Quasi-equilibrium volume changes of polyaniline films upon redox switching. formal potential distribution and configurational modeling

Journal of Physical Chemistry B

Volumn 109, Issue 40, 2005, Pages 18815-18821

  Lizarraga, Leonardo ^a   Andrade, Estela M ^a   Florit, María I ^b   Molina, Fernando V ^a  

^a UNIVERSIDAD DE BUENOS AIRES   (Argentina)

^b INSTITUTO DE INVESTIGACIONES FISICOQUÍMICAS TEÓRICAS Y APLICADAS INIFTA   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC POLYMERS; ELECTROSTATICS; NITROGEN COMPOUNDS; POLYMERS; REDOX REACTIONS; STATISTICAL METHODS; SULFURIC ACID;

ELECTROMECHANICAL BEHAVIOR; POLYANILINES; POLYMER DEFORMATION; REDOX SWITCHING;

PLASTIC FILMS;

ANILINE DERIVATIVE; POLYANILINE; POLYMER; SULFURIC ACID;

ARTICLE; ARTIFICIAL MEMBRANE; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; OXIDATION REDUCTION REACTION;

ANILINE COMPOUNDS; ELECTROCHEMISTRY; MEMBRANES, ARTIFICIAL; MODELS, CHEMICAL; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; POLYMERS; SULFURIC ACIDS;

EID: 27144451250     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp054052s     Document Type: Article

References (61)

1. (a) Evans, G. P. In Advances in Electrochemical Science and Engineering; Gerischer, H., Tobías, C. H., Eds.; VCH: New York, 1990; Vol. 1.
2. (b) Samuelsen, E., Ed. Science and Applications of Conducting Polymers; Hilger: Bristol, U.K., 1991.
3. (c) Inzelt, G. In Electroanalytical Chemistry; Bard, A. J., Ed.; M. Dekker: New York, 1994; Vol. 18, p 89.
4. (a) Kaneto, K.; Kaneko, M.; Min, Y.; MacDiarmid, A. Synth. Met. 1995, 71, 2211-2212.
5. (b) Qi, B.; Lu, W.; Mattes, B. R. J. Phys. Chem. B 2004, 108, 6222-6227.
6. (a) Nicolas-Debarnot, D.; Poncin-Epaillard, F. Anal. Chim. Acta 2003, 475, 1-15.
7. (b) Malinauskas, A.; Garjonytè, R.; Mažeikienè, R.; Jureviciutè, I. Talanta 2004, 64, 121-129.
8. (c) Morrin, A.; Wilbeer, F.; Ngamna, O.; Moulton, S. E.; Killard, A. J.; Wallace, G. G.; Smyth, M. R. Electrochem. Commun. 2005, 7, 317-322.
9. (d) Lee, Y. S.; Song, K. D.; Huh, J. S.; Chung, W. Y.; Lee, D. D. Sens. Actuators, B 2005, 108, 292-297.
10. (a) Hermas, A. A.; Nakayama, M.; Ogura, K. Electrochim. Acta 2005, 50, 2001-2007.
11. (b) Torresi, R. M.; de Souza, S.; Pereira da Silva, J. E.; Cordoba de Torresi, S. I. Electrochim. Acta 2005, 50, 2213-2218.
12. Minjia, H.; Chao, T.; Qunfang, Z.; Guibin, J. J. Chromatogr., A 2004, 1048, 257-262.
13. Ryu, K. S.; Lee, Y.; Han, K. S.; Park, Y. J.; Kang, M. G.; Park, N. G.; Chang, S. H. Solid State Ionics 2004, 175, 765-768.
14. Ryu, K. S.; Hong, Y. S.; Park, Y. J.; Wu, X.; Kim, K. M.; Lee, Y. G.; Chang, S. H.; Lee, S. J. Solid State Ionics 2004, 175, 759-763.
15. (a) Genies, E. M.; Tsintavis, C. T. J. Electroanal Chem. 1985, 195, 109-128.
16. (b) Huang, W.; Humphrey, B.; MacDiarmid, A. J. Chem. Soc., Faraday Trans. 1 1986, 82, 2385-2400.
17. (c) Orata, D.; Buttry, D. A. J. Am. Chem. Soc. 1987, 109, 3574-3581.
18. (d) Horanyi, G.; Inzelt, G. Electrochim. Acta 1988, 33, 947-952.
19. (e) Odin, C.; Nechtschein, M.; Hapiot, P.; Synth. Met. 1992, 47, 329-350.
20. (f) Miras, M. C.; Barbero, C.; Kötz, R.; Hass, O. J. Electroanal. Chem. 1994, 369, 193-197.
21. (g) Andrade, E. M.; Molina, F. V.; Florit, M. I.; Posadas, D. J. Electroanal. Chem. 1996, 419, 15-21.
22. (h) Neudeck, A.; Petr, A.; Dunsch, L. Synth. Met. 1999, 107, 143-158.
23. (i) Inzelt, G. Electrochim. Acta 2000, 45, 3865-3876.
24. (a) Glarum, S. H.; Marshall, J. H. J. Electrochem. Soc. 1987, 134, 2160-2165.
25. (b) Patil, R.; Harima, Y.; Yamashita, K.; Komaguchi, K.; Itagaki, Y.; Shiotani, M. J. Electroanal. Chem. 2002, 518, 13-19.
26. (c) Petr, A.; Neudeck, A.; Dunsch, L. Chem. Phys. Lett. 2005, 401, 130-134.
27. Green, A. G.; Woodhead, A. E. J. Chem. Soc. 1912, 101, 1117-1123.
28. Albery, W. J.; Boutelle, M. G.; Colby, P. J.; Hillman, A. R. J. Electroanal. Chem. 1982, 133, 135-145.
29. (a) Sabatani, E.; Anson, F. C. J. Electroanal. Chem. 1995, 386, 111 -119.
30. (b) Bowden, E. F.; Dautartas, M. F.; Evans, J. F. J. Electroanal. Chem. 1987, 279, 49-69.
31. (c) Dautartas, M. F.; Bowden, E. F.; Evans, J. F. J. Electroanal. Chem. 1987, 219, 71-89.
32. (d) Bowden, E. F.; Dautartas, M. F.; Evans, J. F. J. Electroanal. Chem. 1987, 219, 91-115.
33. (a) Heinze, J.; Störzbach, M.; Mortensen, J. Ber. Bunsen-Ges. Phys. Chem. 1987, 91, 960-967.
34. (b) Heinze, J.; Bilger, R.; Meerholz, K. Ber. Bunsen-Ges. Phys. Chem. 1988, 92, 1266-1271.
35. Vorotyntsev, M. A.; Daikhin, L. I.; Levi, M. D. J. Electroanal. Chem. 1992, 332, 213-235.
36. Vorotyntsev, M. A.; Badiali, J. P. Electrochim. Acta 1994, 39, 289-306.
37. (a) Otero, T. F.; Angulo, E.; Rodríguez, J.; Santamaría, C. J. Electroanal. Chem. 1992, 341, 369-375.
38. (b) Otero, T. F.; Grande, H. J. In Handbook of Conducting Polymers; Stoktheim, T. A., Elsenbaumer, R. L., Reynolds, J. R., Eds.; Marcel Dekker: New York, 1998; Chapter 36.
39. (a) Andrade, E. M.; Molina, F. V.; Florit, M. I.; Posadas, D. Electrochem. Solid-State Lett. 2000, 3, 504-507.
40. (b) Lizarraga, L.; Andrade, E. M.; Molina, F. V. J. Electroanal. Chem. 2004, 561, 127-135.
41. (a) Posadas, D.; Fonticelli, M.; Rodriguez Presa, M. J.; Florit, M. I. J. Phys. Chem. B 2001, 105, 2291-2296.
42. (b) Posadas, D.; Rodriguez Presa, M. J.; Florit, M. I. Electrochim. Acta 2001, 46, 4075-4081.
43. (c) Posadas, D.; Florit, M. I.; J. Phys. Chem. B 2004, 108, 15470-15476.
44. (a) Herod, T. E.; Schenloff, J. B. Chem. Mater. 1993, 5, 951-955.
45. (b) Kaneko, M.; Kaneto, K.; Takashima, W. Jpn. J. Appl. Phys., Part 2 1995, 34, L8374.
46. (c) Kaneko, M.; Kaneto, K. React. Funct. Polym. 1998, 37, 155-161.
47. (d) Kaneko, M.; Kaneto, K. Synth. Met. 1999, 1350-1353.
48. (e) Avlyanov, J. K.; Min, Y.; MacDiarmid, A. G.; Epstein, A. K. Synth. Met. 1995, 72, 65-71.
49. (f) Pereira da Silva, J. E.; Temperini, M. L. A.; Cordoba de Torresi, S. I. K. Electrochim. Acta 1999, 44, 1887-1891.
50. (a) Hill, T. L. J. Chem. Phys. 1952, 20, 1259-1273.
51. (b) Flory, P. J. J. Chem. Phys. 1950, 18, 108-111.
52. (c) Hill, T. L. An Introduction to Statistical Thermodynamics; Addison-Wesley: Reading, MA, 1960; Chapter 21.
53. Flory, P. J. Statistical Mechanics of Chain Molecules; Interscience: New York, 1969.
54. Sips, R. J. Chem. Phys. 1948, 16, 490-495.
55. (a) Koopal, L. K.; van Riemsdijk, W. H.; de Wit, J. C. M.; Benedetti, M. F. J. Colloid Interface Sei. 1994, 166, 51-60.
56. (b) Benedetti, M. F.; Milne, C. J.; Kinniburgh, D. G.; van Riemsdijk, W. H.; Koopal, L. K. Environ. Sci. Technol. 1995, 29, 446-457.
57. Menardo, C.; Genoud, F.; Nechtschein, M.; Travers, J. P.; Hani, P. In Electronic Properties of Conjugated Polymers; Kuzmany, H., Mehring, M., Roth, S., Eds.; Springer-Verlag: Berlin, 1987; pp 244-248.
58. Rodriguez Presa, M. J.; Posadas, D.; Florit, M. I. J. Electroanal. Chem. 2000, 482, 117-124.
59. zc), but these measurements are very difficult in these systems. Thus, no attempt has been made to separate both contributions. Because of the above-mentioned proportionality, this is unlikely to affect the resulting parameters, other than the Qm value.
60. Andrade, E. M.; Molina, F. V.; Posadas, D.; Florit, M. I. J. Electrochem. Soc. 2005, 152, E75-E83.
61. Grossmann, B.; Heinze, J.; Moll, T.; Palivan, C.; Ivan, S.; Gescheidt, G. J. Phys. Chem. B 2004, 108, 4669-4672.