메뉴 건너뛰기




Volumn 357, Issue 1, 2015, Pages 35-40

Enantioselective synthesis of chiral biaryl chlorides/iodides by a chiral phosphoric acid catalyzed sequential halogenation strategy

Author keywords

Asymmetric synthesis; Biaryls; Desymmetrization; Halogenations; Kinetic resolution

Indexed keywords


EID: 84920864433     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201400611     Document Type: Article
Times cited : (16)

References (106)
  • 100
    • 84920857254 scopus 로고    scopus 로고
    • The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
  • 101
    • 84920857252 scopus 로고    scopus 로고
    • note
    • The asymmetric iodination and chlorination with 0.50 mmol of 2c resulted in the almost same chemical yields and slightly lowered enantioselectivities (76%, 93% ee for 3c and 70%, 87% ee for 5c).
  • 102
    • 84920857250 scopus 로고    scopus 로고
    • note
    • Employment of NIS lowered enantioselectivity (73%, 84% ee).
  • 106
    • 84920857248 scopus 로고    scopus 로고
    • note
    • One-pot asymmetric chlorination/bromination sequence did not improve the enantioselectivity (62% ee, cf. 60% ee in desymmetrization).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.