Photopolymerization reactions: On the way to a green and sustainable chemistry

Applied Sciences (Switzerland)

Volumn 3, Issue 2, 2013, Pages 490-514

  Tehfe, Mohamad Ali ^a   Louradour, Fanny ^a   Lalevée, Jacques ^a   Fouassier, Jean Pierre ^a  

^a UNIVERSITÉ DE HAUTE ALSACE   (France)

Author keywords

Cationic photopolymerization; Halogen lamps; Household lamps; Laser diodes; LED; Photoinitiators; Radical photopolymerization; Renewable monomers; Soft irradiation conditions; Sunlight exposure; Visible light sources

Indexed keywords

EID: 84922211307     PISSN: None     EISSN: 20763417     Source Type: Journal    
DOI: 10.3390/app3020490     Document Type: Article

References (139)

1. Radiation Curing of Polymeric Materials; Hoyle, C.E., Kinstle, J.F., Eds.; American Chemical Society: Washington, DC, USA, 1990
2. Lasers in Polymer Science and Technology: Applications; Fouassier, J.P., Rabek, J.F., Eds.; CRC Press: Boca Raton, FL, USA, 1990
3. Pappas, S.P. UV-Curing: Science and Technology; Plenum Press: New York, NY, USA, 1992
4. Radiation Curing in Polymer Science and Technology; Fouassier, J.P., Rabek, J.F., Eds.; Chapman & Hall: London, UK, 1993
5. Photoresponsive Polymers; Krongauz, V., Trifunac, A., Eds.; Chapman and Hall: New York, NY, USA, 1994
6. Reiser, A. Photoreactive Polymers: The Science and Technology of Resists; Wiley: New York, NY, USA, 1989
7. Fouassier, J.P. Photoinitiation, Photopolymerization, Photocuring: Fundamentals and Applications; Carl Hanser GmbH: Munich, Germany, 1995
8. Davidson, S. Exploring the Science, Technology and Application of UV and EB Curing; SITA Technology Ltd.: London, UK, 1999
9. Neckers, D.C. UV and EB at the Millenium; SITA Technology Ltd.: London, UK, 1999
10. Crivello, J.V.; Dietliker, K. Photoinitiators for Free Radical, Cationic and Anionic Photopolymerization; Bradley, G., Ed.; Surface Coatings Technology Series; Wiley: New York, NY, USA, 1999; Volume III
11. Dietliker, K. A Compilation of Photoinitiators Commercially Available for UV Today; SITA Technology Ltd.: London, UK, 2002
12. Belfied, K.D.; Crivello, J.V. Photoinitiated Polymerization; ACS Symp. Ser. 847; American Chemical Society: Washington, DC, USA, 2003
13. Photochemistry and UV Curing; Fouassier, J.P., Ed.; Research Signpost: Trivandrum, India, 2006
14. Photochemistry and Photophysics of Polymer Materials; Allen, N.S., Ed.; Wiley: Hoboken, NJ, USA, 2010
15. Basics of Photopolymerization Reactions; Fouassier, J.P., Allonas, X., Eds.; Research Signpost: Trivandrum, India, 2010
16. Green, W.A. Industrial Photoinitiators; CRC Press: Boca Raton, FL, USA, 2010
17. Peiffer, R.W. Photopolymerization: Fundamentals and Applications; Scranton, A.B., Bowman, A., Eds.; ACS Symp. Ser. 673; Americal Chemical Society: Washington, DC, USA, 1997
18. Handbook of Vinyl Polymers; Mishra, M.K., Yagci, Y., Eds.; CRC Press: Boca Raton, FL, USA, 2009
19. Fouassier, J.P.; Lalevée, J. Photoinitiators for Polymer Synthesis: Scope, Reactivity and Efficiency; Wiley VCH: Weinheim, Germany, 2012
20. Esposito Corcione, C.; Previderio, A.; Frigione, M. Kinetics characterization of a novel photopolymerizable siloxane-modified acrylic resin. Thermochim. Acta 2010, 509, 56-61
21. Esposito Corcione, C.; Greco, A.; Maffezzoli, A. Photopolymerization kinetics of an epoxy-based resin for stereolithography. J. Appl. Polym. Sci. 2004, 92, 3484-3491
22. Esposito Corcione, C.; Greco, A.; Maffezzoli, A. Time-temperature and time-irradiation intensity superposition for photopolymerization of an epoxy based resin. Polymer 2005, 46, 8018-8027
23. Esposito Corcione, C.; Greco, A.; Maffezzoli, A. Temperature evolution during stereolithography building with a commercial epoxy resin. Polym. Eng. Sci. 2006, 46, 493-502
24. Greco, A.; Esposito Corcione, C.; Cavallo, A.; Maffezzoli, A. Influence of stone particles on the rheological behavior of a novel photopolymerizable siloxane-modified acrylic resin. J. Appl. Polym. Sci. 2011, 122, 942-947
25. Frigione, M.; Esposito Corcione, C. Rheological and kinetic characterization of UV photopolymerizable formulations as a function of the boehmite nanoparticle content. Open Mater. Sci. J. 2012, 6, 68-76
26. Esposito Corcione, C.; Frigione, M. Factors influencing photo curing kinetics of novel UV-cured siloxane-modified acrylic coatings: Oxygen inhibition and composition. Thermochim. Acta 2012, 534, 21-27
27. Yilmaz, G.; Iskin, B.; Yilmaz, F.; Yagci, Y. Mesoporous graphitic carbon nitride as a heterogeneous visible light photoinitiator for radical polymerization. ACS Macro Lett. 2012, 1, 1212-1215
28. Karaka-Balta, D.; Temel, G.; Okal, N.; Arsu, N. Thioxanthone-diphenyl anthracene: Visible light photoinitiator. Macromolecules 2012, 45, 119-125
29. Yilmaz, G.; Acik, G.; Yagci, Y. Counteranion sensitization spproach to photoinitiated free radical polymerization. Macromolecules 2012, 45, 2219-2224
30. Kumbaraci, V.; Aydogan, B.; Talinli, N.; Yagci, Y. Naphthodioxinone-1,3-benzodioxole as photochemically masked one-component Type II photoinitiator for free radical polymerization. J. Polym. Sci. Part A 2012, 50, 2612-2618
31. Temel, G.; Enginol, B.; Aydin, M.; Karaca Balta, D.; Arsu, N. Photopolymerization and photophysical properties of amine linked benzophenone photoinitiator for free radical polymerization. J. Photochem. Photobiol. A 2011, 219, 26-31
32. Keskin Dogruyol, S.; Dogruyol, Z.; Arsu, N. A thioxanthone-based visible photoinitiator. J. Polym. Sci. Part A 2011, 49, 4037-4040
33. Sevinc Esen, D.; Karasu, F.; Arsu, N. The investigation of photoinitiated polymerization of multifunctional acrylates with TX-BT by Photo-DSC and RT-FTIR. Progr. Org. Coat. 2011, 70, 102-107
34. Korkut, S.E.; Temel, G.; Karaca Balta, D.; Arsu, N.; Kasim Sener, M. Type II photoinitiator substituted zinc phthalocyanine: Synthesis, photophysical and photopolymerization studies. J. Luminescence 2013, 136, 389-394
35. Asvos, X.; Siskos, M.G.; Zarkadis, A.K.; Hermann, R.; Brede, O. The 2-benzoyl xanthone/triethylamine system as a type II photoinitiator: A laser flash photolysis and computational study. J. Photochem. Photobiol. A 2011, 219, 255-264
36. Santos, W.G.; Schmitt, C.C.; Neumann, M.G. Polymerization of HEMA photoinitiated by the Safranine/diphenylborinate system. J. Photochem. Photobiol. A 2013, 252, 124-130
37. Kitano, H.; Ramachandran, K.; Bowden, N.B.; Scranton, A.B. Unexpected visible-light-induced free radical photopolymerization at low light intensity and high viscosity using a titanocene photoinitiator. J. Appl. Polym. Sci. 2013, 128, 611-618
38. Han, J.; Wang, J.; Shen, K.; Wang, G.; Li, Y.; Zhao, D. Synthesis of novel photochromic spiropyran dyes containing quaternary ammonium salt or cinnamoyl moiety and their properties as photoinitiators. J. Appl. Polym. Sci. 2012, 126, 30-37
39. Ivan, M.G.; Scaiano, J.C. Photoimaging and Photolithographic Process in Polymers. In Handbook on Photochemistry and Photophysics of Polymer Materials; Allen, N.S., Ed.; Wiley: Hoboken, NJ, USA, 2010; pp. 479-508
40. Muftuogli, A.E.; Tasdelen, M.A.; Yagci, Y. Photografting of Polymeric Materials. In Handbook on Photochemistry and Photophysics of Polymer Materials; Allen, N.S., Ed.; Wiley: Hoboken, NJ, USA, 2010; pp. 509-540
41. Yang, J.; Shi, S.; Xu, F.; Nie, J. Synthesis and photopolymerization kinetics of benzophenone sesamol one-component photoinitiator. Photochem. Photobiol. Sci. 2013, 12, 323-329
42. Rosspeintner, A.; Griesser, M.; Pucher, N.; Iskra, K.; Liska, R.; Gescheidt, G. Toward the photoinduced reactivity of 1,5-diphenylpenta-1,4-diyn-3-one (DPD): Real-time investigations by magnetic resonance. Macromolecules 2009, 42, 8034-8038
43. Moszner, N.; Lamparth, I.; Angermann, J.; Fischer, U.K.; Zeuner, F.; Bock, T.; Liska, R.; Rheinberger, V. Synthesis of bis(3-([2-(allyloxy)ethoxy]methyl)-2,4,6-trimethylbenzoyl)(phenyl)phosphine oxide-A tailor-made photoinitiator for dental adhesives. Beilstein J. Org. Chem. 2010, 6, 1-9
44. Dworak, C.; Kopeinig, S.; Hoffmann, H.; Liska, R. Photoinitiating monomers based on diand triacryloylated hydroxylamine derivatives. J. Polym. Sci. Part A 2009, 47, 392-403
45. Li, Z.; Siklos, M.; Pucher, N.; Cicha, K.; Ajami, A.; Husinsky, W.; Rosspeintner, A.; Vauthey, E.; Gescheidt, G.; Stampfl, J.; et al. Synthesis and structure-activity relationship of several aromatic ketone-based two-photon initiators. J. Polym. Sci. Part A 2011, 49, 3688-3699
46. Yagci, Y.; Jockusch, S.; Turro, N.J. Photoinitiated polymerization: advances, challenges, and opportunities. Macromolecules 2010, 43, 6245-6260
47. Kabatc, J.; Jurek, K. Free radical formation in three-component photoinitiating systems. Polymer 2012, 53, 1973-1980
48. Czech, Z.; Butwin, A.; Kabatc, J. Photoreactive s-triazine as crosslinking agents for UV-crosslinkable acrylic pressure-sensitive adhesives. J. Appl. Polym. Sci. 2011, 120, 3621-3627
49. Jedrzejewska, B.; Urbanski, S. Studies on an argon laser-induced photopolymerization employing both mono-and bischromophoric hemicyanine dye-borate complex as a photoinitiator. Part III. J. Appl. Polym. Sci. 2010, 118, 1395-1405
50. Kabatc, J.; Krzyzanowska, E.; Jedrzejewska, B.; Pietrzak, M.; Paczkowski, J. Novel N-ethyl-2-styrylquinolinum iodides as sensitizers in photoinitiated free radical polymerization of trimethylolopropane triacrylate (TMPTA). J. Appl. Polym. Sci. 2010, 118, 165-172
51. Lalevée, J.; Tehfe, M.A.; Allonas, X.; Foussier, J.P. Photoinitiating systems based on unusual radicals. In Polymer Initiators; Ackrine, W.J., Ed.; Nova Science Publishers, Inc.: Hauppauge, NY, USA, 2010; chapter 8
52. Lalevée, J.; Tehfe, M.A.; Blanchard, N.; Morlet-Savary, F.; Fouassier, J.P. Redox or photoinduced ring opening polymerization: Initiating systems based on organosilanes bearing a Si-Si bond. In Radical Polymerization: New Developments; Pauloskas, I.O., Urbonas, L.A., Eds.; Nova Science Publishers, Inc.: Hauppauge, NY, USA, 2011; chapter 7
53. Fouassier, J.P.; Lalevée, J. Three-component photoinitiating systems: Towards innovative tailor made high performance combinations. Adv. Chem. 2012, 2, 2621-2629
54. Lalevée, J.; Fouassier, J.P. Overview of Radical Initiation. In Encyclopedia of Radicals in Chemistry, Biology and Materials; Studer, A., Chatgilialoglou, C., Eds.; Wiley: New York, NY, USA, 2012; Volume 1, chapter 2
55. Lalevee, J.; EL Roz, M.; Allonas, X.; Fouassier, J.P. On the silyl radical chemistry in photopolymerization reactions. In Organosilanes: Properties, Performance and Applications; Wyman, E., Skief, M.C., Eds.; Nova Science Publishers: Hauppauge, NY, USA, 2009; chapter 6
56. Fouassier, J.P.; Lalevée, J. Design of Chromophores for Photoinitiators of Polymerization: Brief Survey and Recent Achievements. In New Developments in Chromophore Research; Nova Science Publishers: Hauppauge, NY, USA; in press
57. Lalevée, J.; Tehfe, M.A.; Dumur, F.; Gigmes, D.; Morlet-Savary, F.; Graff, B.; Fouassier, J.P. Green light induced cationic ring opening polymerization reactions: Perylene bis-dicarboximides as efficient photosensitizers. Macromol Chem. Phys. 2013, doi:10.1002/macp.201200728
58. Tehfe, M.A.; Dumur,F.; Graff, B.; Clément, J.L.; Gigmes, D.; Morlet-Savary, F.; Fouassier, J.P.; Lalevée, J. A new cleavable photoinitiator architecture with huge molar extinction coefficients for polymerization in the 340-420 nm range. Macromolecules 2013, 46, 736-746
59. Lalevée, J.; El Roz, M.; Tehfe, M.A.; Allonas, X.; Fouassier, J.P. Long wavelength cationic photopolymerization in aerated media: A remarkable titanocene/tris(trimethylsilyl)silane/onium salt photoinitiating system. Macromolecules 2009, 42, 8669-8674
60. Lalevée, J.; Blanchard, N.; Fries, C.; Tehfe, M.A.; Morlet-Savary, F.; Fouassier, J.P. New thioxanthone and xanthone derivative based on silyl radical chemistry. Polym. Chem. 2011, 2, 1077-1084
61. Tarzi, O.I.; Allonas, X.; Ley, C.; Fouassier, J.P. Pyrromethene derivatives in three-component photoinitiating systems for free radical photopolymerization. J. Polym. Sci. Part A 2010, 48, 2594-2603
62. Tehfe, M.A.; Dumur, F.; Contal, E.; Graff, B.; Gigmes, D.; Morlet-Savary, F.; Fouassier, J.P.; Lalevée, J. New insights in radical and cationic polymerization upon visible light exposure: Role of novel photoinitiator systems based on the pyrene chromophore. Polym. Chem. 2013, 4, 1625-1634
63. Telitel, S.; Blanchard, N.; Schweitzer, S.; Morlet-Savary, F.; Graff, B.; Fouassier, J.P.; Lalevée, J. Bodipy derivatives and boranil as new photoinitiating systems of cationic polymerization exhibiting a tunable absorption in the 400-600 nm spectral range. Polymer 2013, doi:10.1016/j.polymer.2013.02.013
64. Tehfe, M.A.; Dumur, F.; Morlet-Savary, F.; Graff, B.; Fouassier, J.P.; Gigmes, D.; Lalevée, J. Trifunctional photoinitiators based on a triazine skeleton for visible light sources and UV LED induced polymerizations. Macromolecules 2012, 45, 8639-8647
65. Telitel, S.; Lalevée, J.; Blanchard, N.; Kavalli, T.; Tehfe, M.A.; Morlet-Savary, F.; Graff, B.; Fouassier, J.P. Photopolymerization of cationic monomers and acrylate/divinylether blends under visible lights using pyrromethene dyes. Macromolecules 2012, 45, 6864-6868
66. Tehfe, M.A.; Zein-Fakih, A.; Lalevée, J.; Dumur, F.; Gigmes, D.; Morlet-Savary, F.; Fouassier, J.P. Pyridinium salts: New systems for photopolymerization reactions upon visible light exposure. Eur. Polym. J. 2013, 49, 567-574
67. Tehfe, M.A.; Lalevée, J.; Dumur, F.; Zein-Fakih, A.; Gigmes, D.; Morlet-Savary, F.; Fouassier, J.P. Dye photosensitized cationic ring-opening polymerization: search for new dye skeletons. Polymer 2012, 53, 4947-4954
68. Tehfe, M.A.; Lalevée, J.; Fouassier, J.P. A breakthrough for long wavelength absorbing photoinitiating systems under soft irradiation conditions based on violanthrone derivatives. Macromolecules 2011, 44, 8374-8379
69. Lalevée, J.; Tehfe, M.A.; Morlet-Savary, F.; Fouassier, J.P. Cationic photosensitive formulations based on the silyl radical chemistry for green and red diode laser exposure. Polym. Chem. 2012, 3, 1899-1902
70. Lalevée, J.; Blanchard, N.; Tehfe, M.A.; Peter, M.; Morlet-Savary, F.; Fouassier, J.P. Household LED irradiation under air: Cationic polymerization using iridium or ruthenium complex photocatalysts. Polym. Bull. 2012, 68, 341-347
71. Lalevée, J.; Dumur, F.; Mayer, C.R.; Gigmes, D.; Nasr, G.; Tehfe, M.A.; Morlet-Savary, F.; Telitel, S.; Graff, B.; Fouassier, J.P. Photopolymerization of N-vinylcarbazole using visible-light harvesting iridium complexes as photoinitiators. Macromolecules 2012, doi:10.1021/ma3005229
72. Tehfe, M.A.; Lalevée, J.; Telitel, S.; Sun, J.; Zhao, J.; Morlet-Savary, F.; Graff, B.; Fouassier, J.P. Iridium complexes incorporating coumarin moiety as photocatalysts for ring opening photopolymerizations. Polymer 2012, 53, 2803-2808
73. Tehfe, M.A.; Dumur, F.; Graff, B.; Morlet-Savary, F.; Gigmes, D.; Fouassier, J.P.; Lalevée, J. Design of new Type I & Type II photoinitiators possessing highly coupled pyrene-ketone moieties. Polym. Chem. 2013, 4, 2313-2324
74. Tehfe, M.A.; Dumur, F.; Graff, B.; Morlet-Savary, F.; Gigmes, D.; Fouassier, J.P.; Lalevée, J. Light harvesting organic photoinitiators of polymerization. Macromol. Rapid Comm. 2013, 34, 239-245
75. Tehfe, M.A.; Lalevée, J.; Morlet-Savary, F.; Graff, B.; Blanchard, N.; Fouassier, J.P. Organic photocatalyst for polymerization reactions: 9,10-bis[(triisopropylsilyl)ethynyl] anthracene. ACS Macro Lett. 2012, 1, 198-203
76. Tehfe, M.A.; Lalevée, J.; Telitel, S.; Contal, E.; Dumur, F.; Gigmes, D.; Bertin, D.; Nechab, M.; Bertrand, M.; Morlet-Savary, F.; et al. Polyaromatic structures as organophotocatalysts for efficient dual radical/cationic photopolymerizations under visible lights and interpenetrated polymer networks synthesis. Macromolecules 2012, 45, 4454-4460
77. Lalevée, J.; Fouassier, J.P. Recent advances in sunlight induced polymerization: Role of new photoinitiating systems based on the silyl chemistry. Polym. Chem. 2011, 2, 1107-1113
78. Eiselé, G.; Fouassier, J.-P.; Reeb, R. Kinetics of photocrosslinking reactions of a DCPA/EA matrix in the presence of thiols and acrylates. J. Polym. Sci. Part A 1997, 35, 2333-2345
79. Bibaut-Renauld, C.; Burget, D.; Fouassier, J.-P.; Varelas, C.-G.; Thomatos, J.; Tsagaropoulos, G.; Ryrfors, L.O.; Karlsson, O.J. Use of α-diketones as visible photoinitiators for the photocrosslinking of waterborne latex paints. J. Polym. Sci. Part A 2002, 40, 3171-3181
80. Decker, C.; Bendaikha, T. Interpenetrating polymer networks. II. Sunlight-induced polymerization of multifunctional acrylates. J. Appl. Polym. Sci. 1998, 70, 2269-2282
81. Chiang, W.; Lin, W.T. Syntheses and cured films properties of UV-autocurable BTDA-based multiacrylate resins. J. Appl. Polym. Sci. 1994, 51, 1901-1909
82. Chiang, W.; Ding, F.C. Synthesis and properties of ultraviolet-curable resins via a thio-ene (thiol and allyl) addition reaction. J. Appl. Polym. Sci. 2002, 86, 1878-1885
83. Zang, H.L.; Massingilland, J.L.; Woo, J.T. Zero VOC sunlight curable coatings. J. Coat. Technol. 2000, 72, 79-81
84. Decker, C.; Zahouily, K.; Decker, D.; Nguyen Thi Viet, T. Performance analysis of acylphosphine oxides in photoinitiated polymerization. Polymer 2001, 42, 7551-7560
85. Paczkowska, B.; Strzelec, S.; Linden, L.A.; Packowski, D. Photochemical preparation of polymer-clay composites. J. Appl. Clay Sci. 2004, 25, 221-227
86. Ledwith, A. Possibilities for promoting cationic polymerization by common sources of free radicals. Polymer 1978, 19, 1217-1219
87. Baumann, H.; Timpe, H.J. Lichtinitiierte polymer-und polymerisationsreaktionen. photoinduzierte zersetzung von diaryliodonium-und triarylsulfoniumsalzen durch benzoinderivate und benzilketale. Z. Chem. 1984, 24, 18-19
88. Yagci, Y.; Schnabel, W. Acylphosphine oxides as free radical promoters in cationic polymerizations. Makromol. Chem. Rapid Commun. 1987, 8, 209-213
89. Yagci, Y.; Kminek, I.; Schnabel, W. Long wavelength photoinitiated cationic polymerization using diphenyliodonium salt and catena-poly (phenyl-4-phenylphenylsilicon). Polymer 1993, 34, 426-428
90. Yagci, Y.; Ledwith, A. Mechanistic and kinetic studies on the photoinitiated polymerization of tetrahydrofuran. J. Polym. Sci. Part A 1988, 26, 1911-1918
91. Crivello, J.V.; Sangermano, M. Visible and long-wavelength photoinitiated cationic polymerization. J. Polym. Sci. Part A 2001, 39, 343-356
92. Dursun, C.; Degirmenci, M.; Yagci, Y.; Jockusch, S.; Turro, N.J. Free radical promoted cationic polymerization by using bisacylphosphine oxide photoinitiators: Substituent effect on the reactivity of phosphinoyl radicals. Polymer 2003, 44, 7389-7396
93. Crivello, J.V. Radical-promoted visible light photoinitiated cationic polymerization of epoxides. J. Macromol. Sci. Part A 2009, 46, 474-483
94. Yagci, Y.; Denizligil, S. Photoinitiated cationic polymerization using O-phthaldehyde and pyridinium salt. J. Polym. Sci. Part A 1995, 33, 1461-1464
95. Yagci, Y.; Reetz, I. Externally stimulated initiator systems for cationic polymerization. Prog. Polym. Sci. 1998, 23, 1485-1538
96. Bulut, U.; Gunbas, G.E.; Topare, L. A quinoxaline derivative as a long wavelength photosensitizer for diaryliodonium salts. J. Polym. Sci. Part A 2010, 48, 209-213
97. Crivello, J.V. A new visible light sensitive photoinitiator system for the cationic polymerization of epoxides. J. Polym. Sci. Part A 2009, 47, 866-875
98. Crivello, J.V.; Bulut, U. Curcumin: A naturally occurring long-wavelength photosensitizer for diaryliodonium salts. J. Polym. Sci. Part A 2005, 43, 5217-5321
99. Lalevée, J.; Blanchard, N.; Tehfe, M.A.; Chany, A.C.; Morlet-Savary, F.; Fouassier, J.P. Green bulb lamp induced cationic photopolymerization reactions under air. Macromolecules 2010, 43, 10191-10195
100. Lalevée, J.; Tehfe, M.A.; Morlet-Savary, F.; Graff, B.; Allonas, X.; Fouassier, J.P. Oxygen mediated and wavelength tunable cationic photopolymerization reactions under air and low Intensity: A new concept. Progr. Organ. Coat. 2011, 70, 23-31
101. Tehfe, M.A.; Lalevée, J.; Gigmes, D.; Fouassier, J.P. Green Chemistry: sunlight induced cationic polymerization of renewable epoxy monomer under air. Macromolecules 2010, 43, 1364-1370
102. Tehfe, M.A.; Blanchard, N.; Fries, C.; Lalevée, J.; Allonas, X.; Fouassier, J.P. Bis(germyl)ketones: Toward a new class of type I photoinitiating systems under visible light irradiation. Macromol. Rapid Comm. 2010, 31, 473-478
103. Telitel, S.; Schweitzer, S.; Morlet-Savary, F.; Graff, B.; Tschamber, T.; Blanchard, N.; Fouassier, J.P.; Lelli, M.; Lacôte, E.; Lalevée, J. Soft photopolymerizations initiated by dye-sensitized formation of NHC-boryl radicals under visible lights. Macromolecules 2013, 46, 43-48
104. Lalevée, J.; Tehfe, M.A.; Zein-Fakih, A.; Ball, B.; Telitel, S.; Morlet-Savary, F.; Graff, B.; Fouassier, J.P. N-vinylcarbazole: an additive for free radical promoted cationic polymerization upon visible-light. ACS Macro Lett. 2012, 1, 802-806
105. Tehfe, M.-A.; Lalevée, J.; Morlet-Savary, F.; Graff, B.; Fouassier, J.-P. On the use of bis(cyclopentadienyl)titanium(IV) dichloride in visible light induced ring opening photopolymerization. Macromolecules 2011, 44, 8374-8379
106. Lalevée, J.; Tehfe, M.-A.; Dumur, F.; Gigmes, D.; Blanchard, N.; Morlet-Savary, F.; Fouassier, J.-P. Iridium photocatalysts in free radical polymerization under visible lights. ACS Macro Lett. 2012, 1, 286-290
107. Tehfe, M.-A.; Lalevée, J.; Morlet-Savary, F.; Graff, B.; Blanchard, N.; Fouassier, J.-P. Tunable Organophotocatalysts for polymerization reactions under visible lights, macromolecules. Macromolecules 2012, 45, 1746-1752
108. Nicewicz, D.A.; MacMillan, D.W.C. Merging photoredox catalysis with organocatalysis: The direct asymmetric alkylation of aldehydes. Science 2008, 322, 77-80
109. Shih, H.-W.; Vander Wal, M.N.; Grange, R.L.; MacMillan, D.W.C. Enantioselective α-benzylation of aldehydes via photoredox organocatalysis. J. Am. Chem. Soc. 2010, 132, 13600-13603
110. Zeitler, K. Photoredox catalysis with visible light. Angew. Chem. Int. Ed. 2009, 48, 9785-9789
111. Narayanam, J.M.R.; Stephenson, C.R.J. Visible light photoredox catalysis: Applications in organic synthesis. Chem. Soc. Rev. 2011, 40, 102-113
112. Dai, C.; Narayanam, J.M.R.; Stephenson, C.R.J. Visible-light-mediated conversion of alcohols to halides. Nat. Chem. 2011, 3, 140-145
113. Ischay, M.A.; Lu, Z.; Yoon, T.P. [2+2] cycloadditions by oxidative visible light photocatalysis. J. Am. Chem. Soc. 2010, 132, 8572-8574
114. Yoon, T.P.; Ischay, M.A.; Du, J. Visible light photocatalysis as a greener approach to photochemical synthesis. Nat. Chem. 2010, 2, 527-532
115. Larraufie, M.H.; Pellet, R.; Fensterbank, L.; Goddard, J.P.; Lacôte, E.; Malacria, M.; Ollivier, C. Visible-light-induced photoreductive generation of radicals from epoxides and aziridines. Angew. Chem. Int. Ed. 2011, 50, 4463-4466
116. Courant, T.; Masson, G. Photoredox-initiated α-alkylation of imines through a three-component radical/cationic reaction. Chem. Eur. J. 2012, 18, 423-427
117. Zhang, G.; Song, I.Y.; Ahn, K.H.; Park, T.; Choi, W. Free radical polymerization initiated and controlled by visible light photocatalysis at ambient temperature. Macromolecules 2011, 44, 7594-7599
118. Pelletier, H.; Belgacem, N.; Gandini, A. Acrylated vegetable oils as photocrosslinkable materials. J. Appl. Polym. Sci. 2006, 99, 3218-3221
119. Durmaz, Y.Y.; Karagoz, B.; Bicak, N.; Yagci, Y. Synthesis of block copolymers by combination of ATRP and photoiniferter processes. Polym. Intern. 2008, 57, 1182-1187
120. Dworak, C.; Koch, T.; Varga, F.; Liska, R. Photopolymerization of biocompatible phosphorus-containing vinyl esters and vinyl carbamates. J. Polym. Sci. Part A 2010, 48, 2916-2924
121. Nagata, M.; Inaki, K. Biodegradable and photocurable multiblock copolymers with shape-memory properties from poly(e-caprolactone) diol, poly(ethylene glycol), and 5-cinnamoyloxyisophthalic acid. J. Appl. Polym. Sci. 2011, 120, 3556-3564
122. Jabbari, E.; He, X. Synthesis and characterization of bioresorbable in situ crosslinkable ultra low molecular weight poly(lactide) macromer. J. Mater. Sci. Mater. Med. 2008, 19, 311-318
123. Bayramoglu, G.; Kayaman-Apohan, N.; Vezir Kahraman, M.; Karadenizli, S.; Erdem Kuruca, S.; Güngör, A. Preparation of bow tie-type methacrylated poly(caprolactone-co-lactic acid) scaffolds: Effect of collagen modification on cell growth. Polym. Adv. Techn. 2012, 23, 1403-1413
124. Schuster, M.; Turecek, C.; Weigel, G.; Saf, R.; Stampfl, J.; Varga, F.; Liska, R. Vinyl esters: Low cytotoxicity monomers for the fabrication of biocompatible 3D scaffolds by lithography based additive manufacturing. J. Polym. Sci. Part A 2009, 47, 7078-7089
125. Hedin, J.; Oestlund, A.; Nyden, M. UV induced cross-linking of starch modified with glycidyl methacrylate. Carbohydr. Polym. 2010, 79, 606-613
126. Barrett, D.G.; Merkel, T.J.; Luft, J.C.; Yousaf, M.N. One-step syntheses of photocurable polyesters based on a renewable resource. Macromolecules 2010, 43, 9660-9667
127. Jiratumnukul, N.; Itarat, R. Ultraviolet curable epoxidized sunflower oil/organo clay nanocomposite coatings. J. Appl. Polym. Sci. 2008, 110, 2164-2167
128. Shibata, M.; Teramoto, N.; Someya, Y.; Suzuki, S. Bio-based nanocomposites composed of photo-cured epoxidized soybean oil and supramolecular hydroxystearic acid nanofibers. J. Polym. Sci. Part B 2009, 47, 669-673
129. Gupta, M.K.; Singh, R.P. Cationic Initiators in Photocuring Applications. In Basics of Photopolymerization Reactions; Fouassier, J.P., Allonas, X., Eds.; Research Signpost: Trivandrum, India, 2010; Volume 1, pp. 23-35
130. Acosta Ortiz, R.; Prieto López, D.; Guillén Cisneros, M.L.; Rico Valverde, J.C.; Crivello, J.V. A kinetic study of the acceleration effect of substituted benzyl alcohol on the cationic photopolymerization rate of epoxidized natural oils. Polymer 2005, 46, 1535-1541
131. Decker, C.; Nguyen Thi Viet, T.; Le Xuan, H. Photoréticulation de caoutchoucs fonctionnalisés: Polymérisation cationique de caoutchoucs époxydés. Eur. Polym. J. 1996, 32, 1319-1326
132. Crivello, J.V.; Narajan, R.; Sternstein, S.S. Fabrication and mechanical characterization of glass fiber reinforced UV-cured composites from epoxidized vegetable oils. J. Appl Polym Sci. 1997, 64, 2073-2087
133. Desroches, M.; Caillol, S.; Lapinte, V.; Auvergne, R.; Boutevin, B. Synthesis of biobased polyols by thiol-ene coupling from vegetable oils. Macromolecules 2011, 44, 2489-2500
134. Raj Mahendran, A.; Wuzella, G.; Aust, N.; Kandelbauer, A. Photocrosslinkable modified vegetable oil based resin for wood surface coating application. Progr. Org. Coatings 2012, 74, 697-704
135. Kollbe Ahn, B.; Sung, J.; Kim, N.; Kraft, S.; Susan Sun, X. UV-curable pressure-sensitive adhesives derived from functionalized soybean oils and rosin ester. Polym. Int. 2012, doi:10.1002/pi.4420
136. Thanamongkollit, N.; Miller, K.R.; Soucek, M.D. Route to co-acrylic modified alkyd resins via a controlled polymerization technique. Progr. Org. Coat. 2012, 73, 425-434
137. Teck Chye Ang, D.; Neon Gan, S. Novel approach to enhance film properties of environmentally friendly UV-curable alkyd coating using epoxidised natural rubber. Progr. Org. Coat. 2012, 73, 409-414
138. Teck Chye Ang, D.; Neon Gan, S. Environment friendly UV-curable resins from palm stearin alkyds. J. Appl. Polym. Sci. 2012, 125, 306-313
139. Bao, Y.; He, J.; Li, Y. Facile and efficient synthesis of hyperbranched polyesters based on renewable castor oil. Polym. Int. 2012, doi:10.1002/pi.4440