A UV-Visible/Raman spectroelectrochemical study of the stability of poly(3,4-ethylendioxythiophene) films

Polymer Degradation and Stability

Volumn 96, Issue 12, 2011, Pages 2112-2119

  Zanfrognini, B ^a   Colina, A ^b   Heras, A ^b   Zanardi, C ^a   Seeber, R ^a   Lopez Palacios J ^b  

^a UNIVERSITY OF MODENA AND REGGIO EMILIA   (Italy)

^b UNIVERSITY OF BURGOS   (Spain)

Author keywords

Conducting polymers; Electrochemistry; PEDOT; Raman spectroscopy; Spectroelectrochemistry

Indexed keywords

ANALYTICAL TOOL; AQUEOUS MEDIUM; DOPING AND DE-DOPING; GLASSY CARBON ELECTRODES; MECHANISTIC ASPECTS; PEDOT; PH VALUE; PHOTOINDUCED PROCESS; SPECTROELECTROCHEMICAL STUDY; SPECTROELECTROCHEMICAL TECHNIQUE; UV-VISIBLE;

CARBON FILMS; CONDUCTING POLYMERS; CONDUCTIVE FILMS; DEGRADATION; ELECTRODES; GLASS MEMBRANE ELECTRODES; GLASSY CARBON; ORGANIC CONDUCTORS; POLYMER FILMS; RAMAN SPECTROSCOPY; SPECTROELECTROCHEMISTRY; SURFACE ACTIVE AGENTS;

SEMICONDUCTOR DOPING;

EID: 80655148894     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2011.09.017     Document Type: Article

References (25)

1. N. Rozlosnik New directions in medical biosensors employing poly(3,4-ethylenedioxy thiophene) derivative-based electrodes Analytical and Bioanalytical Chemistry 395 3 2009 637 645
2. J. Jang, M. Chang, and H. Yoon Chemical sensors based on highly conductive poly(3,4-ethylene- dioxythiophene) nanorods Advanced Materials 17 13 2005 1616 1620 (Pubitemid 40963858)
3. I.C. Seung, and B.L. Sang Fast electrochemistry of conductive polymer nanotubes: synthesis, mechanism, and application Accounts of Chemical Research 41 6 2008 699 707
4. J.K. Lee, M. Chatzichristidi, A.A. Zakhidov, H.S. Hwang, E.L. Schwartz, and J. Sha Acid-diffusion behavior in organic thin films and its effect on patterning Journal of Materials Chemistry 19 19 2009 2986 2992
5. D. Hohnholz, H. Okuzaki, and A.G. MacDiarmid Plastic electronic devices through line patterning of conducting polymers Advanced Functional Materials 15 1 2005 51 56 (Pubitemid 40183835)
6. A. Laforgue All-textile flexible supercapacitors using electrospun poly(3,4-ethylenedioxythiophene) nanofibers Journal of Power Sources 196 1 2011 559 564
7. 2 nanoparticle enrichment in poly(3,4-ethylenedioxythiophene) nanowires for electrochemical energy storage ACS Nano 4 7 2010 4299 4307
8. K.K. Tintula, A.K. Sahu, A. Shahid, S. Pitchumani, P. Sridhar, and A.K. Shukla Mesoporous carbon and poly(3,4-ethylenedioxythiophene) composite as catalyst support for polymer electrolyte fuel cells Journal of the Electrochemical Society 157 11 2010
9. C. Arbizzani, M. Biso, E. Manferrari, and M. Mastragostino Methanol oxidation by pEDOT-pSS/PtRu in DMFC Journal of Power Sources 178 2 2008 584 590 (Pubitemid 351317875)
10. F. Jonas, and G. Heywang Technical applications for conductive polymers Electrochimica Acta 39 8-9 1994 1345 1347
11. L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, and J.R. Reynolds Poly(3,4-ethylenedioxythiophene) and its derivatives: past, present, and future Advanced Materials 12 7 2000 481 494
12. G. Heywang, and F. Jonas Poly(alkylenedioxythiophene)s - new, very stable conducting polymers Advanced Materials 4 2 1992 116 118
13. T. Yamamoto, T. Shimizu, and E. Kurokawa Doping behavior of water-soluble [pi]-conjugated polythiophenes depending on pH and interaction of the polymer with DNA Reactive and Functional Polymers 43 1-2 2000 79 84 (Pubitemid 30555560)
14. B. Winther-Jensen, and K. West Stability of highly conductive poly-3,4-ethylene-dioxythiophene Reactive and Functional Polymers 66 5 2006 479 483
15. P. Tehrani, A. Kanciurzewska, X. Crispin, N.D. Robinson, M. Fahlman, and M. Berggren The effect of pH on the electrochemical over-oxidation in PEDOT: PSS films Solid State Ionics 177 39-40 2007 3521 3527 (Pubitemid 44960502)
16. N. Sakmeche, S. Aeiyach, J.J. Aaron, M. Jouini, J.C. Lacroix, and P.C. Lacaze Improvement of the electrosynthesis and physicochemical properties of poly(3,4-ethylenedioxythiophene) using a sodium dodecyl sulfate micellar aqueous medium Langmuir 15 7 1999 2566 2574
17. L. Pigani, A. Heras, Ã. Colina, R. Seeber, and J. LÃpez-Palacios Electropolymerisation of 3,4-ethylenedioxythiophene in aqueous solutions Electrochemistry Communications 6 11 2004 1192 1198
18. E. Ventosa, A. Colina, A. Heras, A. MartÃ-nez, O. Orcajo, and V. Ruiz Electrochemical, spectroscopic and electrogravimetric detection of oligomers occluded in electrochemically synthesized poly(3,4- ethylenedioxythiophene) films Electrochimica Acta 53 12 2008 4219 4227
19. A.J.F. Romero, J.J.L. Cascales, and T.F. Otero In situ FTIR spectroscopy study of the break-in phenomenon observed for PPy/PVS films in acetonitrile Journal of Physical Chemistry B 109 44 2005 21078 21085 (Pubitemid 41698370)
20. G. Inzelt Role of polymeric properties in the electrochemical behavior of redox polymer-modified electrodes Electrochimica Acta 34 2 1989 83 91
21. J. Bobacka, A. Lewenstam, and A. Ivaska Electrochemical impedance spectroscopy of oxidized poly(3,4-ethylenedioxythiophene) film electrodes in aqueous solutions Journal of Electroanalytical Chemistry 489 1 2000 17 27
22. T. Sovány, K. Nikowitz, G. Regdon Jr., P. Kása Jr., and K. Pintye-Hódi Raman spectroscopic investigation of film thickness Polymer Testing 28 7 2009 770 772
23. S. Garreau, G. Louarn, J.P. Buisson, G. Froyer, and S. Lefrant In situ spectroelectrochemical Raman studies of poly(3,4-ethylenedioxythiophene) (PEDT) Macromolecules 32 20 1999 6807 6812
24. 14-alkyl derivative of poly(3,4-ethylenedioxythiophene) (PEDT) Electrochimica Acta 46 8 2001 1207 1214 (Pubitemid 32138992)
25. S. Garreau, J.L. Duvail, and G. Louarn Spectroelectrochemical studies of poly(3,4-ethylenedioxythiophene) in aqueous medium Synthetic Metals 125 3 2002 325 329 (Pubitemid 33125991)