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Volumn 53, Issue 50, 2014, Pages 13876-13879

Palladium-catalyzed direct C-H functionalization of benzoquinone

Author keywords

Benzoquinone; C H functionalization; Palladium; Synthetic methods; Water

Indexed keywords

ACETONE; PALLADIUM; WATER;

EID: 84919390782     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201408054     Document Type: Article
Times cited : (65)

References (43)
  • 23
    • 77956471191 scopus 로고    scopus 로고
    • Decarboxylative arylation produced low to moderate yields and was restricted to electron-rich aryl compounds with ortho substituents: Y Zhao, Y Zhang, J. Wang, H. Li, L. Wu, Z. Liu, Synlett 2010, 2352-2356.
    • (2010) Synlett , pp. 2352-2356
    • Zhao, Y.1    Zhang, Y.2    Wang, J.3    Li, H.4    Wu, L.5    Liu, Z.6
  • 30
    • 85067767726 scopus 로고    scopus 로고
    • 24] limiting its applications in synthesis
    • 24] limiting its applications in synthesis.
  • 34
    • 85067782984 scopus 로고    scopus 로고
    • Products with acyclic alkenes were too unstable/reactive to isolate
    • Products with acyclic alkenes were too unstable/reactive to isolate.
  • 35
    • 85067757968 scopus 로고    scopus 로고
    • Control reactions without Pd resulted in less than 5% conversion to 3a
    • Control reactions without Pd resulted in less than 5% conversion to 3a.
  • 41
    • 85067779650 scopus 로고    scopus 로고
    • Control reactions show that the 2, 5 and 2, 6 isomers do not interconvert under the reaction conditions
    • Control reactions show that the 2, 5 and 2, 6 isomers do not interconvert under the reaction conditions.
  • 42
    • 85067741543 scopus 로고    scopus 로고
    • In some reactions with electron-poor substituents, the products began to compete with DCBQ as oxidant, so more oxidant was often required
    • In some reactions with electron-poor substituents, the products began to compete with DCBQ as oxidant, so more oxidant was often required.
  • 43
    • 85067746290 scopus 로고    scopus 로고
    • See the Supporting Information for initial DFT calculations
    • See the Supporting Information for initial DFT calculations.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.