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The ζ potential of the vesicular assembly was measured to be -30.20 mV, whereas it increased to -55.33 mV after the addition of an excess amount of 5. These observations further indicate the embedding phenomenon of an excess amount of 5 in the vesicles (Figures S40-S42 in the Supporting Information).
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note
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As for complex 1·5 in a 1:1.0 stoichiometric ratio, the morphologies of the assembly were also investigated by TEM images. Firstly, the vesicular assemblies can be observed from the sample prepared by using an aqueous solution of the fresh complex 1·5. After the solution of complex 1·5 remained for several hours, the vesicular aggregates disappeared and formed some amorphous aggregations.
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2O owing to self-aggregation of 5 in aqueous solution. To solve this problem, tetrasodium-meso-tetra(4-sulfonatophenyl)zinc(II) porphyrin Zn·5 was used for NMR spectroscopic studies.
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