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II-catalyzed oxidation reactions has highlighted their similarities: Reference 1e.
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II-catalyzed oxidation reactions has highlighted their similarities: Reference 1e.
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II-H complexes, but these do not appear to be operative in catalytic reactions (with the possible exception of the [(-)-sparteine]Pd(H)Cl catalyst system): Keith, J. M.; Nielsen, R. J.; Oxgaard, J.; Goddard, W. A., III J. Am. Chem. Soc. 2005, 127, 13172-13179
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See Supporting Information for details.
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See Supporting Information for details.
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22
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79954466922
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2 concentration of ∼9 mM in benzene ([Pd-H] = 0.5 mM). See Supporting Information for additional discussion.
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2 concentration of ∼9 mM in benzene ([Pd-H] = 0.5 mM). See Supporting Information for additional discussion.
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23
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79954552592
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2H). See ref 3b for discussion. The reaction with BQ forms the protic product 6, which could similarly affect the reaction rate and lead to a nonexponential time course.
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2H). See ref 3b for discussion. The reaction with BQ forms the protic product 6, which could similarly affect the reaction rate and lead to a nonexponential time course.
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II species (e.g., see ref 10b). We examined the oxygenation of 1 in the presence of cyclohexenone, methyl acrylate, and maleic anhydride. The reaction was unaffected by the presence of cyclohexenone or methyl acrylate. In the presence of maleic anhydride, 1 undergoes rapid conversion into a complex mixture of products, none of which is Pd-OOH product 4. See Supporting Information for details.
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II species (e.g., see ref 10b). We examined the oxygenation of 1 in the presence of cyclohexenone, methyl acrylate, and maleic anhydride. The reaction was unaffected by the presence of cyclohexenone or methyl acrylate. In the presence of maleic anhydride, 1 undergoes rapid conversion into a complex mixture of products, none of which is Pd-OOH product 4. See Supporting Information for details.
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See ref 10h and the following for recent demonstrations of this principle
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See ref 10h and the following for recent demonstrations of this principle: Engle, K. M.; Wang, D.-H.; Yu, J.-Q. J. Am. Chem. Soc. 2010, 132, 14137-14151
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