Half-sandwich iridium- and rhodium-based organometallic architectures: Rational design, synthesis, characterization, and applications

Accounts of Chemical Research

Volumn 47, Issue 12, 2014, Pages 3571-3579

  Han, Ying Feng ^a   Jin, Guo Xin ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84918571317     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar500335a     Document Type: Article

References (56)

1. Cook, T. R.; Zheng, Y.-R.; Stang, P. J. Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials. Chem. Rev. 2013, 113, 734-777.
2. Chakrabarty, R.; Mukherjee, P. S.; Stang, P. J. Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles. Chem. Rev. 2011, 111, 6810-6918.
3. Caulder, D. L.; Raymond, K. N. Supermolecules by Design. Acc. Chem. Res. 1999, 32, 975-982.
4. Leininger, S.; Olenyuk, B.; Stang, P. J. Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals. Chem. Rev. 2000, 100, 853-908.
5. Holliday, B. J.; Mirkin, C. A. Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry. Angew. Chem., Int. Ed. 2001, 40, 2022-2043.
6. Cotton, F. A.; Lin, C.; Murillo, C. A. Supramolecular Arrays Based on Dimetal Building Units. Acc. Chem. Res. 2001, 34, 759-771.
7. Fujita, M.; Tominaga, M.; Hori, A.; Therrien, B. Coordination Assemblies from a Pd(II)-Cornered Square Complex. Acc. Chem. Res. 2005, 38, 369-378.
8. Pluth, M. D.; Raymond, K. N. Reversible Guest Exchange Mechanisms in Supramolecular Host-Guest Assemblies. Chem. Soc. Rev. 2007, 36, 161-171.
9. Yoshizawa, M.; Klosterman, J. K.; Fujita, M. Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts. Angew. Chem., Int. Ed. 2009, 48, 3418-3438.
10. Pluth, M. D.; Bergman, R. G.; Raymond, K. N. Proton-Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host. Acc. Chem. Res. 2009, 42, 1650-1659.
11. Koblenz, T. S.; Wassenaar, J.; Reek, J. N. H. Reactivity within a Confined Self-Assembled Nanospace. Chem. Soc. Rev. 2008, 37, 247-262.
12. (a) Wang, J.-Q.; Zhang, C.; Weng, L.-H.; Jin, G.-X. Synthesis and Characterization of Organometallic Macrocyclic Rhodium (III) Complex with Pyrazine Ligands. Chin. Sci. Bull. 2004, 49, 1122-1125.
13. (b) Wang, J.-Q.; Ren, C.-X.; Jin, G.-X. Synthesis and Structural Characterization of Macrocyclic Half-sandwich Rhodium(III) and Iridium(III) Complexes Bearing Bipyridyl Derivatives and Terephthalate. Organometallics 2006, 25, 74-81.
14. (c) Han, Y.-F.; Jia, W.-G.; Yu, W.-B.; Jin, G.-X. Stepwise Formation of Organometallic Macrocycles, Prisms and Boxes from Ir, Rh and Ru-Based Half-Sandwich Units. Chem. Soc. Rev. 2009, 38, 3419-3434.
15. (d) Conrady, F. M.; Fröhlich, R.; Schulte to Brinke, C.; Hahn, F. E. Stepwise Formation of a Molecular Square with Bridging NH,O-Substituted Dicarbene Building Blocks. J. Am. Chem. Soc. 2011, 133, 11496-11499.
16. (a) Fish, R. H. Bioorganometallic Chemistry: Synthesis, Structure, and Molecular Recognition Chemistry of (c¸5-pentamethyl-cyclopentadienyl)-Rhodium-DNA/RNA Complexes in Water. Coord. Chem. Rev. 1999, 185-186, 569-584.
17. (b) Severin, K. Self-Assembled Organometallic Receptors for Small Ions. Coord. Chem. Rev. 2003, 245, 3-10.
18. (c) Severin, K. Supramolecular Chemistry with Organometallic Half-Sandwich Complexes. Chem. Commun. 2006, 3859-3867.
19. +-Specific Receptors. Acc. Chem. Res. 2007, 40, 233-242.
20. (a) Therrien, B. Arene Ruthenium Cages: Boxes Full of Surprises. Eur. J. Inorg. Chem. 2009, 2445-2453.
21. (b) Singh, A. K.; Pandey, D. S.; Xu, Q.; Braunstein, P. Recent Advances in Supramolecular and Biological Aspects of Arene Ruthenium(II) Complexes. Coord. Chem. Rev. 2014, 270-271, 31-56.
22. (c) Yuan, M.; Weisser, F.; Sarkar, B.; Garci, A.; Braunstein, P.; Routaboul, L.; Therrien, B. Synthesis and Electrochemical Behavior of a Zwitterion-Bridged Metalla-Cage. Organometallics 2014, 33, 5043-5045.
23. Yan, H.; Süss-Fink, G.; Neels, A.; Stoeckli-Evans, H. Mono-, Diand Tetra-nuclear p-Cymeneruthenium Complexes Containing Oxalato Ligands. J. Chem. Soc., Dalton Trans. 1997, 4345-4350.
24. Han, Y.-F.; Lin, Y.-J.; Jia, W.-G.; Weng, L.-H.; Jin, G.-X. Stepwise Formation of Tetra- and Hexanuclear Iridium and Rhodium Complexes Containing Oxalato Ligands. Organometallics 2007, 26, 5848-5853.
25. Zhang, W.-Z.; Han, Y.-F.; Lin, Y.-J.; Jin, G.-X. [2 + 2] Photodimerization in the Solid State Aided by Molecular Templates of Rectangular Macrocycles Bearing Oxamidato Ligands. Organometallics 2010, 29, 2842-2849.
26. Han, Y.-F.; Lin, Y.-J.; Jia, W.-G.; Jin, G.-X. Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands. Organometallics 2008, 27, 4088-4097.
27. Han, Y.-F.; Jia, W.-G.; Lin, Y.-J.; Jin, G.-X. Stepwise Formation of Molecular Rectangles of Half-Sandwich Rhodium and Ruthenium Complexes Containing Bridging Chloranilate Ligands. Organometallics 2008, 27, 5002-5008.
28. Jia, W.-G.; Han, Y.-F.; Lin, Y.-J.; Weng, L.-H.; Jin, G.-X. Stepwise Formation of Half-Sandwich Iridium-Based Rectangles Containing 2,5-Diarylamino-1,4-benzoquinone Derivatives Linkers. Organometallics 2009, 28, 3459-3464.
29. Han, Y.-F.; Li, H.; Jin, G.-X. Host-Guest Chemistry with Bi- and Tetra-Nuclear Macrocyclic Metallasupramolecules. Chem. Commun. 2010, 46, 6879-6890.
30. Han, Y.-F.; Jia, W.-G.; Lin, Y.-J.; Jin, G.-X. Extending Rectangular Metal-Organic Frameworks to the Third Dimension: Discrete Organometallic Boxes for Reversible Trapping of Halocarbons Occurring with Conservation of the Lattice. Angew. Chem., Int. Ed. 2009, 48, 6234-6238.
31. Han, Y.-F.; Fei, Y.; Jin, G.-X. Self-Assembled Half-Sandwich Ir, Rh-Based Organometallic Molecular Boxes for Reversible Trapping of Halocarbon Molecules. Dalton Trans. 2010, 39, 3976-3984.
32. Han, Y.-F.; Lin, Y.-J.; Jin, G.-X. Discrete Half-Sandwich Ir, Rh-Based Organometallic Molecular Boxes: Synthesis, Characterization, and Their Properties. Dalton Trans. 2011, 40, 10370-10375.
33. Lin, Y.-J.; Han, Y.-F.; Jin, G.-X. Synthesis and Structural Characterization of Half-Sandwich Iridium Macro-Metallacycles Containing 1,5-Dihydroxy-9,10-Anthraquinone Ligand. J. Organomet. Chem. 2012, 708, 31-36.
34. Jia, A.-Q.; Han, Y.-F.; Lin, Y.-J.; Jin, G.-X. Syntheses and Reactions of Half-Sandwich Iridium, Rhodium, and Ruthenium Metallacycles Containing 4-Pyridyl Dithioether Ligands. Organometallics 2010, 29, 232-240.
35. Zhang, W.-Y.; Han, Y.-F.; Jin, G.-X. Synthesis, Characterization, and Properties of Half-Sandwich Iridium/Rhodium-Based Metallarectangles. Organometallics 2014, 33, 3091-3095.
36. Han, Y.-F.; Lin, Y.-J.; Jia, W.-G.; Wang, G.-L.; Jin, G.-X. Template-Controlled Topochemical Photodimerization Based on "Organometallic Macrocycles" through Single-Crystal to Single-Crystal Transformation. Chem. Commun. 2008, 1807-1809.
37. Wu, T.; Lin, Y.-J.; Jin, G.-X. Size Recognition and Optical Unloading of Polyaromatic Compounds Based on a Coordination Box Containing Face-to-Face Olefin Bonds. RSC Adv. 2013, 3, 11476-11479.
38. Han, Y.-F.; Jin, G.-X.; Hahn, F. E. Postsynthetic Modification of Dicarbene-Derived Metallacycles via Photochemical [2 + 2] Cycloaddition. J. Am. Chem. Soc. 2013, 135, 9263-9266.
39. Han, Y.-F.; Li, H.; Zheng, Z.-F.; Jin, G.-X. Self-Assembled Hexanuclear Organometallic Cages: Synthesis, Characterization, and Host-Guest Properties. Chem. - Asian J. 2012, 7, 1243-1250.
40. Han, Y.-F.; Lin, Y.-J.; Weng, L.-H.; Berke, H.; Jin, G.-X. Stepwise Formation of "Organometallic Boxes" with Half-Sandwich Ir, Rh and Ru Fragments. Chem. Commun. 2008, 350-352.
41. Han, Y.-F.; Lin, Y.-J.; Jia, W.-G.; Jin, G.-X. Half-Sandwich Ir-Based Neutral Organometallic Macrocycles Containing Pyridine-4-Thiolato Ligands. Dalton Trans. 2009, 2077-2080.
42. Wang, G.-L.; Lin, Y.-J.; Berke, H.; Jin, G.-X. Two-Step Assembly of Multinuclear Metallacycles with Half-Sandwich Ir, Rh, and Ru Fragments for Counteranion Encapsulation. Inorg. Chem. 2010, 49, 2193-2201.
43. Wang, G.-L.; Lin, Y.-J.; Jin, G.-X. Anion-Templated Assembly of Half-Sandwich Rhodium-Based Multinuclear Metallamacrocycles. Chem. - Eur. J. 2011, 17, 5578-5587.
44. Han, Y.-F.; Jin, G.-X. Cyclometalated [Cp∗M(C∧X)] (M = Ir, Rh; X = N, C, O, P) Complexes. Chem. Soc. Rev. 2014, 43, 2799-2823.
45. Han, Y.-F.; Li, H.; Weng, L.-H.; Jin, G.-X. Efficient Formation of Organoiridium Macrocycles via C-H Activation Directed Self-Assembly. Chem. Commun. 2010, 46, 3556-3558.
46. Li, H.; Han, Y.-F.; Jin, G.-X. Bis-Imine-Cyclometalated Macrocycles: Synthesis, Characterization and Observation of Solution Behavior. Dalton Trans. 2011, 40, 4982-4993.
47. Yu, W.-B.; Han, Y.-F.; Lin, Y.-J.; Jin, G.-X. Cleavage of C-H Bonds for Building Tetranuclear Half-Sandwich Iridium Macrocycles with Ortho-Metalated Spacers. Organometallics 2010, 29, 2827-2830.
48. Yu, W.-B.; Han, Y.-F.; Lin, Y.-J.; Jin, G.-X. Construction of Tetranuclear Macrocycles through C-H Activation and Structural Transformation Induced by [2 + 2] Photocycloaddition Reaction. Chem. - Eur. J. 2011, 17, 1863-1871.
49. Han, Y.-F.; Jin, G.-X. Flexible Organometallic Cages: Efficient Formation by C-H Activation-Directed Multicomponent Assembly, Isomerization, and Host-Guest Properties. Chem. - Asian J. 2011, 6, 1348-1352.
50. Han, Y.-F.; Lin, Y.-J.; Hor, T. S. A; Jin, G.-X. Efficient Route to Organometallic Cage Formation via C-H Activation-Directed Multi-component Assembly Accompanying Aromatic Guest Encapsulation. Organometallics 2012, 31, 995-1000.
51. Yao, Z.-J.; Yu, W.-B.; Lin, Y.-J.; Huang, S.-L.; Li, Z.-H.; Jin, G.-X. Iridium-Mediated Regioselective B-H/C-H Activation of Carborane Cage: A Facile Synthetic Route to Metallacycles with a Carborane Backbone. J. Am. Chem. Soc. 2014, 136, 2825-2832.
52. Liu, J.-J.; Lin, Y.-J.; Jin, G.-X. Box-like Heterometallic Macrocycles Derived from Bis-Terpyridine Metalloligands. Organometallics 2014, 33, 1283-1290.
53. Zhang, Y.-Y.; Lin, Y.-J.; Jin, G.-X. Nano-Sized Heterometallic Macrocycles Based on 4-Pyridinylboron-Capped Iron(II) Clathrochelates: Syntheses, Structures and Properties. Chem. Commun. 2014, 50, 2327-2329.
54. Huang, S.-L.; Lin, Y.-J.; Hor, T. S. A.; Jin, G.-X. Cp∗Rh-Based Heterometallic Metallarectangles: Size-Dependent Borromean Link Structures and Catalytic Acyl Transfer. J. Am. Chem. Soc. 2013, 135, 8125-8128.
55. Huang, S.-L.; Lin, Y.-J.; Li, Z.-H.; Jin, G.-X. Self-Assembly of Molecular Borromean Rings from Bimetallic Coordination Rectangles. Angew. Chem., Int. Ed. 2014, 53, 11218-11222.
56. Li, H.; Han, Y.-F.; Lin, Y.-J.; Guo, Z.-W.; Jin, G.-X. Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy. J. Am. Chem. Soc. 2014, 136, 2982-2985.