Effects of mesostructured silica catalysts on the depolymerization of organosolv lignin fractionated from woody eucalyptus

Bioresource Technology

Volumn 180, Issue , 2015, Pages 222-229

  Klamrassamee, Thepparat ^a   Laosiripojana, Navadol ^a   Cronin, Dylan ^b   Moghaddam, Lalehvash ^b   Zhang, Zhanying ^b   Doherty, William O S ^b  

^a KING MONGKUT'S UNIVERSITY OF TECHNOLOGY THONBURI   (Thailand)

^b QUEENSLAND UNIVERSITY OF TECHNOLOGY   (Australia)

Author keywords

Depolymerization; Fractionation; Lignin; Mesostructured silica; Syringol

Indexed keywords

CATALYSTS; CHROMATOGRAPHY; DEPOLYMERIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FRACTIONATION; GAS CHROMATOGRAPHY; LIGNIN; MASS SPECTROMETRY; SILICA; ZIRCONIUM ALLOYS;

FOURIER TRANSFORM INFRA RED (FTIR) SPECTROSCOPY; GAS CHROMATOGRAPHY-MASS SPECTROMETRIES (GC-MS); MESOSTRUCTURED SILICA; METHANOL/WATER MIXTURES; ORGANOSOLV LIGNIN; PHENOLIC COMPOUNDS; SOLID/LIQUID RATIOS; SYRINGOL;

WOOD;

4 METHYL 2 PENTANONE; LIGNIN; METHANOL; PHENOL DERIVATIVE; SILICON DIOXIDE; SYRINGOL; SBA-15; SOLVENT;

ABSORPTION; ACIDITY; CATALYST; DICOTYLEDON; ETHER; FRACTIONATION; METHANOL; PHENOLIC COMPOUND; SILICA; SOLVENT; TEMPERATURE EFFECT; WOODY PLANT;

ABSORPTION; ACIDITY; ARTICLE; CATALYST; DEPOLYMERIZATION; EUCALYPTUS; FRACTIONATION; HIGH TEMPERATURE; INFRARED SPECTROSCOPY; LIQUEFACTION; MASS FRAGMENTOGRAPHY; MOLECULAR WEIGHT; NONHUMAN; PHYSICAL CHEMISTRY; PRIORITY JOURNAL; WOOD CHIP; CATALYSIS; CHEMISTRY; POLYMERIZATION; WOOD;

CATALYSTS; EUCALYPTUS; FRACTIONATION; ORGANOSOLV LIGNINS; SILICA;

EUCALYPTUS;

CATALYSIS; EUCALYPTUS; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; LIGNIN; METHANOL; PHENOLS; POLYMERIZATION; SILICON DIOXIDE; SOLVENTS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; WOOD;

EID: 84921505557     PISSN: 09608524     EISSN: 18732976     Source Type: Journal    
DOI: 10.1016/j.biortech.2014.12.098     Document Type: Article

References (33)

1. Bai Y.Y., Xiao L.P., Shi Z.J., Sun R.C. Structural variation of bamboo lignin before and after ethanol organosolv pretreatment. Int. J. Mol. Sci. 2013, 14:21394-213413.
2. Barbier J., Charon N., Dupassieux N., Loppinet-Serani A., Mahé L., Ponthus J., Courtiade M., Ducrozet A., Quoineaud A.-A., Cansell F. Hydrothermal conversion of lignin compounds. A detailed study of fragmentation and condensation reaction pathways. Biomass Bioenergy 2012, 46:479-491.
3. Beauchet R., Monteil-Rivera F., Lavoie J.M. Conversion of lignin to aromatic-based chemicals (L-chems) and biofuels (L-fuels). Bioresour. Technol. 2012, 121:328-334.
4. Boeriu C.G., Bravo D., Gosselink R.J.A., van Dam J.E.G. Characterisation of structure-dependent functional properties of lignin with infrared spectroscopy. Ind. Crop. Prod. 2004, 20:205-218.
5. Boerjan W., Ralph J., Baucher M. Lignin biosynthesis. Ann. Rev. Plant Biol. 2003, 54:519-546.
6. Casas A., Oliet M., Alonso M.V., Rodríguez F. Dissolution of Pinus radiata and Eucalyptus globulus woods in ionic liquids under microwave radiation: lignin regeneration and characterization. Sep. Purif. Technol. 2012, 97:115-122.
7. Deepa A.K., Dhepe P.L. Solid acid catalyzed depolymerization of lignin into value added aromatic monomers. RSC Adv. 2014, 4:12625-12629.
8. El Hage R., Brosse N., Chrusciel L., Sanchez C., Sannigrahi P., Ragauskas A. Characterization of milled wood lignin and ethanol organosolv lignin from miscanthus. Polym. Degrad. Stabil. 2009, 94:1632-1638.
9. El Hage R., Brosse N., Sannigrahi P., Ragauskas A. Effects of process severity on the chemical structure of Miscanthus ethanol organosolv lignin. Polym. Degrad. Stabil. 2010, 95:997-1003.
10. El Mansouri N.-E., Salvadó J. Analytical methods for determining functional groups in various technical lignins. Ind. Crop. Prod. 2007, 26:116-124.
11. Guo F., Fang Z., Xu C.C., Smith R.L. Solid acid mediated hydrolysis of biomass for producing biofuels. Prog. Energy Combust. Sci. 2012, 38:672-690.
12. Ibarra D., del Río J.C., Gutiérrez A., Rodríguez I.M., Romero J., Martínez M.J., Martínez Á.T. Chemical characterization of residual lignins from eucalypt paper pulps. J. Anal. Appl. Pyrol. 2005, 74:116-122.
13. Kang S., Li X., Fan J., Chang J. Hydrothermal conversion of lignin: a review. Renew. Sust. Energy Rev. 2013, 27:546-558.
14. Klamrassamee T., Champreda V., Reunglek V., Laosiripojana N. Comparison of homogeneous and heterogeneous acid promoters in single-step aqueous-organosolv fractionation of eucalyptus wood chips. Bioresour. Technol. 2013, 147:276-284.
15. Kleinert M., Barth T. Phenols from lignin. Chem. Eng. Technol. 2008, 31:736-745.
16. Kobayashi H., Ohta H., Fukuoka A. Conversion of lignocellulose into renewable chemicals by heterogeneous catalysis. Catal. Sci. Technol. 2012, 2:869-883.
17. Laurichesse S., Avérous L. Chemical modification of lignins: towards biobased polymers. Prog. Polym. Sci. 2014, 39:1266-1290.
18. Moghaddam L., Zhang Z., Wellard R.M., Bartley J.P., O'Hara I.M., Doherty W.O.S. Characterisation of lignins isolated from sugarcane bagasse pretreated with acidified ethylene glycol and ionic liquids. Biomass Bioenergy 2014, 70:498-512.
19. Mousavioun P., Doherty W.O.S., George G. Thermal stability and miscibility of poly(hydroxybutyrate) and soda lignin blends. Ind. Crop. Prod. 2010, 32:656-661.
20. Nguyen T.D.H., Maschietti M., Belkheiri T., Åmand L.-E., Theliander H., Vamling L., Olausson L., Andersson S.-I. Catalytic depolymerisation and conversion of Kraft lignin into liquid products using near-critical water. J. Supercrit. Fluids 2014, 86:67-75.
21. Pandey M.P., Kim C.S. Lignin depolymerization and conversion: a review of thermochemical methods. Chem. Eng. Technol. 2011, 34:29-41.
22. Pu Y., Cao S., Ragauskas A.J. Application of quantitative 31P NMR in biomass lignin and biofuel precursors characterization. Energy Environ. Sci. 2011, 4:3154-3166.
23. Rencoret J., Gutierrez A., Nieto L., Jimenez-Barbero J., Faulds C.B., Kim H., Ralph J., Martinez A.T., Del Rio J.C. Lignin composition and structure in young versus adult Eucalyptus globulus plants. Plant Physiol. 2011, 155:667-682.
24. Roberts V.M., Stein V., Reiner T., Lemonidou A., Li X., Lercher J.A. Towards quantitative catalytic lignin depolymerization. Chemistry 2011, 17:5939-5948.
25. Salas P., Chen L.F., Wang J.A., Armendariz H., Guzman M.L., Montoya J.A., Acosta D.R. Thermal stability and surface acidity of mesoporous silica doubly doped by incorporation of sulfate and zirconium ions. Appl. Surf. Sci. 2005, 252:1123-1131.
26. Singh S.K., Ekhe J.D. Towards effective lignin conversion: HZSM-5 catalyzed one-pot solvolytic depolymerization/hydrodeoxygenation of lignin into value added compounds. RSC Adv. 2014, 4:27971-27978.
27. Sluiter J.B., Ruiz R.O., Scarlata C.J., Sluiter A.D., Templeton D.W. Compositional analysis of lignocellulosic feedstocks. 1. Review and description of methods. J. Agric. Food Chem. 2010, 58:9043-9053.
28. Toledano A., Serrano L., Labidi J. Organosolv lignin depolymerization with different base catalysts. J. Chem. Technol. Biotechnol. 2012, 87:1593-1599.
29. Vanholme R., Demedts B., Morreel K., Ralph J., Boerjan W. Lignin biosynthesis and structure. Plant Physiol. 2010, 153:895-905.
30. Wang H., Tucker M., Ji Y. Recent development in chemical depolymerization of lignin: a review. J. Appl. Chem. 2013, 2013:1-9.
31. Zakzeski J., Bruijnincx P.C.A., Jongerius A.L., Weckhuysen B.M. The catalytic valorization of lignin for the production of renewable chemicals. Chem. Rev. 2010, 110:3552-3599.
32. Zakzeski J., Jongerius A.L., Bruijnincx P.C., Weckhuysen B.M. Catalytic lignin valorization process for the production of aromatic chemicals and hydrogen. ChemSusChem 2012, 5:1602-1609.
33. Zhou X.-F. Conversion of kraft lignin under hydrothermal conditions. Bioresour. Technol. 2014, 170:583-586.