vicente Usefulness of F(dm/dQ) function for elucidating the ions role in PB films J. Electrochem. Soc. 154 2007 F134 F140
61. A. Zykwinska, W. Domagala, A. Czardybon, B. Pilawa, and M. Lapkowski In situ EPR spectroelectrochemical studies of paramagnetic centres in poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(3,4-butylenedioxythiophene) (PBuDOT) films Chem. Phys. 292 2003 31 45
62. C. Visy, and J. Kankare Polythiophene puzzle - a plausible solution J. Electroanal. Chem. 442 1998 175 188
63. C. Visy, and J. Kankare Direct in situ conductance evidence for non-faradaic electrical processes in poly(3-methylthiophene) Electrochimica Acta 45 2000 1811 1820
64. E.-G. Kim, and J.-L. Bredas Electronic Evolution of Poly(3,4-ethylenedioxythiophene) (PEDOT): From the Isolated Chain to the Pristine and Heavily Doped Crystals J. Am. Chem. Soc. 130 2008 16880 16889
65. J. Roncali Conjugated Poly(thiophenes) - Synthesis, Functionalization, and Applications Chem. Rev. 92 1992 711 738
66. E. Kriván, C. Visy, and J. Kankare Key role of the desolvation in the achievement of the quasi-metallic state of electronically conducting polymers Electrochimica Acta 50 2005 1247 1254
67. W. Hong, Y. Xu, G. Lu, C. Li, and G. Shi Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells Electrochem. Commun. 10 2008 1555 1558
68. S.K.M. Jonsson, J. Birgerson, X. Crispin, G. Greczynski, W. Osikowicz, A.W.D. van der Gon, W.R. Salaneck, and M. Fahlman The effects of solvents on the morphology and sheet resistance in poly (3,4-ethylenedioxythiophene)-polystyrenesulfonic acid (PEDOT-PSS) films Synth. Met. 139 2003 1 10
69. G. Greczynski, T. Kugler, M. Keil, W. Osikowicz, M. Fahlman, and W.R. Salaneck Photoelectron spectroscopy of thin films of PEDOT-PSS conjugated polymer blend: a mini-review and some new results J. Electron Spectrosc. Relat. Phenom. 121 2001 1 17