Observation of electron-beam-induced phase evolution mimicking the effect of the charge-discharge cycle in Li-rich layered cathode materials used for Li ion batteries

Chemistry of Materials

Volumn 27, Issue 4, 2015, Pages 1375-1380

  Lu, Ping ^a   Yan, Pengfei ^b   Romero, Eric ^a   Spoerke, Erik David ^a   Zhang, Ji Guang ^c   Wang, Chong Min ^b  

^a SANDIA NATIONAL LABORATORIES   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATHODES; ELECTRIC BATTERIES; ELECTROCHEMISTRY; ELECTRODES; ELECTRON BEAMS; ELECTRON IRRADIATION; ELECTRONS; ENERGY DISPERSIVE SPECTROSCOPY; IRRADIATION; LITHIUM; LITHIUM COMPOUNDS; MANGANESE; METAL IONS; NICKEL; SALT DEPOSITS; SCANNING ELECTRON MICROSCOPY; SECONDARY BATTERIES; SURFACE DEFECTS; TRANSITION METAL COMPOUNDS; TRANSITION METALS; TRANSMISSION ELECTRON MICROSCOPY; X RAY SPECTROSCOPY;

CHARGE DISCHARGE CYCLING; CHARGE-DISCHARGE CYCLE; ELECTROCHEMICAL CHARGE; ELECTRON BEAM IRRADIATION; ENERGY DISPERSIVE X RAY SPECTROSCOPY; LAYERED CATHODE MATERIALS; LITHIUM-RICH LAYERED OXIDES; SCANNING TRANSMISSION ELECTRON MICROSCOPY;

LITHIUM BATTERIES;

EID: 84923336758     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm5045573     Document Type: Article

References (29)

1. Choi, N. S.; Chen, Z. H.; Freunberger, S. A.; Ji, X. L.; Sun, Y. K.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho, J.; Bruce, P. G. Angew. Chem., Int. Ed. 2012, 51, 9994-10024
2. Mizushima, K.; Jones, P. C.; Wiseman, P. J.; Goodenough, J. B. Mater. Res. Bull. 1980, 15, 783-789
3. Thackeray, M. M.; Johnson, C. S.; Vaughey, J. T.; Li, N.; Hackney, S. A. J. Mater. Chem. 2005, 15, 2257-2267
4. Wen, J. G.; Bareno, J.; Lei, C. H.; Kang, S. H.; Balasubramanian, M.; Petrov, I.; Abraham, D. P. Solid State Ionics 2011, 182, 98-107
5. Zheng, J.; Gu, M.; Genc, A.; Xiao, J.; Xu, P.; Chen, X.; Zhu, Z.; Zhao, W.; Pullan, L.; Wang, C.; Zhang, J. G. Nano Lett. 2014, 14, 2628-2635
6. Wang, R.; He, X. Q.; He, L. H.; Wang, F. W.; Xiao, R. J.; Gu, L.; Li, H.; Chen, L. Q. Adv. Energy Mater. 2013, 3, 1358-1367
7. Yu, X.; Lyu, Y.; Gu, L.; Wu, H.; Bak, S.-M.; Zhou, Y.; Amine, K.; Ehrlich, S. N.; Li, H.; Nam, K.-W.; Yang, X.-Q. Adv. Energy Mater. 2014, 4, n/a-n/a
8. Nam, K.-W.; Bak, S.-M.; Hu, E.; Yu, X.; Zhou, Y.; Wang, X.; Wu, L.; Zhu, Y.; Chung, K.-Y.; Yang, X.-Q. Adv. Funct. Mater. 2013, 23, 1047-1063
9. Lu, Z. H.; MacNeil, D. D.; Dahn, J. R. Electrochem. Solid-State Lett. 2001, 4, A191-A194
10. Yan, P.; Nie, A.; Zheng, J.; Zhou, Y.; Lu, D.; Zhang, X.; Xu, R.; Belharouak, I.; Zu, X.; Xiao, J.; Amine, K.; Liu, J.; Gao, F.; Shahbazian-Yassar, R.; Zhang, J. G.; Wang, C. M. Nano Lett. 2015, 15, 514-522
11. Croy, J. R.; Kim, D.; Balasubramanian, M.; Gallagher, K.; Kang, S.-H.; Thackeray, M. M. J. Electrochem. Soc. 2012, 159, A781
12. Boulineau, A.; Simonin, L.; Colin, J.-F.; Bourbon, C.; Patoux, S. Nano Lett. 2013, 13, 3857-3863
13. Xu, B.; Fell, C. R.; Chi, M.; Meng, Y. S. Energy Environ. Sci. 2011, 4, 2223-2233
14. Xu, J.; Lee, D. H.; Clement, R. J.; Yu, X. Q.; Leskes, M.; Pell, A. J.; Pintacuda, G.; Yang, X. Q.; Grey, C. P.; Meng, Y. S. Chem. Mater. 2014, 26, 1260-1269
15. Gu, M.; Genc, A.; Belharouak, I.; Wang, D.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. Chem. Mater. 2013, 25, 2319-2326
16. Gu, M.; Belharouak, I.; Zheng, J. M.; Wu, H. M.; Xiao, J.; Genc, A.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. ACS Nano 2013, 7, 760-767
17. Gu, M.; Belharouak, I.; Genc, A.; Wang, Z.; Wang, D.; Amine, K.; Gao, F.; Zhou, G.; Theuvthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. M. Nano Lett. 2012, 12, 5186-5191
18. Boulineau, A.; Simonin, L.; Colin, J.-F.; Canevet, E.; Daniel, L.; Patoux, S. Chem. Mater. 2012, 24, 3558-3566
19. Lin, F.; Markus, I. M.; Nordlund, D.; Weng, T.-C.; Asta, M. D.; Xin, H. L.; Doeff, M. M. Nat. Commun. 2014, 5, 3529-3537
20. Hobbs, L. W. In Quntitative Electron Microscopy; Chapman, J. N.; Craven, A. J., Eds.; Scottish Universities Summer Schools in Physics: Edinburgh, Scotland, 1984; Chapter 17.
21. Egerton, E. F.; Li, P.; Malac, M. Micron 2004, 35, 399-409
22. Lin, F.; Markus, I. M.; Doeff, M. M.; Xin, H. L. Sci. Rep. 2014, 4, 5694-5699
23. Zhang, X.; Xu, R.; Li, L.; Yu, C.; Ren, Y.; Belharouaka, I. J. Electrochem. Soc. 2013, 160, A1079-A1083
24. Lu, P.; Zhou, L.; Kramer, M. J.; Smith, D. J. Sci. Rep. 2014, 4, 3945-3950
25. Lu, P.; Romero, E.; Lee, S.; MacManus-Driscoll, J. L.; Jia, Q. X. Microsc. Microanal. 2014, 20, 1782-1790
26. Jarvis, K. A.; Deng, Z. Q.; Allard, L. F.; Manthiram, A.; Ferreira, P. J. Chem. Mater. 2011, 23, 3614-3621
27. Armstrong, A. R.; Holzapfel, M.; Novak, P.; Johnson, C. S.; Kang, S. H.; Thackeray, M. M.; Bruce, P. G. J. Am. Chem. Soc. 2006, 128, 8694-8698
28. Knotek, M. L.; Feibelman, P. J. Surf. Sci. 1979, 90, 78
29. McCartney, M. R.; Crozier, P. A.; Weiss, J. K.; Smith, D. J. Vacuum 1991, 42, 301-308