Synthesis and characterization of organometallic macrocyclic rhodium (III) complex with pyrazine ligands

Chinese Science Bulletin

Volumn 49, Issue 11, 2004, Pages 1122-1125

  Wang, Jianqiang ^a   Zhang, Zheng ^a   Weng, Linhong ^a   Jin, Guoxin ^a  

^a FUDAN UNIVERSITY   (China)

Author keywords

Half sandwich rhodium complex; Organometallic macrocyclic complex; Pyrazine; Single crystal structure

Indexed keywords

TETRA;

EID: 30344441368     PISSN: 10016538     EISSN: 18619541     Source Type: Journal    
DOI: 10.1360/04wb0040     Document Type: Article

References (17)

1. Fujita, M., Metal-directed self-assembly of two- and three-dimensional synthetic receptors, Chem. Soc. Rev., 1998, 27(6): 417-425.
2. Leininger, S., Olenyuk, B., Stang, P. J., Self-assembly of discrete cyclic nanostructures mediated by transition metals, Chem. Rev., 2000, 100(3): 853-908.
3. Holliday, B. J., Mirkin, C. A., Strategies for the construction of supramolecular compounds through coordination chemistry, Angew. Chem. Int. Ed. Engl., 2001, 40(11): 2022-2043.
4. Fujita, M., Yazaki, J., Ogura, K., Preparation of a macrocyclic polynuclear complex, [(en) Pd (4,4′-bpy)] 4(NO3) 8, which recognizes an organic molecule in aqueous media, J. Am. Chem. Soc., 1990, 112(14): 5645-5647.
5. Schmitz, M., Leininger, S., Fan, J. et al., Preparation and solid-state properties of self-assembled dinuclear platinum (I) and palladium (II) rhomboids from carbon and silicon tectons, Organmetallics, 1999, 18(23): 4817-4824.
6. Sun, S. S., Lees, A. J., Transition metal based supramolecular systems: synthesis, photophysics, photochemistry and their potential applications as luminescent anion chemosensors, Coord. Chem. Rev., 2002, 230(1-2): 170-191.
7. +-metallacrown complex, Angew. Chem. Int. Ed. Engl., 2002, 41(8): 1419-1422.
8. Melissa, L. M., del Pilar Mejia, M., Nguyen, S. T., Artificial enzymes formed through directed assembly of molecular square encapsulated epoxidation catalysts, Angew. Chem. Int. Ed. Engl., 2001, 40(22): 4239-4242.
9. Lu, S. X., Jin, G. X., Eibl, S. et al., Dinuclear half-sandwich complexes containing bridging 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligands, Organometallics, 2002, 21(12): 2533-2535.
10. Kong, Q. A., Jin, G. X., Half-sandwich rhodium polychalcogenide complexes and a carbon insertion into Te-Te bond. Chin. Sci. Bull., 2002, 47(3): 187-189.
11. Kong, Q. A., Jin, G. X., Cai, S. Y. et al., Synthesis and reaction of 16-electron CptRh halfsandwich complexes containing 1, 2-dichalcogenolate carborane ligands, Chin. Sci. Bull., 2003, 48(16): 1733-1736.
12. Yamamotoa, Y, Suzuki, H, Tajima, N. et al., Stepwise formation of quasi-octehedral macrocyclic complexes of rhodium bearing a pentamethylcyclopentadienyl group, Chem. Eur. J., 2002, 8(2): 372-379.
13. Severin, K., Self-assembled organometallic receptors for small ions, Coord. Chem. Rev., 2003, 245(1-2): 3-10.
14. 3 polytelluride, J. Am. Chem. Soc., 2001, 123(4): 735-736.
15. Yu, X. Y., Jin, G. X., Hu, N. H. et al., Synthesis and structural characterization of organolanthanide complexes with 1,2-dicarbacloso- dodecaborane-1,2-dichalcogenolate ligands, Organometallics, 2002, 21 (25): 5540-5548.
16. Nutton, A., Bailey, P. M., Maitlis, P. M., Pentamethylcyclopentadienyl- rhodium and -iridium complexes, Part 29, J. Chem. Soc., Dalton Trans, 1981, 10(9): 1997-2002.
17. Churchill, E. R., Julis, S. A., Rotella, F. J., Comparative geometry Rh(μ -Cl)Rh and Rh(μ -H)(μ- Cl)Rh bridges, Inorg. Chem., 1977, 16(5): 1137-1141.