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Volumn 33, Issue 1, 2015, Pages 1-55

The Chemistry of TALSPEAK: A Review of the Science

Author keywords

actinide; DTPA; HDEHP; lactic acid; lanthanide; solvent extraction; TALSPEAK

Indexed keywords

ACTINIDES; AMINES; CHLORINE COMPOUNDS; FISSION PRODUCTS; LACTIC ACID; LITHIUM COMPOUNDS; NUCLEAR FUELS; REAGENTS; SOLVENT EXTRACTION;

EID: 84916887247     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366299.2014.985912     Document Type: Article
Times cited : (161)

References (73)
  • 1
    • 0016179319 scopus 로고
    • Extraction in the separation of rare earths and trivalent actinides
    • Marinsky J. A., Marcus Y., (eds), Marcel Dekker, New York:
    • Weaver, B. Solvent extraction in the separation of rare earths and trivalent actinides. In Ion Exchange and Solvent Extraction; Vol. 6, J. A. Marinsky and Y. Marcus, Eds., Marcel Dekker: New York, 1974; pp 189–277.
    • (1974) Ion Exchange and Solvent Extraction , vol.6 , pp. 189-277
    • Solvent, W.B.1
  • 2
    • 33645932937 scopus 로고    scopus 로고
    • Separations and transmutation criteria to improve utilization of a geologic repository
    • Wigeland, R. A.; Bauer, T. H.; Fanning, T. H.; Morris, E. E. Separations and transmutation criteria to improve utilization of a geologic repository. Nucl. Technol. 2006, 154, 95–106.
    • (2006) Nucl. Technol , vol.154 , pp. 95-106
    • Wigeland, R.A.1    Bauer, T.H.2    Fanning, T.H.3    Morris, E.E.4
  • 3
    • 54849413968 scopus 로고    scopus 로고
    • Complexation and separation of lanthanides(III) and actinides(III) by heterocyclic n-donors in solution
    • Kolarik, Z. Complexation and separation of lanthanides(III) and actinides(III) by heterocyclic n-donors in solution. Chem. Rev. 2008 108, 4208–4252.
    • (2008) Chem. Rev , vol.108 , pp. 4208-4252
    • Kolarik, Z.1
  • 4
    • 44349162395 scopus 로고    scopus 로고
    • An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III)
    • Ekberg, C.; Fermvik, A.; Retegan, T.; Skarnemark, G.; Foreman, M. R. S.; Hudson, M. J.; Englund, S.; Nilsson M. An overview and historical look back at the solvent extraction using nitrogen donor ligands to extract and separate An(III) from Ln(III). Radiochim. Acta 2008 96, 225–234.
    • (2008) Radiochim. Acta , vol.96 , pp. 225-234
    • Ekberg, C.1    Fermvik, A.2    Retegan, T.3    Skarnemark, G.4    Foreman, M.R.S.5    Hudson, M.J.6    Englund, S.7    Nilsson, M.8
  • 5
    • 78649491548 scopus 로고    scopus 로고
    • Overview of Recent Advances in An(III)/Ln(III) Separation by Solvent Extraction
    • Moyer B. A., (ed), Taylor and Francis, Philadelphia: Chap. 3
    • Hill, C. Overview of Recent Advances in An(III)/Ln(III) Separation by Solvent Extraction. In Ion Exchange and Solvent Extraction; Vol. 19; Moyer, B. A., Ed.; Taylor and Francis: Philadelphia, 2010; Chap. 3, pp 119–193.
    • (2010) Ion Exchange and Solvent Extraction , vol.19 , pp. 119-193
    • Hill, C.1
  • 6
    • 84903083714 scopus 로고    scopus 로고
    • Development of Highly Selective Compounds for Solvent Extraction Processes: Partitioning and Transmutations of Long-Lived Radionuclides from Spent Nuclear Fuels
    • Nash K. L., Lumetta G. J., (eds), Woodhead Publishing, Oxford:
    • Hill, C. Development of Highly Selective Compounds for Solvent Extraction Processes: Partitioning and Transmutations of Long-Lived Radionuclides from Spent Nuclear Fuels. In Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment; Nash, K. L., Lumetta, G. J., Eds.; Woodhead Publishing: Oxford, 2011; pp 311–362.
    • (2011) Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment , pp. 311-362
    • Hill, C.1
  • 8
    • 67649509695 scopus 로고    scopus 로고
    • Extraction behaviour of actinides and lanthanides in TALSPEAK, TRUEX and NPEX processes of UREX+
    • Gelis, A. V.; Vandegrift, G. F.; Bakel, A.; Bowers, D. L.; Hebden, A. S.; Pereira, C.; Regalbuto, M. Extraction behaviour of actinides and lanthanides in TALSPEAK, TRUEX and NPEX processes of UREX+. Radiochim. Acta, 2009, 97(4–5), 231–232.
    • (2009) Radiochim. Acta , vol.97 , Issue.4-5 , pp. 231-232
    • Gelis, A.V.1    Vandegrift, G.F.2    Bakel, A.3    Bowers, D.L.4    Hebden, A.S.5    Pereira, C.6    Regalbuto, M.7
  • 10
    • 84864062771 scopus 로고    scopus 로고
    • Alternative Separation and Extraction: UREX+ Processes for Actinide and Targeted Fission Product Recovery
    • Nash K. L., Lumetta G. J., (eds), Woodhead Publishing: Oxford
    • Regalbuto, M. Alternative Separation and Extraction: UREX+ Processes for Actinide and Targeted Fission Product Recovery. In Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment; Nash, K. L., Lumetta, G. J., Eds.; Woodhead Publishing: Oxford, 2011; pp 176–200.
    • (2011) In Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment; , pp. 176-200
    • Regalbuto, M.1
  • 12
    • 84963487910 scopus 로고
    • Hot test of a TALSPEAK procedure for separation of actinides and lanthanides using recirculating DTPA-lactic acid solution
    • Persson, G.; Svantesson, I.; Wingefors, S.; Liljenzin, J. O. Hot test of a TALSPEAK procedure for separation of actinides and lanthanides using recirculating DTPA-lactic acid solution. Solvent Extr. Ion Exch. 1984, 2(1), 89–113.
    • (1984) Solvent Extr. Ion Exch , vol.2 , Issue.1 , pp. 89-113
    • Persson, G.1    Svantesson, I.2    Wingefors, S.3    Liljenzin, J.O.4
  • 14
    • 0018482427 scopus 로고
    • Separation of transplutonium and rare earth elements by extraction with diisodecyl phosphoric acid from DTPA solution
    • Tachimori, S.; Sato, A.; Nakamura, H. Separation of transplutonium and rare earth elements by extraction with diisodecyl phosphoric acid from DTPA solution. J. Nucl. Sci. Technol. 1979, 16(6), 434–440.
    • (1979) J. Nucl. Sci. Technol , vol.16 , Issue.6 , pp. 434-440
    • Tachimori, S.1    Sato, A.2    Nakamura, H.3
  • 15
    • 33846685614 scopus 로고    scopus 로고
    • Science and Technology
    • Morss L. R., Katz J. J., Edelstein N., Fuger J., (eds), Springer, Dordrecht, The Netherlands: Chap. 24
    • Nash, K. L.; Madic, C.; Mathur, J. N.; Lacquement, J. Actinide Separation Science and Technology. In The Chemistry of Actinides and Transactinide Elements; Morss, L. R., Katz, J. J., Edelstein, N., Fuger, J., Eds.; Springer: Dordrecht, The Netherlands, 2006; Chap. 24, 2622–2798.
    • (2006) The Chemistry of Actinides and Transactinide Elements , pp. 2622-2798
    • Nash, K.L.1    Madic, C.2    Mathur, J.N.3    Actinide Separation, L.J.4
  • 16
    • 35248891926 scopus 로고    scopus 로고
    • A review of the development and operational characteristics of the TALSPEAK process
    • Nilsson, M.; Nash, K. L. A review of the development and operational characteristics of the TALSPEAK process. Solvent Extr. Ion Exch. 2007, 25(6), 665–701.
    • (2007) Solvent Extr. Ion Exch , vol.25 , Issue.6 , pp. 665-701
    • Nilsson, M.1    Nash, K.L.2
  • 18
    • 70449511737 scopus 로고    scopus 로고
    • Trans-lanthanide extraction studies in the TALSPEAK system: Investigating the effect of acidity and temperature
    • Nilsson, M.; Nash, K. L. Trans-lanthanide extraction studies in the TALSPEAK system: Investigating the effect of acidity and temperature. Solvent Extr. Ion Exch. 2009, 27(3), 354–377.
    • (2009) Solvent Extr. Ion Exch , vol.27 , Issue.3 , pp. 354-377
    • Nilsson, M.1    Nash, K.L.2
  • 19
    • 51249187169 scopus 로고
    • E. A. On the mechanism of trivalent actinide extraction in the system HDEHP-lactic acid with DTPA J. Radioanal
    • Kosyakov, V. N.; Yerin, E. A. Separation of transplutonium and rare-earth elements by extraction with HDEHP from DTPA solutions. J. Radioanal. Chem. 1978, 43, 37–51
    • Kosyakov, V. N.; Yerin, E. A. On the mechanism of trivalent actinide extraction in the system HDEHP-lactic acid with DTPA J. Radioanal. Chem. 1980, 56(1–2), 93–104. Kosyakov, V. N.; Yerin, E. A. Separation of transplutonium and rare-earth elements by extraction with HDEHP from DTPA solutions. J. Radioanal. Chem. 1978, 43, 37–51.
    • (1980) Chem , vol.56 , Issue.1-2 , pp. 93-104
    • Kosyakov, V.N.1    Yerin2
  • 20
    • 0002446222 scopus 로고
    • Separation of americium and neodymium by selective stripping and subsequent extraction with HDEHP using DTPA-lactic acid solution in a closed loop
    • Svantesson, I.; Hagström, I.; Persson, G.; Liljenzin, J. O. Separation of americium and neodymium by selective stripping and subsequent extraction with HDEHP using DTPA-lactic acid solution in a closed loop. Radiochem. Radioanal. Lett. 1979, 37(4–5), 251–222.
    • (1979) Radiochem. Radioanal. Lett , vol.37 , Issue.4-5 , pp. 222-251
    • Svantesson, I.1    Hagström, I.2    Persson, G.3    Liljenzin, J.O.4
  • 21
    • 84916892572 scopus 로고
    • ORNL-P-1577, Oak Ridge National Laboratory, Oak Ridge, TN:United States Atomic Energy Commission [Unclassified and Declassified Reports Published by the Atomic Energy Commission and Its Contractors]
    • Leuze, R. E.; Baybarz, R. D.; Kappelmann, F. A.; Weaver, B. Behavior of the transplutonium elements in solvent extraction systems. United States Atomic Energy Commission [Unclassified and Declassified Reports Published by the Atomic Energy Commission and Its Contractors], ORNL-P-1577, Oak Ridge National Laboratory: Oak Ridge, TN, 1965; 16
    • (1965) Behavior of the transplutonium elements in solvent extraction systems , pp. 16
    • Leuze, R.E.1    Baybarz, R.D.2    Kappelmann, F.A.3    Weaver, B.4
  • 22
    • 0030705308 scopus 로고    scopus 로고
    • Citrate-based “TALSPEAK” actinide-lanthanide separation process
    • Del Cul, G. D.; Toth, L. M.; Bond, W. D.; Davis, G. D.; Dai, S. Citrate-based “TALSPEAK” actinide-lanthanide separation process, Sep. Sci. Technol. 1997, 32(1–4), 431–446.
    • (1997) Sep. Sci. Technol , vol.32 , Issue.1-4 , pp. 431-446
    • Del Cul, G.D.1    Toth, L.M.2    Bond, W.D.3    Davis, G.D.4    Dai, S.5
  • 23
    • 0016320397 scopus 로고
    • Acidic organophosphorus extractants—XXI. Kinetics and equilibria of extraction of Eu(III) by di(2-ethylhexyl) phosphoric acid from complexing media
    • thSeptember
    • thSeptember, 1974, Vol. 3, pp 2593–2606.
    • (1974) Proc. Int. Solvent Extr. Conf , Issue.3 , pp. 2593-2606
    • Kolarik, Z.1    Kuhn, W.2
  • 24
    • 0042090337 scopus 로고
    • Kinetics and Mechanisms of Actinide Redox and Complexation Reactions
    • Sykes A. G., (ed), Academic Press, New York:
    • Nash, K. L.; Sullivan, J. C. Kinetics and Mechanisms of Actinide Redox and Complexation Reactions. In Advances in Inorganic and Bioinorganic Reaction Mechanisms; Vol. 5, Sykes, A. G. Ed., Academic Press: New York, 1986; pp 185–213.
    • (1986) Advances in Inorganic and Bioinorganic Reaction Mechanisms , vol.5 , pp. 185-213
    • Nash, K.L.1    Sullivan, J.C.2
  • 25
    • 70350333422 scopus 로고
    • Kinetics of Complexation and Redox Reactions of the Lanthanides in Aqueous Solutions
    • Gschneidner Jr. K. A., Eyring L., (eds), North Holland, Amsterdam: Chap. 102
    • Nash, K. L.; Sullivan, J. C. Kinetics of Complexation and Redox Reactions of the Lanthanides in Aqueous Solutions. In Handbook for the Physics and Chemistry of the Rare Earths; Vol. 15, Gschneidner, K. A., Jr., Eyring, L., Eds., North Holland: Amsterdam, 1991; Chap. 102, pp 347–391.
    • (1991) Handbook for the Physics and Chemistry of the Rare Earths , vol.15 , pp. 347-391
    • Nash, K.L.1    Sullivan, J.C.2
  • 26
    • 0020135561 scopus 로고
    • Mechanism of the Interfacial Mass Transfer of Eu(III)
    • Danesi, P. R; Cianetti, C. Kinetics and Mechanism of the Interfacial Mass Transfer of Eu(III). Sep. Sci. Technol. 1982, 17, 969–984.
    • (1982) Sep. Sci. Technol , vol.17 , pp. 969-984
    • Cianetti, D.P.1    Kinetics, C.2
  • 27
    • 84916891603 scopus 로고
    • IMR-Report, No. 1393/v/C
    • 3system. IMR-Report, No. 1393/v/C, 1972.
    • (1972) 3system
    • Fidelis, I.1
  • 28
    • 53949116750 scopus 로고
    • Trends in Thermodynamic Functions of Complexation of the Lanthanide Ions with Different Ligands and the Double-Double Effect in the Enthalpy Changes
    • Fidelis, I. Trends in Thermodynamic Functions of Complexation of the Lanthanide Ions with Different Ligands and the Double-Double Effect in the Enthalpy Changes. Bull. l’Acad. Pol. Des Sci. 1972, 20(6), 605–610.
    • (1972) Bull. l’Acad. Pol. Des Sci , vol.20 , Issue.6 , pp. 605-610
    • Fidelis, I.1
  • 29
    • 53949113989 scopus 로고    scopus 로고
    • Two-phase calorimetry. I. Studies on the thermodynamics of lanthanide extraction by bis(2-ethyl(hexyl)) phosphoric acid
    • Zalupski, P. R.; Nash, K. L. Two-phase calorimetry. I. Studies on the thermodynamics of lanthanide extraction by bis(2-ethyl(hexyl)) phosphoric acid. Solvent Extr. Ion Exch. 2008, 26(5), 514–553.
    • (2008) Solvent Extr. Ion Exch , vol.26 , Issue.5 , pp. 514-553
    • Zalupski, P.R.1    Nash, K.L.2
  • 31
    • 84894489130 scopus 로고    scopus 로고
    • Acid dissociation constants and rare earth stability constants for DTPA
    • Grimes, T. S.; Nash, K. L. Acid dissociation constants and rare earth stability constants for DTPA. J. Solution Chem. 2014, 43(2), 298–313.
    • (2014) J. Solution Chem , vol.43 , Issue.2 , pp. 298-313
    • Grimes, T.S.1    Nash, K.L.2
  • 33
    • 0004798566 scopus 로고
    • Separation of transplutonium elements
    • Stary, J. Separation of transplutonium elements. Talanta 1966, 13(3), 421–437.
    • (1966) Talanta , vol.13 , Issue.3 , pp. 421-437
    • Stary, J.1
  • 35
    • 0001654795 scopus 로고
    • The complexation of lanthanides by aminocarboxylate ligands—I: Stability Constants
    • Gritmon, T. F.; Goedken, M. P.; Choppin, G. R. The complexation of lanthanides by aminocarboxylate ligands—I: Stability Constants. J. Inorg. Nucl. Chem. 1977, 39, 2021–2023.
    • (1977) J. Inorg. Nucl. Chem , vol.39 , pp. 2021-2023
    • Gritmon, T.F.1    Goedken, M.P.2    Choppin, G.R.3
  • 36
    • 77956204787 scopus 로고    scopus 로고
    • Effect of Temperature on the Protonation of the TALSPEAK Ligands: Lactic and Diethylenetrinitropentaacetic Acids
    • Tian, G.-X.; Rao, L.-F. Effect of Temperature on the Protonation of the TALSPEAK Ligands: Lactic and Diethylenetrinitropentaacetic Acids. Sep. Sci. Technol. 2010, 45(12–13), 1718–1724.
    • (2010) Sep. Sci. Technol , vol.45 , Issue.12-13 , pp. 1718-1724
    • Tian, G.-X.1    Rao, L.-F.2
  • 37
    • 34547807616 scopus 로고    scopus 로고
    • Thermodynamics and dissociation constants of carboxylic acids at high ionic strength and temperature
    • Thakur, P.; Mathur, J. N.; Moore, R. C.; Choppin, G. R. Thermodynamics and dissociation constants of carboxylic acids at high ionic strength and temperature. Inorg. Chim. Acta. 2007, 360(12), 3671–3680.
    • (2007) Inorg. Chim. Acta , vol.360 , Issue.12 , pp. 3671-3680
    • Thakur, P.1    Mathur, J.N.2    Moore, R.C.3    Choppin, G.R.4
  • 38
    • 0001445299 scopus 로고
    • Observations on the rare earths—LXXV: The stabilities of diethylenetriaminepentaacetic acid chelates
    • Moeller, T.; Thompson, L. C. Observations on the rare earths—LXXV: The stabilities of diethylenetriaminepentaacetic acid chelates. J. Inorg. Nucl. Chem. 1962, 24, 499–510.
    • (1962) J. Inorg. Nucl. Chem , vol.24 , pp. 499-510
    • Moeller, T.1    Thompson, L.C.2
  • 39
    • 0001363699 scopus 로고
    • The complexation of lanthanides by aminocarboxylate ligands—II: Thermodynamic parameters
    • Choppin, G. R.; Goedken, M. P.; Gritmon, T. F. The complexation of lanthanides by aminocarboxylate ligands—II: Thermodynamic parameters. J. Inorg. Nucl. Chem. 1977, 39, 2025–2030.
    • (1977) J. Inorg. Nucl. Chem , vol.39 , pp. 2025-2030
    • Choppin, G.R.1    Goedken, M.P.2    Gritmon, T.F.3
  • 40
    • 24744462585 scopus 로고
    • Temperature dependence of heats of complexing of rare earth elements with diethylenetriaminepentaacetic acid in an aqueous solution
    • Milyukov, P. M. Temperature dependence of heats of complexing of rare earth elements with diethylenetriaminepentaacetic acid in an aqueous solution. Izv. Vyssh. Ucheb. Zaved. Khim. 1988, 31, 23–25.
    • (1988) Izv. Vyssh. Ucheb. Zaved. Khim , vol.31 , pp. 23-25
    • Milyukov, P.M.1
  • 41
    • 77951696611 scopus 로고    scopus 로고
    • Do aqueous ternary complexes influence the TALSPEAK process?
    • Leggett, C. J.; Liu, G.; Jensen, M. P. Do aqueous ternary complexes influence the TALSPEAK process? Solvent Extr. Ion Exch. 2010, 28(3), 313–334.
    • (2010) Solvent Extr. Ion Exch , vol.28 , Issue.3 , pp. 313-334
    • Leggett, C.J.1    Liu, G.2    Jensen, M.P.3
  • 42
    • 77956220402 scopus 로고    scopus 로고
    • Lactic acid partitioning in TALSPEAK extraction systems
    • Grimes, T. S.; Nilsson, M. A.; Nash, K. L. Lactic acid partitioning in TALSPEAK extraction systems. Sep. Sci. Technol. 2010, 45(12–13), 1725–1732.
    • (2010) Sep. Sci. Technol , vol.45 , Issue.12-13 , pp. 1725-1732
    • Grimes, T.S.1    Nilsson, M.A.2    Nash, K.L.3
  • 44
    • 0001721727 scopus 로고
    • Sodium and strontium extraction by di(2-ethylhexyl) phosphate: mechanisms and equilibria
    • McDowell, W. J.; Coleman, C. F. Sodium and strontium extraction by di(2-ethylhexyl) phosphate: mechanisms and equilibria. J. Inorg. Nucl. Chem. 1965, 27, 1117–1139.
    • (1965) J. Inorg. Nucl. Chem , vol.27 , pp. 1117-1139
    • McDowell, W.J.1    Coleman, C.F.2
  • 45
    • 84916892569 scopus 로고    scopus 로고
    • Partitioning of sodium and lactate between organic di(2-ethylhexyl)phosphoric acid solution and aqueous lactate buffer solution
    • Uruga, K.; Grimes, T. S.; Enokida, Y.; Nash. K. L. Partitioning of sodium and lactate between organic di(2-ethylhexyl)phosphoric acid solution and aqueous lactate buffer solution. Solvent Extr. Ion Exch., (in preparation).
    • Solvent Extr. Ion Exch., (in preparation)
    • Uruga, K.1    Grimes, T.S.2    Enokida, Y.3    Nash, K.L.4
  • 46
    • 77958600090 scopus 로고    scopus 로고
    • Thermodynamic features of the complexation of neodymium(III) and americium(III) by lactate in trifluoromethanesulfonate media
    • Zalupski, P. R.; Nash, K. L.; Martin, L. R. Thermodynamic features of the complexation of neodymium(III) and americium(III) by lactate in trifluoromethanesulfonate media. J. Solution Chem. 2010, 39(8), 1213–1229.
    • (2010) J. Solution Chem , vol.39 , Issue.8 , pp. 1213-1229
    • Zalupski, P.R.1    Nash, K.L.2    Martin, L.R.3
  • 47
    • 84916892568 scopus 로고    scopus 로고
    • Toward understanding the thermodynamics of TALSPEAK process. Medium effects on actinide complexation. From IOP Conference Series: Mater
    • 012076/1–012076/8
    • Zalupski, P. R.; Nash, K. L.; Nakamura, Y.; Yamamoto, M.; Martin, L. R., Toward understanding the thermodynamics of TALSPEAK process. Medium effects on actinide complexation. From IOP Conference Series: Mater. Sci. Eng. 2010, 9, 012076/1–012076/8.
    • (2010) Sci. Eng , vol.9
    • Zalupski, P.R.1    Nash, K.L.2    Nakamura, Y.3    Yamamoto, M.4    Martin, L.R.5
  • 48
    • 84916941084 scopus 로고    scopus 로고
    • Activity coefficients of di-(2-ethylhexyl) phosphoric acid in select diluents
    • Gray, M.; Zalupski, P.; Nilsson, M. Activity coefficients of di-(2-ethylhexyl) phosphoric acid in select diluents. Procedia Chemistry 2012, 7, 209–214.
    • (2012) Procedia Chemistry , vol.7 , pp. 209-214
    • Gray, M.1    Zalupski, P.2    Nilsson, M.3
  • 49
    • 84861934368 scopus 로고    scopus 로고
    • Optical spectroscopy study of organic-phase lanthanide complexes in the TALSPEAK separations process
    • Grimes, T. S.; Tian, G.; Rao, L.; Nash, K. L. Optical spectroscopy study of organic-phase lanthanide complexes in the TALSPEAK separations process. Inorg. Chem. 2012, 51(11), 6299–6307.
    • (2012) Inorg. Chem , vol.51 , Issue.11 , pp. 6299-6307
    • Grimes, T.S.1    Tian, G.2    Rao, L.3    Nash, K.L.4
  • 50
    • 0000503861 scopus 로고
    • The preparation and infa-red absorption spectra of several complexes of bis-(2-ethylhexyl)-phosphoric acid
    • Peppard, D. F.; Ferraro, J. R. The preparation and infa-red absorption spectra of several complexes of bis-(2-ethylhexyl)-phosphoric acid. J. Inorg. Nucl. Chem. 1959, 10, 275–288.
    • (1959) J. Inorg. Nucl. Chem , vol.10 , pp. 275-288
    • Peppard, D.F.1    Ferraro, J.R.2
  • 52
    • 84870025324 scopus 로고    scopus 로고
    • Small-angle neutron scattering study of organic-phase aggregation in the TALSPEAK process
    • Grimes, T. S.; Jensen, M. P.; Debeer-Schmidt, L.; Littrell, K.; Nash, K. L. Small-angle neutron scattering study of organic-phase aggregation in the TALSPEAK process. J. Phys. Chem. B 2012, 116(46), 13722–13730.
    • (2012) J. Phys. Chem. B , vol.116 , Issue.46 , pp. 13722-13730
    • Grimes, T.S.1    Jensen, M.P.2    Debeer-Schmidt, L.3    Littrell, K.4    Nash, K.L.5
  • 56
    • 70749117810 scopus 로고    scopus 로고
    • Rydberg Expanded. J., Cox M., Musikas C., Choppin G. R., (eds), Second Edition, Revised, Marcel Dekker, New York: Chap. 6
    • Danesi, P. R. Solvent Extraction Kinetics. In Solvent Extraction Principles and Practice; Second Edition, Revised and Expanded. J. Rydberg, M. Cox, C. Musikas, and G. R. Choppin, Eds., Marcel Dekker: New York; Chap. 6, pp 203–251.
    • In Solvent Extraction Principles and Practice; , pp. 203-251
    • Danesi, P.R.1    Kinetics, S.E.2
  • 57
    • 80053308559 scopus 로고    scopus 로고
    • Toward mechanistic understanding of nuclear reprocessing chemistries by quantifying lanthanide solvent extraction kinetics via microfluidics with constant interfacial area and rapid mixing
    • Nichols, K. P.; Pompano, R. R.; Li, L.; Gelis, A. V.; Ismagilov, R. F. Toward mechanistic understanding of nuclear reprocessing chemistries by quantifying lanthanide solvent extraction kinetics via microfluidics with constant interfacial area and rapid mixing. J. Am. Chem. Soc. 2011, 133(39), 15721–15729.
    • (2011) J. Am. Chem. Soc , vol.133 , Issue.39 , pp. 15721-15729
    • Nichols, K.P.1    Pompano, R.R.2    Li, L.3    Gelis, A.V.4    Ismagilov, R.F.5
  • 58
    • 84869988401 scopus 로고    scopus 로고
    • The kinetics of lanthanide complexation by EDTA and DTPA in lactate media
    • Nash, K. L.; Brigham, D.; Shehee, T. C.; Martin, A. The kinetics of lanthanide complexation by EDTA and DTPA in lactate media. Dalton Trans. 2012, 41(48), 14547–14556.
    • (2012) Dalton Trans , vol.41 , Issue.48 , pp. 14547-14556
    • Nash, K.L.1    Brigham, D.2    Shehee, T.C.3    Martin, A.4
  • 61
    • 85121161434 scopus 로고    scopus 로고
    • From Pacifichem 2010, International Chemical Congress of Pacific Basin Societies, Honolulu, HI, United States: December 15–20
    • 2O at elevated temperatures and the application in TALSPEAK process study. From Pacifichem 2010, International Chemical Congress of Pacific Basin Societies, Honolulu, HI, United States, December 15–20, 2010.
    • (2010) 2O at elevated temperatures and the application in TALSPEAK process study
    • Tian, G.1    Rao, L.2
  • 63
    • 51249182903 scopus 로고
    • Radiation effects on the separation of lanthanides and transplutonides by the TALSPEAK-type extraction
    • Tachimori, S.; Nakamura, T. Radiation effects on the separation of lanthanides and transplutonides by the TALSPEAK-type extraction. J. Radioanal. Chem. 1979, 52(2), 343–354.
    • (1979) J. Radioanal. Chem , vol.52 , Issue.2 , pp. 343-354
    • Tachimori, S.1    Nakamura, T.2
  • 65
    • 62149090647 scopus 로고    scopus 로고
    • Determination of Arrhenius and thermodynamic parameters for the aqueous reaction of the hydroxyl radical with lactic acid
    • Martin, L. R.; Mezyk, S. P.; Mincher, B. J. Determination of Arrhenius and thermodynamic parameters for the aqueous reaction of the hydroxyl radical with lactic acid. J. Phys. Chem. A 2009, 113(1), 141–145.
    • (2009) J. Phys. Chem. A , vol.113 , Issue.1 , pp. 141-145
    • Martin, L.R.1    Mezyk, S.P.2    Mincher, B.J.3
  • 66
    • 84874164328 scopus 로고    scopus 로고
    • Explorations of TALSPEAK chemistry in extraction chromatography: Comparisons of TTHA with DTPA and HDEHP with HEH[EHP]
    • Braley, J. C.; McAlister, D. R.; Horwitz, E. P.; Nash, K. L. Explorations of TALSPEAK chemistry in extraction chromatography: Comparisons of TTHA with DTPA and HDEHP with HEH[EHP]. Solvent Extr. Ion Exch. 2013, 31(2), 107–121.
    • (2013) Solvent Extr. Ion Exch , vol.31 , Issue.2 , pp. 107-121
    • Braley, J.C.1    McAlister, D.R.2    Horwitz, E.P.3    Nash, K.L.4
  • 67
    • 84860110594 scopus 로고    scopus 로고
    • Alternatives to HDEHP and DTPA for simplified TALSPEAK separations
    • Braley, J. C.; Grimes, T. S.; Nash, K. L. Alternatives to HDEHP and DTPA for simplified TALSPEAK separations. Ind. Eng. Chem. Res. 2012, 51(2), 627–636.
    • (2012) Ind. Eng. Chem. Res , vol.51 , Issue.2 , pp. 627-636
    • Braley, J.C.1    Grimes, T.S.2    Nash, K.L.3
  • 69
    • 84892680804 scopus 로고    scopus 로고
    • Distribution of lanthanide and actinide elements between bis-(2-ethylhexyl)phosphoric acid and buffered lactate solutions containing selected complexants
    • Rudisill, T. S.; DiPrete, D. P.; Thompson, M. C. Distribution of lanthanide and actinide elements between bis-(2-ethylhexyl)phosphoric acid and buffered lactate solutions containing selected complexants. J. Radioanal. Nucl. Chem. 2013, 296(2), 631–638.
    • (2013) J. Radioanal. Nucl. Chem , vol.296 , Issue.2 , pp. 631-638
    • Rudisill, T.S.1    DiPrete, D.P.2    Thompson, M.C.3
  • 70
    • 84899866444 scopus 로고    scopus 로고
    • Trivalent lanthanide/actinide separation using aqueous-modified TALSPEAK chemistry
    • (in preparation)
    • Grimes, T. S.; Tillotson, R. D.; Martin, L. R. Trivalent lanthanide/actinide separation using aqueous-modified TALSPEAK chemistry. Solvent Extr. Ion Exch. 2014, (in preparation).
    • (2014) Solvent Extr. Ion Exch
    • Grimes, T.S.1    Tillotson, R.D.2    Martin, L.R.3
  • 71
    • 84897710142 scopus 로고    scopus 로고
    • Ionic liquid based separations of trivalent lanthanide and actinide ions
    • Shkrob, I. A.; Marin, T. W.; Jensen, M. P. Ionic liquid based separations of trivalent lanthanide and actinide ions. Ind. Eng. Chem. Res. 2014, 53(9), 3641–3653.
    • (2014) Ind. Eng. Chem. Res , vol.53 , Issue.9 , pp. 3641-3653
    • Shkrob, I.A.1    Marin, T.W.2    Jensen, M.P.3
  • 72
    • 79960924760 scopus 로고    scopus 로고
    • Extraction separation of rare-earth ions via competitive ligand complexations between aqueous and ionic-liquid phases
    • Sun, X.; Bell, J. R.; Luo, H.; Dai, S. Extraction separation of rare-earth ions via competitive ligand complexations between aqueous and ionic-liquid phases. Dalton Transactions 2011, 40(31), 8019–8023.
    • (2011) Dalton Transactions , vol.40 , Issue.31 , pp. 8019-8023
    • Sun, X.1    Bell, J.R.2    Luo, H.3    Dai, S.4
  • 73
    • 84864858346 scopus 로고    scopus 로고
    • Study of the interaction between HDEHP and CMPO and its effect on the extraction of selected lanthanides
    • Tkac, P.; Vandegrift, G. F.; Lumetta, G. J.; Gelis, A. V. Study of the interaction between HDEHP and CMPO and its effect on the extraction of selected lanthanides. Ind. Eng. Chem. Res. 2012, 51(31), 10433–10444.
    • (2012) Ind. Eng. Chem. Res , vol.51 , Issue.31 , pp. 10433-10444
    • Tkac, P.1    Vandegrift, G.F.2    Lumetta, G.J.3    Gelis, A.V.4


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